欢迎登录材料期刊网

材料期刊网

高级检索

主要研究了在纳米多孔Ti02/Ti电极上外加阳极偏压对亚甲基蓝光催化降解的影响.另外还讨论了在TiO2/Ti中掺杂过渡族金属离子对亚甲基蓝降解情况的影响.降解程度通过亚甲基蓝的褪色情况来表征.实验结果表明,降解效率随着所加阳极偏压的增大而增大,直到阳极偏压达到3.5 V,增大速率开始减小.掺杂Mn2+和Cr3+可以促进光电催化效率,而掺杂Ni2+却会降低光电催化效率.离子半径和各离子的功函数可以解释这种现象.

参考文献

[1] Frank S N;Bard A J .[J].Journal of the American Chemical Society,1997,99(14):4467.
[2] 郝维昌,潘锋,王天民,郑树凯.TiO2/PSS自组装薄膜的光催化性能[J].稀有金属材料与工程,2004(01):63-66.
[3] Vinodgopal K .[J].Environmental Science and Technology,1995,29:841.
[4] Vinodgopal K;Bedja I;Kamat P V .[J].Chemistry of Materials,1996,8:2180.
[5] He Chen;Xiong Ya;Zhu XiHai .[J].Catalysis Communications,2003,4:183.
[6] Sasaki T;Koshizaki N et al.[J].J chem,2001,145:11.
[7] 沈嘉年,宋江江,马寒冰,武朋飞,肖美群,姚书典.钛上阳极氧化生成TiO2光催化薄膜的结构与性能[J].稀有金属材料与工程,2004(10):1076-1079.
[8] Baraka A M;Hamed H A H A;Shaarawy H H .[J].Anti-Corrosion Methods and Materials,2002,49(04):282.
[9] John V C .[J].Journal of the American podiatric medical Association,1987,257:2796.
[10] Memming R .[J].Topics in Current Chemistry,1988,143:81.
[11] 梅燕,贾振斌,邱丽,曹江林,张艳峰,魏雨.负载型TiO2纳米薄膜电极光电催化氧化甲醇的研究[J].稀有金属材料与工程,2003(08):662-665.
[12] 曾谨言.量子力学[M].北京:科学出版社,1990:97.
[13] An Taicheng;Li Guiying;Xiong Ya et al.[J].Mater Phys Mech,2001,4:101.
[14] Yang Shaogui;Quan Xie;Li Xinyong;Liu Yazi;Chen Shuo;Chen Guohua .Preparation,characterization and photoelectrocatalytic properties of nanocrystalline Fe_2O_3/TiO_2,ZnO/TiO_2,and Fe_2O_3/ZnO/TiO_2 composite film electrodes towards pentachlorophenol degradation[J].Physical chemistry chemical physics: PCCP,2004(3):659-664.
[15] Burns A;Li W;Baker C.[A].,2002:521.
[16] Li Yanping et al.[J].Journal of Applied Physics,2004,95(12):7961.
[17] Zhao Gaolin;Kosuta H;Yoko T .[J].Thin Solid Films,1996,277:147.
[18] [OL].http://environmentalchemistry.com/yogi/periodic/,2005-07.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%