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回顾了目前关于LiH水解产物及其动力学的研究进展.已有的研究表明,LiH水解产物组成包括Li2O、LiOH和LiOH·H2O,它们由外向里形成LiOH·H2O/LiOH/Li2O/LiH水解层结构.LiH的水解反应普遍存在一种"准线性"动力学行为,并且受到H2O浓度、温度、压力等因素影响."层扩散控制"模型很好地解释了这些现象,但仍然存在一些局限性.

参考文献

[1] Jun Lu;Zhigang Zak Fang;Hong Yong Sohn .A hybrid method for hydrogen storage and generation from water[J].Journal of Power Sources,2007(2):853-858.
[2] Anderson A;Luty F .Raman scattering,defect lumine-scence,and phonon spectra of 7LiH,6LiH and 7LiD crystals[J].Physical Review B:Condensed Matter,1983,28(06):3415.
[3] Hase Y;Yoshida I V P .The Raman active vibrational modes and isotopic effects of four isotopically substituted lithium hydroxides[J].Chemical Physics Letters,1979,65(01):46.
[4] Tyutyunnik V I .Lithium hydroxide monohydrate single crystal:Infrared reflectivity and Raman study[J].Journal of Raman Spectroscopy,2000,31(07):559.
[5] Ishii Y;Nagasaki T;Igawa N et al.Temperature dependence of the Raman spectrum in lithium oxide single crystal[J].Journal of the American Ceramic Society,1991,74(09):2324.
[6] Vidal J P;Vidal-Valat G .Accurate Debye-Waller factors of7LiH and 7LiD by neutron diffraction at three temperatures[J].Acta Crystallographica,1986,B(42):131.
[7] Haertling C;Hanrahan R J;Smith R .A literature review of reactions and kinetics of lithium hydride hydrolysis[J].Journal of Nuclear Materials,2006,349(1-2):195.
[8] Balooch M.;Dinh LN.;Calef DF. .The reaction kinetics of lithium salt with water vapor[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2002(2/3):200-209.
[9] J. Phillips;J. Tanski .Structure and kinetics of formation and decomposition of corrosion layers formed on lithium compounds exposed to atmospheric gases[J].International Materials Reviews,2005(5):265-286.
[10] Holcombe C;Powell G .Some observation on the reaction layer of LiOH on LiH[J].Journal of Nuclear Materials,1973,47(01):121.
[11] Holcombe C E .Retardation of the reaction of lithium hydride with water vapor[Oak Ridge Y-12 Plant Report Y-1835,Oak Ridge Y-12 Plant][R].,1972.
[12] McLaughlin J F;Cristy S S .Composition of corrosion films on lithium hydride surfaces after exposure to air[Oak Ridge Y-12 Plant Report Y-1929][R].Oak Ridge,TN,1974.
[13] Tanski J A .Analysis of a new reaction mechanism for hydrolysis of LiH[LAUR-00-5324][R].Los Alamos National Laboratory,2000.
[14] Cristy S S .SIMS depth profiling of an insulating air-sensitive material[Oak Ridge Y-12 Plant Report Y/DW-725,Oak Ridge Y-12 Plant][R].,1987.
[15] Myers S M .Ion-backscattering study of LiOH-to-Li2O conversion on a LiH substrate[J].Journal of Applied Physics,1974,45:4320.
[16] Dinh LN.;Leckey JH.;Balooch M.;Cecala CM. .The effects of moisture on LiD single crystals studied by temperature-programmed decomposition[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2001(2/3):193-204.
[17] Smyrl N R;Fuller E L;Powell G L .Monitoring the heterogeneous reaction of LiH and LiOH with H2O and CO2 by diffuse reflectance infrared fourier transform spectroscopy[J].Applied Spectroscopy,1983,37(01):38.
[18] Powell G L;Milosevic M;Lucania J .The spectropus system:Remote sampling accessories for reflectance,emission,and transmission analysis using fourier transform infrared spectroscopy[J].Applied Spectroscopy,1992,46(01):111.
[19] Awbery RP;Broughton DA;Tsang SC .In situ observation of lithium hydride hydrolysis by DRIFT spectroscopy[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2008(1/3):94-102.
[20] Dinh LN.;McLean W.;Schildbach MA.;LeMay JD.;Siekhaus WJ.;Balooch M. .The nature and effects of the thermal stability of lithium hydroxide[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2003(2/3):175-188.
[21] Pitcher G K;Kavarnos G J .A test assembly for hydrogen production by the hydrolysis of solid lithium hydride[J].International Journal of Hydrogen Energy,1997,22(06):575.
[22] Carol L. Haertling;Robert J. Hanrahan;Joseph R. Tesmer .Hydrolysis Studies of Polycrystalline Lithium Hydride[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(4):1716-1724.
[23] Bronghton D A .Hydrolysis of lithium hydride[D].Reading:The University of Reading,2001.
[24] Wilson, KV;Patterson, BM;Phillips, J .Microbalance study of the corrosion kinetics of lithium hydride by water[J].Journal of Nuclear Materials,2008(1/2):229-240.
[25] Cecala C M;Shaw S S;Leckey J H .Reaction of lithium hydride with water[Y/DZ-2304,BWXT/Y-12][R].National Security Complex,Oak Ridge,TN,2001.
[26] Kong V C Y;Foulkes F R;Kirk D W et al.Development of hydrogen storage for fuel cell generators.Ⅰ:Hydrogen generation using hydrolysis hydrides[J].International Journal of Hydrogen Energy,1999,24(07):665.
[27] Kong V C Y;Foulkes F R;Dirk D W et al.Development of hydrogen storage for fuel cell generators.Ⅱ:Utilization of calcium hydride and lithium hydride[J].International Journal of Hydrogen Energy,2003,28(02):205.
[28] Leckey J H;Nulf L E;Kirpatrick J R .Reaction of lithium hydride with water[J].Langmuir,1996,12(26):6361.
[29] Ruiming Ren;Angel L.Ortiz;Tippawan Markmaitree;William Osborn;Leon L.Shaw .Stability of Lithium Hydride in Argon and Air[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(21):10567-10575.
[30] Jonathan Phillips;Kennard V. Wilson;Dan Kelly .Generation of a Highly Effective Corrosion Barrier on LiH Surfaces[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(49):19405-19411.
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