通过介绍自组装软模板法制备有序中孔炭的发展历程和基本原理,说明该方法具有操作简单、成本低、易于控制等优点.重点评述了自组装软模板法制备有序中孔炭在产物形貌控制和多级孔结构制备方面的研究进展,分析认为,今后的研究可以在拓展前驱体范围、提高宏观产物柔韧性以及导电性等方面得到进一步发展.
参考文献
| [1] | Chengdu Liang;Zuojiang Li;Sheng Dai .Mesoporous Carbon Materials: Synthesis and Modification[J].Angewandte Chemie,2008(20):3696-3717. |
| [2] | Wan Y;Sho Y;Zhao D .Supramolecular aggregates as templates: Ordered mesoporous polymers and carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):932-945. |
| [3] | 传秀云,周述慧.模板法合成中孔炭材料[J].新型炭材料,2011(02):151-160. |
| [4] | 刘蕾,袁忠勇.介孔碳材料的研究进展[J].中国科技论文在线,2011(03):161-175. |
| [5] | Ryoo R;Joo S H;Jun S .Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation[J].Journal of Physical Chemistry B,1999,103(37):7743-7746. |
| [6] | Lee Jinwoo;Yoon Songhun .Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors[J].Chemical communications,1999(21):2177-2178. |
| [7] | Seong-Su Kim;Dong-Keun Lee;Jainisha Shah;Thomas J. Pinnavaia .Nanocasting of carbon nanotubes: in-situ graphitization of a low-cost mesostructured silica templated by non-ionic surfactant micelles[J].Chemical communications,2003(12):1436-1437. |
| [8] | Kim J;Lee J;Hyeon T .Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(12/12):2711-2719. |
| [9] | X. Liu;F. Chang;L. Xu .Synthesis and characterization of a new nanoporous carbon material with a bimodal pore system[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(1):184-190. |
| [10] | 宋怀河,李丽霞,陈晓红.有序介孔炭的模板合成进展[J].新型炭材料,2006(04):374-383. |
| [11] | 李娜,王先友,易四勇,戴春岭.模板法制备中孔碳材料[J].化学进展,2008(07):1202-1207. |
| [12] | Kosonen H.;Ruokolainen J.;Torkkeli M.;Serimaa R.;Nyholm P.;Ikkala O. .Micro- and macrophase separation in phenolic resol resin/PEO-PPO-PEO block copolymer blends: Effect of hydrogen-bonded PEO length[J].Macromolecular chemistry and physics,2002(2):388-392. |
| [13] | Harri Kosonen;Janne Ruokolainen;Per Nyholm;Olili Ikkala .Self-organized cross-linked phenolic thermosets: thermal and dynamic mechanical properties of novolac/block copolymer blends[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(23):9481-9486. |
| [14] | Kosonen H.;Nyholm P.;Ikkala O.;Ruokolainen J. .Self-organized thermosets: Blends of hexamethyltetramine cured novolac with poly(2-vinylpyridine)-block-poly(isoprene)[J].Macromolecules,2001(9):3046-3049. |
| [15] | Chengdu Liang;Kunlun Hong;Jimmy W.Ma .Synthesis of a Large-Scale Highly Ordered Porous Carbon Film by Self-Assembly of Block Copolymers[J].Angewandte Chemie,2004(43):5785-5789. |
| [16] | Shunsuke Tanaka;Norikazu Nishiyama;Yasuyuki Egashira;Korekazu Ueyama .Synthesis of ordered mesoporous carbons with channel structure from an organic-organic nanocomposite[J].Chemical communications,2005(16):2125-2127. |
| [17] | Yan Meng;Dong Gu;Fuqiang Zhang;Yifeng Shi;Haifeng Yang;Zheng Li;Chengzhong Yu;Bo Tu;Dongyuan Zhao .Ordered Mesoporous Polymers and Homologous Carbon Frameworks:Amphiphilic Surfactant Templating and Direct Transformation[J].Angewandte Chemie,2005(43):7053-7059. |
| [18] | Meng Y;Gu D;Zhang FQ;Shi YF;Cheng L;Feng D;Wu ZX;Chen ZX;Wan Y;Stein A .A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(18):4447-4464. |
| [19] | Wang XQ;Liang CD;Dai S .Facile synthesis of ordered mesoporous carbons with high thermal stability by self-assembly of resorcinol-formaldehyde and block copolymers under highly acidic conditions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(14):7500-7505. |
