基于国内外最新研究文献,系统论述了易溶性磺化聚苯胺的合成及溶液成膜.结合典型实例,论述了磺化聚苯胺的合成及成膜方法,着重分析了磺酸基的引入对聚苯胺电导性及其在有机溶剂和水中的溶解性的改善作用.讨论了目前存在的问题和未来研究方向.指出磺化聚苯胺的磺化度最高可达1.3,在水中的溶解度最高可达10.9 wt%,不经外掺杂导电率最高可达50.3 S/cm,是一类可溶液浇铸成膜的具有广阔商业应用前景的导电聚合物.
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