研究了纯Fe、纯Y、Fe-15Y和Fe-30Y合金在600~800℃高硫压(10-3Pa)-低氧压(10-19Pa于600℃或10-15Pa于700℃和800℃)混合气中的腐蚀行为.Y在600℃和700℃发生加速腐蚀,但在800℃形成的腐蚀膜有保护性.加入Y能够降低合金的腐蚀速率,但在所有条件下,合金都形成FeS最外层膜、由两金属的化合物组成的中间层和由α-Fe和Y的硫氧化物的细微混合物所组成内硫化-氧化区.Fe似以相当高的速率穿过中间层形成FeS外层.在合金/氧化膜界面内侧不产生Y的贫化现象.从Y在Fe
Corrosion of Fe 15Y and Fe 30Y alloys and of pure Fe and Y at 600~800℃ in gas mixtures H 2 H 2S CO 2 has been studied. The gases provided sulfur pressure of 10-3Pa at 600~800℃ plus oxygen pressures 10-19Pa at 600℃ and 10-15Pa at 700~800℃. Yttrium
参考文献
[1] | StringerJ.inHigh-TemperatureOxidationandSulfidationProceses,Ed.EmburyJD.NewYork:PergamonPress,1990,2572NIUYan,GesmundoF,VianiF,etal.Corros.Sci.,1994,36:19733牛焱,RebeloMC,GesmundoF,etal.中国腐蚀与防护学报,1996,16:1074NIUYan,GesmundoF,WUWeitao,ZENGChaoliu,VianiF.ActaMetalurgicaSinica(Englishleter),1996,9:15StrafordKN,WinstanleyGR,HarisonJM.Werkst.Korros.,1974,25:4876NIUYan,GesmundoF,CasteloP,etal.Coros.Sci.1997,39:10937NIUYan,YanRY,WUWeitao,etal.Oxid.Met.,1998,49:918GesmundoF,YoungDJ,RoySK.HighTemp.Mater.Proc.,1989,8:1499RahmelA,SchorM,Velasco-TelezA,etal.Oxid.Met.,1987,27:19910MilsKC.Thermaldynamicdateforinorganicsulfides,selenidesandtelurides,London:Butterworth,197411GesmundoF,VianiF,NIUYan.Oxide.Met.,1994,42:40912MeijeringJL.inAdvancesinMeterialsScience,EdHermanH.NewYork:WileyIntersc.,1971,113YoungDJ,WatsonS.Oxid.Met.,1995,44:23914WagnerC.Z.Elektrochem.,1959,63:77215GesmundoF,VianiF,NIUYan.Oxide.Met.,1997,47:355 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%