欢迎登录材料期刊网

材料期刊网

高级检索

以钛酸纳米管和Cu(NO3)2为前驱体,采用沉积-沉淀法制备CuO修饰TiO2纳米管(CuO/TiO2 NTs).通过TEM(透射电子显微镜)、XRD(X射线衍射)和XPS(X射线光电子能谱)表征材料的结构,并研究制备过程中pH值对所得CuO/TiO2 NTs催化CO氧化活性的影响.研究表明,通过沉积-沉淀法可以制备高活性的CuO/TiO2NTs,随溶液的pH值升高,铜的负载量变少,而且不易被还原的二价铜含量升高,导致催化剂的活性变差.

参考文献

[1] Larsson PO.;Andersson A. .Complete oxidation of CO, ethanol, and ethyl acetate over copper oxide supported on titania and ceria modified titania[J].Journal of Catalysis,1998(1):72-89.
[2] Zheng XC;Wu SH;Wang SP;Wang SR;Zhang SM;Huang WP .The preparation and catalytic behavior of copper-cerium oxide catalysts for low-temperature carbon monoxide oxidation[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):217-223.
[3] Zhou H B;Huang Z;Sun C et al.Catalytic decomposition of N2O over CuxCe1-xOy mixed oxides[J].Applied Catalysis B:Environmental,2012,125:492.
[4] Cao J L;Wang Y;Zhang T Y et al.Preparation,characterization and catalytic behavior of nanostructured mesoporous CuO/Ce0.s Zr0.2O2 catalysts for low-temperature CO oxidation[J].Applied Catalysis B:Environmental,2008,78(1-2):120.
[5] Xu B;Dong L;Chen Y .Influence of CuO loading on dispersion and reduction behavior of CuO/TiO2 (anatase) system[J].Journal of the Chemical Society Faraday Transactions,1998,94(13):1905.
[6] Bond G C;Namijo S N;Wakeman J S .Thermal analysis of catalyst precursors:Part 2.Influence of support and metal precursor on the reducibility of copper catalysts[J].Journal of Molecular Catalysis,1991,64(03):305.
[7] Stangland EE.;Andres RP.;Delgass WN.;Stavens KB. .Characterization of gold-titania catalysts via oxidation of propylene to propylene oxide[J].Journal of Catalysis,2000(2):332-347.
[8] Chary KVR;Sagar GV;Naresh D;Seela KK;Sridhar B .Characterization and reactivity of copper oxide catalysts supported on TiO2-ZrO2[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(19):9437-9444.
[9] Haruta M;Ueda A;Tsubota S et al.Low-temperature catalytic combustion of methanol and its decomposed derivatives over supported gold catalysts[J].Catalysis Today,1996,29(1-4):443.
[10] Xi Liu;Thomas F. Jaramillo;Andrei Kolmakov .Synthesis of Au nanoclusters supported upon a TiO_2 nanotube array[J].Journal of Materials Research,2005(5):1093-1096.
[11] Zhu Baolin;Guo Qi;Huang Xueliang et al.Characterization and catalytic performance of TiO2 nanotubes-supported gold and copper particles[J].Journal of Molecular Catalysis A:Chemical,2006,249(1-2):211.
[12] Zhu B L;Zhang X X;Wang S R et al.Synthesis and catalytic performance of TiO2 nanotubes-supported copper oxide for low-temperature CO oxidation[J].Microporous and Mesoporous Materials,2007,102(1-3):333.
[13] Sun X M;Li Y D .Synthesis and characterization of ion-exchangeable titanate nanotubes[J].Chemistry-A European Journal,2003,9(10):2229.
[14] Francisco M S P;Mastelaro V R;Nascente P A P et al.Activity and characterization by XPS,HR-TEM,Raman spectroscopy,and BET surface area of CuO/CeO2-TiO2 catalysts[J].Journal of Physical Chemistry B,2001,105(43):10515.
[15] Melian-Cabrera I.;Granados ML.;Fierro JLG. .Bulk and surface structures of palladium-modified copper-zinc oxides ex hydroxycarbonate precursors[J].Chemistry of Materials,2002(4):1863-1872.
[16] Chusuei C C;Brookshier M A;Goodman D W .Correlation of relative X-ray photoelectron spectroscopy shake-up intensity with CuO particle size[J].LANGMUIR,1999,15(08):2806.
[17] Chary K V R;Seela K K;Sagar G V et al.Characterization and reactivity of niobia supported copper oxide catalysts[J].Journal of Physical Chemistry B,2004,108(02):658.
[18] Liu Z;Amiridis MD;Chen Y .Characterization of CuO supported on tetragonal ZrO2 catalysts for N2O decomposition to N-2[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(3):1251-1255.
[19] Huang T J;Tsai D H .CO oxidation behavior of copper and copper oxides[J].Catalysis Letters,2003,87(3-4):173.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%