研究了TeO2--Nb2O5--P2O5三元系统的玻璃形成能力和相关理化性能。结果表明, 在TeO2(80%--90%), Nb2O5(0--20%), P2O5(0--20%)(摩尔分数)成分范围内可以形成性能良好的透明玻璃, 碲氧、磷氧和少量的铌氧结构单元共同构建了稳定的链状玻璃网络骨架。TeO2--Nb2O5--P2O5玻璃的转变温度为394--425℃、折射率为1.65--1.88。
The glass forming ability and the properties of TeO2--Nb2O5--P2O5 ternary system were investigated in this paper. It was found that the transparent glasses with good quality can be prepared in the range of TeO2 80\%--90%, Nb2O5 0--20%, P2O5 0--20% (molar fraction). The chain--like glass network was stabilized by constructing with tellurium--oxide, phosphorus--oxide and few niobium--oxide coordination polyhedra. The transition temperature of the TeO2--Nb2O5--P2O5 glasses is from 394 to 425℃, and its refractive index is from 1.65 to 1.88.
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