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采用电化学阴极渗氢、慢应变速率拉伸试验(SSRT)、定氢仪和扫描电子显微镜(SEM)研究了不同时效状态7050铝合金的氢致开裂行为,并应用自由电子理论计算了氢对铝合金晶界上原子结合力的影响.结果表明:氢在铝合金晶界上发生了偏聚,氢的偏聚增大了晶胞点阵常数,降低了晶界原子的平均结合能和原子间的结合力,从而使合金氢脆敏感性(IHE)增加.时效程度对7050铝合金的IHE有很大的影响.在同一充氢条件下,欠时效状态下的铝合金氢含量最大,氢脆效应也最明显,过时效氢含量最低,氢脆效应最弱,峰时效居中.

参考文献

[1] 刘继华,李荻,刘培英.热处理对7075铝合金应力腐蚀及断口形貌的影响[J].材料热处理学报,2010(07):109-113.
[2] 宋仁国;张金宝;曾梅光 .7175铝合金时效"双峰”应力腐蚀敏感性的研究[J].金属热处理学报,1996,17(02):51-54.
[3] 杜爱华,龙晋明,裴和中.高强铝合金应力腐蚀研究进展[J].中国腐蚀与防护学报,2008(04):251-256.
[4] Li G F;Zhang X M;Li P H et al.Effect of retrogression heating rate on microstructures and mechanical properties of aluminum alloy 7050[J].Transactions of Nonferrous Metals Society of China,2010,20:935-941.
[5] G. Silva;B. Rivolta;R. Gerosa;U. Derudi .Study of the SCC Behavior of 7075 Aluminum Alloy After One-Step Aging at 163℃[J].Journal of Materials Engineering and Performance,2013(1):210-214.
[6] Henry Holoroyd N J;Scamans G M .Stress Corrosion cracking in Al-Zn-Mg-Cu aluminum alloys in saline environment[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,2013,44(03):1230-1253.
[7] Najjar D;Magnin T;Warner T J .Influence of critical surface defects and localized competition between anodic dissolution and hydrogen effects during stress corrosion cracking of a 7050 aluminum alloy[J].Materials Science and Engineering A,1997,238(02):293-302.
[8] Lee S M;Pyun S I;Chun Y G .A critical evaluation of the stress-corrosion cracking mechanism in high-strength aluminum alloys[J].Metallurgical Transactions A,1991,22(10):2407-2414.
[9] Gest R J;Troiano A R .Stress corrosion and hydrogen embrittlement in an aluminum alloy[J].CORROSION,1974,30(08):274-279.
[10] Shuhei Osaki;Hideki Kondo;Katsuyuki Kinoshita .Contribution of Hydrogen Embrittlement to SCC Process in Excess Si Type Al-Mg-Si Alloys[J].Materials transactions,2006(4):1127-1134.
[11] Takano N .Hydrogen diffusion and embrittlement in 7075 aluminum alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(0):336-339.
[12] 褚武扬;乔利杰.断裂与环境断裂[M].北京:科学出版社,2000:148-150.
[13] Pressouyre G M .Trap theory of hydrogen embrittlement[J].ACTA METALLURGICA,1980,28(07):895-911.
[14] Viswanadhan R K;Sun T S;Green J A S .Grain-boundary segregation in Al-Zn-Mg alloys-implications to stress-corrosion cracking[J].Metallurgical Transactions A,1980,11(01):85-89.
[15] Talianker M;Cina B .Retrogression and reaging and the role of dislocations in the stress corrosion of 7000-type aluminum alloy[J].Metallurgical Transactions A,1989,20(10):2087-2092.
[16] 刘继华;李荻;刘蓓英 等.7075铝合金耐腐蚀性与热处理的相关性[J].中国有色金属学报,2002,12:208-211.
[17] 宋仁国;曾梅光 .高强铝合金Mg偏析对晶界结合力和断裂应力的影响[J].东北大学学报,1994,88(15):5-9.
[18] 冯端;王业宁;丘第荣.金属物理[M].北京:科学出版社,1987:46-47.
[19] Doyama M;Koehler J S .Relation between formation energy of a vacancy and nearest neighbor interactions in pure metals and liquid-metals[J].ACTA METALLURGICA,1976,24(09):871-879.
[20] 宋仁国;曾梅光;张宝金 等.7050铝合金晶界偏析与应力腐蚀、疲劳腐蚀行为的研究[J].中国腐蚀与防护学报,1996,16(01):1-8.
[21] Song RG;Blawert C;Dietzel W;Atrens A .A study on stress corrosion cracking and hydrogen embrittlement of AZ31 magnesium alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):308-317.
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