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采用回流焊技术制备Cu/AuSn20/Ni(质量百分比)焊点,通过扫描电子显微镜及电子万能试验机分析焊点在300℃钎焊后的界面组织及剪切强度。结果表明,Cu/AuSn20/Ni焊点在300℃钎焊较短时间时,AuSn20焊料形成(Au5Sn+AuSn)共晶组织,Cu/AuSn20上界面形成胞状的ζ-(Au,Cu)5Sn层;AuSn20/Ni下界面形成片状(Ni,Au)3Sn2金属间化合物(IMC);随着钎焊时间的延长,基板中Cu、Ni原子不断往焊料扩散,焊料成分发生变化,冷却后焊点的共晶组织消失,上界面形成ζ(Cu)固溶体,下界面的片状(Ni,Au)3Sn2不断长大形成连续IMC层,焊点组织最终由℃(Cu)固溶体和(Ni,Au)3Sn2IMC组成。钎焊接头的剪切强度随钎焊时间延长而增大,但是增大幅度较小。

The Cu/AuSn20/Ni (mass percent) joint was prepared by the reflow bonding process, and the micro- structure and shear strength of the Cu/AuSn20/Ni joint were investigated. The results showed that, the solder formed a (AusSn+AuSn) eutectic microstructure after reflow at 300℃ for a short time, and the cellular-like (Au,Cu)5 Sn intermetallic compound (IMC) was formed at the upper Cu/AuSn20 interface, while the flake-like (Ni,Au)3Sn2 IMC was formed at the lower AuSn20/Ni interface. Upon increasing the reflow time, more and more Cu(Ni)atoms from the suhtrates diffused into the solder, resulting the shift of chemical composition of the solder. So that the (Au,Cu)sSn phase at the upper Cu/AuSn20 interface transformed into the ζ(Cu) solid solution. The (Ni,Au)3Sn2 phase at the lower AuSn20/Ni interface grew gradually to form a continuous IMC layer. The eutectic microstructure in the solder vanished and the final microstructure of Cu/AuSn20/Ni joint was composed of the ζ(Cu) solid solution and (Ni,Au)3Sn2 IMC layer. The shear strength of the Cu/AuSn20/ Ni joint increased slightly with the increasing of the reflow time.

参考文献

[1] 魏秀琴 .亚共晶Sn-Zn合金无铅电子焊料研究[D].南昌大学,2006.
[2] 吕娟,赵麦群,康晶,吕海霞,佟玉飞.Sn-9Zn系无铅焊料钎焊接头剪切性能的研究[J].金属功能材料,2010(03):72-75.
[3] Niwat M;Kannachai K .Effect of soldering condition on formation of intermetallic phases developed between Sn- 0,3Ag-0,7Cu low-silver lead-free solder and Cu substrate[J].Journal of Alloys and Compounds,2011,509:6276-6279.
[4] Kim K S;Huh S H;Suganuma K .Effects of intermetal- lie compounds on properties of Sn-Ag-Cu lead-free sold- ered joints[J].Journal of Alloys and Compounds,2003,352:226-236.
[5] Siva P.V. Nadimpalli;Jan K. Spelt .Effect of geometry on the fracture behavior of lead-free solder joints[J].Engineering Fracture Mechanics,2011(6):1169-1181.
[6] Yoon J W;Jung S B .Investigation of interracial reaction between Au-Sn solder and Kovar for hermetic sealing ap- plication[J].Microelectronic Engineering,2007,84:2634-2639.
[7] Yoon JW;Chun HS;Jung SB .Correlation between interfacial reactions and shear strengths of Sn-Ag-(Cu and Bi-In)/ENIG plated Cu solder joints[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(0):731-734.
[8] 孙晓亮,马光,李银娥,刘啸锋.AuSn20焊料制备技术及发展趋势[J].电工材料,2010(03):9-11.
[9] 周涛,汤姆·鲍勃,马丁·奥德,贾松良.金锡焊料及其在电子器件封装领域中的应用[J].电子与封装,2005(08):5-8.
[10] 刘泽光,陈登权,罗锡明,许昆.微电子封装用金锡合金钎料[J].贵金属,2005(01):62-65.
[11] 刘泽光,陈登权,许昆,罗锡明,陈亮维.D-KH法制备金锡合金的组织与结构[J].贵金属,2005(03):30-33.
[12] Erika H;Maridn P;Emil L et al.Kinetics of interme- tallic phase formation at tile interface of Sn-Ag-Cu-X(X =Bi,ln) solders with Cu substrate[J].Journal of Al- loys and Compounds,2011,509:7052-7059.
[13] Cheng-En Ho;Sheng-Wei Lin;Yen-Chen Lin .Effects of Pd concentration on the interfacial reaction and mechanical reliability of the Sn-Pd/Ni system[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(29):7749-7757.
[14] Massalski T 13;Okamoto H.Binary alloy phase dia- grams[M].Ohio:ASM International,1990:433.
[15] Anhock S;Oppermann H;Kallmayer C.Investi- gations of Au/Sn alloys on different end-metallizations for high temperature applications[A].Berlin,Germany,1998
[16] IPMA.The thermodynamic databank for interconnectionand packaging materials[M].Helsinki:Helsinki Univer- sity of Technology,2000
[17] Chung H M;Chen C M;Lin C P .Mierostrueture evolu- tion of the Au-20wt%Sn solder on the Cu substrate dur- ing reflow[J].Journal of Alloys and Compounds,2009,485:219-224.
[18] Lauril T;Vuorinen V;Kivilahti J K .Interracial reac- tions between lead-free solders and common base materi- als[J].Materials Science and Engineering R:Reports,2005,49:1-60.
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