利用滴定水解法制备了Fe3O4纳米颗粒,经XRD和漫反射吸收谱分析,Fe3O4晶粒粒径约为18nm,从紫外至近红外(200~3000nm)均有很强的光吸收。纳米Fe3O4有明显的负磁阻和湿敏效应,其阻抗随磁感应强度和湿度的增大而减小。
The Fe3O4 magnetic nano-articles prepared by the titration hydrolyzation method were studied with X-ray diffration(XRD), UV-Vis diffusive reflectance
spectrum(DRS), Magnetoresistance measurement and digital bridge LCR. The results show that the Fe3O4 magnetic particles have strong absorptions in the rang
from 250nm to 3000nm;the average diameter of the Fe3O4 nano-particles is about 18nm. The Fe3O4 granular film has obvious negative magnetoresistivity
effect and humidity sensitive character. The impedance of the Fe3O4 nano-particles decreases with increasing magnetic induction and humidity respectively.
参考文献
[1] | Vijayakumar R, Koltypin Y, Felner I, et al. Mater. Sci. Eng. A-Struct. Mater., 2000, 286 (1): 101--105. [2] 邱星屏. 厦门大学学报(自然科学版), 1999, 38 (5): 711--715. [3] Tryk D A, Fujishima A, Honda K. Electrochimica ACTA, 2000, 45 (15--16): 2363--2376. [4] O’Connor C J, Seip C, Sangregorio C, et al. Mol. Cryst. Liq. Cryst. Sci. Tec. A, 1999, 334: 1135--1154. [5] Pohm V A, Daughton J M, Brown J, et al. IEEE Trans. Magn., 1995, 31: 3200--3204. [6] Schuler D, Frankel R B. Appl. Microbiol. Biotechnol., 1999, 52 (4): 464--468. [7] Ruuge E K, Rusetski A N. J. Magn. Magn.Mater., 1993, 122: 335--339. [8] 刘维桥, 孙桂大. 固体催化剂实用研究方法, 北京: 中国石化出版社, 2000. 87. [9] 徐毓龙. 氧化物与化合物半导体基础. 西安: 西电出版社, 1991. 205. [10] 蔡建旺, 赵见高, 詹文山, 等. 物理学进展, 1997, 17 (2): 119--149. [11] 严百平, 朱秉升. 西安交通大学学报, 1997, 31 (8): 39--42. |
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