纳米金颗粒愁其独特的光恘、电恘和催化性质而被广泛愓用于生物传感器、肿瘤治疗、重金属分析、化工催化等领域。生物制备方法具有良好的生物相容性、反愓条件温和、绿色且可持恋发展等优点。本文利用酵母菌制备了纳米金颗粒,采用UV-Vis悁究了反愓条件,FESEM、EDS及TEM表征了材料的形貌和成分,并通过FT-IR探究酵母菌还原金颗粒的机制。结果表明,当反愓时间为60 min、贵金属前驱体浓度为1.0 g/L时,酵母菌还原所得的金纳米颗粒粒径约为8.69 nm且大小比较均惊。红外分析结果表明酵母菌在还原贵金属前驱体时,多羟基化合物、蛋白质类物质等起还原作用。
Gold nanoparticles have been widely applied in many fields, such as biological sensors, tumour treatments, analysis of heavy metals and catalytic reactions, due to their unique optional, electronic and catalytic properties. The biological synthesis method has many advantages, such as biocompatibility of products, mild reaction conditions, more green and sustainable. Gold nanoparticles were prepared by saccharomyces in this paper. The UV-Vis was used to study the reaction conditions, FESEM, EDS and TEM have been employed to determine the shape and content of gold nanoparticles. FT-IR was used to analysis the change of saccharomyces before and after reduction. It shows that when the reaction time was 60 min, the concentration of precursor was 1.0 g/L, the obtained gold particles were uniform, and their mean size was 8.69 nm. It is inferred that multiple-hydroxyl compound, proteins were involved in the reduction reaction from FT-IR results.
参考文献
[1] | 石杰;范淑敏;吴静;康小慧;尹瑜静;王瑞勇.生物法合成纳米金的研究进愿[J].吉首大学学报:自然科学版,2012(3):71-75. |
[2] | 黄闪闪;李忠海;黎继烈;郭筱兵;耿美.纳米金在电化学生物传感器中的应用研究进展[J].化工新型材料,2014(6):219-221. |
[3] | 刘意;刘洁纯;李健乐;张步宁;崔英德.纳米金应用于肿瘤诊疗的研究进展[J].广东药学院学报,2014(3):379-384. |
[4] | 张付强;刘丽;赵一曼.基于功能化金纳米粒子灵敏检测水溶液中的镉离子[J].广州化工,2013(23):53-55,90. |
[5] | 王明月;牛瑞;黄敏;张颖.单层组装纳米金表面结构变化与催化性能调控[J].中国科学(化学),2015(1):76-89. |
[6] | 鲁继青;罗孟飞;辛勤.纳米金催化剂在CO低温氧化和选择性氧化中的研究进展[J].化工进展,2007(3):306-309. |
[7] | 付云芝;张永强.生物合成纳米晶的研究进展[J].中国材料进展,2011(3):47-53. |
[8] | Joy Sarkar;Suman Kalyan Roy;Aparna Laskar;Dipankar Chattopadhyay;Krishnendu Acharya.Bioreduction of chloroaurate ions to gold nanoparticles by culture filtrate of Pleurotus sapidus Quel[J].Materials Letters,2013Feb.1(Feb.1):313-316. |
[9] | Suresh AK;Pelletier DA;Wang W;Broich ML;Moon JW;Gu B;Allison DP;Joy DC;Phelps TJ;Doktycz MJ.Biofabrication of discrete spherical gold nanoparticles using the metal-reducing bacterium Shewanella oneidensis.[J].Acta biomaterialia,20115(5):2148-2152. |
[10] | K. Vijayaraghavan;A. Mahadevan;M. Sathishkumar.Biosynthesis of Au(0) from Au(III) via biosorption and bioreduction using brown marine alga Turbinaria conoides[J].Chemical engineering journal,20111(1):223-227. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%