| [20] | An alternative method to remove PEO-PPO-PEO template in organic-inorganic mesoporous nanocomposites by sulfuric acid extraction[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(17):5343. |
| [21] | Fujian Liu;Caijin Li;Limin Ren .High-temperature synthesis oi stable and ordered mesoporous polymer monoliths with low dielectric constants[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(42):7921-7928. |
| [22] | Harri Kosonen;Sami Valkama;Antti Nykaenen;Miika Toivanen;Gerrit ten Brinke;Janne Ruokolainen;Olli Ikkala .Functional Porous Structures Based on the Pyrolysis of Cured Templates of Block Copolymer and Phenolic Resin[J].Advanced Materials,2006(2):201-205. |
| [23] | Valkama S;Nykanen A;Kosonen H;Ramani R;Tuomisto F;Engelhardt P;ten Brinke G;Ikkala O;Ruokolainen J .Hierarchical porosity in self-assemhled polymers: Post-modification of block copolymer-phenolic resin complexes hy pyrolysis allows the control of micro- and mesoporosity[J].Advanced functional materials,2007(2):183-190. |
| [24] | Adrian T.Rodriguez;Min Chen;Zhu Chen .Nanoporous Carbon Nanotubes Synthesized through Confined Hydrogen-Bonding Self-Assembly[J].Journal of the American Chemical Society,2006(29):9276-9277. |
| [25] | Deng YH;Yu T;Wan Y;Shi YF;Meng Y;Gu D;Zhang LJ;Huang Y;Liu C;Wu XJ .Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene[J].Journal of the American Chemical Society,2007(6):1690-1697. |
| [26] | Yonghui Deng;Jia Liu;Chong Liu .Ultra-Large-Pore Mesoporous Carbons Templated from Poly(ethylene oxide)-b-Polystyrene Diblock Copolymer by Adding Polystyrene Homopolymer as a Pore Expander[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(23):7281-7286. |
| [27] | Junyong Zhang;Yonghui Deng;Jing Wei .Design of Amphiphilic ABC Triblock Copolymer for TemplatingSynthesis of Large-Pore Ordered Mesoporous Carbons with TunablePore Wall Thickness[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(17):3996-4005. |
| [28] | Deng Y;Liu C;Gu D;Yu T;Tu B;Zhao D .Thick wall mesoporous carbons with a large pore structure templated from a weakly hydrophobic PEO-PMMA diblock copolymer[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(1):91-97. |
| [29] | Chengdu Liang;Sheng Dai .Synthesis of Mesoporous Carbon Materials via Enhanced Hydrogen-Bonding Interaction[J].Journal of the American Chemical Society,2006(16):5316-5317. |
| [30] | Wu, Zhangxiong;Webley, Paul A.;Zhao, Dongyuan .Comprehensive Study of Pore Evolution, Mesostructural Stability, and Simultaneous Surface Functionalization of Ordered Mesoporous Carbon (FDU-15) by Wet Oxidation as a Promising Adsorbent[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(12):10277-10286. |
| [31] | Zhang FQ;Meng Y;Gu D;Yan Y;Chen ZX;Tu B;Zhao DY .An aqueous cooperative assembly route to synthesize ordered mesoporous carbons with controlled structures and morphology[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(22):5279-5288. |
| [32] | Fuqiang Zhang;Yan Meng;Dong Gu;Yan Yan;Chengzhong Yu;Bo Tu;Dongyuan Zhao .A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Ia3d Bicontinuous Cubic Structure[J].Journal of the American Chemical Society,2005(39):13508-13509. |
| [33] | Liu CY;Li LX;Song HH;Chen XH .Facile synthesis of ordered mesoporous carbons from F108/resorcinol-formaldehyde composites obtained in basic media[J].Chemical communications,2007(7):757-759. |
| [34] | Jin Jin;Norikazu Nishiyama;Yasuyuki Egashira .Pore structure and pore size controls of ordered mesoporous carbons prepared from resorcinol/formaldehyde/triblock polymers[J].Microporous and Mesoporous Materials,2009(1/3):218-223. |
| [35] | 张雅心,张学军.模板剂对介孔碳孔道结构及有序性的影响[J].北京化工大学学报（自然科学版）,2010(05):83-87. |
| [36] | Huang Y;Cai H Q;Yu T et al.Formation of mesoporous carbon with a face-centered-cubic fd (3)over-barm structure and bimodal architectural pores from the reverse amphiphilic triblock copolymer ppo-peo-ppo[J].Angewandte Chemie International Edition,2007,46(07):1089-1093. |
| [37] | Yan Huang;Huaqiang Cai;Ting Yu .Highly Ordered Mesoporous Carbonaceous Frameworks from a Template of a Mixed Amphiphilic Triblock-Copolymer System of PEO-PPO-PEO and Reverse PPO-PEO-PPO[J].Chemistry, an Asian journal,2007(10):1282-1289. |
| [38] | Mingxian Liu;Lihua Gan;Ci Tian .Mesoporous carbon foams through surfactant templating[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(15):3045-3046. |
| [39] | Mingjiang Xie;Houhuan Dong;Dongdong Zhang .Simple synthesis of highly ordered mesoporous carbon by self-assembly of phenol-formaldehyde and block copolymers under designed aqueous basic/acidic conditions[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(7):2459-2464. |
| [40] | Kataoka, S;Yamamoto, T;Endo, A;Nakaiwa, M;Ohmori, T .Synthesis and characterization of mesoporous carbon thin films from phloroglucinol/surfactant self-assembly[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2009(1/3):142-145. |
| [41] | Lei Liu;Feng-Yun Wang;Gao-Song Shao .Synthesis of ultra-large mesoporous carbons from triblock copolymers and phloroglucinol/formaldehyde polymer[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(9):2660-2664. |
| [42] | Meng Y;Gu D;Zhang FQ;Shi YF;Cheng L;Feng D;Wu ZX;Chen ZX;Wan Y;Stein A .A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(18):4447-4464. |
| [43] | Yan Meng;Dong Gu;Fuqiang Zhang;Yifeng Shi;Haifeng Yang;Zheng Li;Chengzhong Yu;Bo Tu;Dongyuan Zhao .Ordered Mesoporous Polymers and Homologous Carbon Frameworks:Amphiphilic Surfactant Templating and Direct Transformation[J].Angewandte Chemie,2005(43):7053-7059. |
| [44] | Fuqiang Zhang;Yan Meng;Dong Gu;Yan Yan;Chengzhong Yu;Bo Tu;Dongyuan Zhao .A Facile Aqueous Route to Synthesize Highly Ordered Mesoporous Polymers and Carbon Frameworks with Ia3d Bicontinuous Cubic Structure[J].Journal of the American Chemical Society,2005(39):13508-13509. |
| [45] | Wang XQ;Liang CD;Dai S .Facile synthesis of ordered mesoporous carbons with high thermal stability by self-assembly of resorcinol-formaldehyde and block copolymers under highly acidic conditions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(14):7500-7505. |
| [46] | An-Hui Lu;Bemd Spliethoff;Ferdi Schtith .Aqueous Synthesis of Ordered Mesoporous Carbon via Self-Assembly Catalyzed by Amino Acid[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(16):5314-5319. |
| [47] | Richard T. Mayes;Costas Tsouris;James O. Kiggans Jr. .Hierarchical ordered mesoporous carbon from phloroglucinol-glyoxal and its application in capacitive deionization of brackish water[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(39):8674-8678. |
| [48] | Donghui Long;Wenming Qiao;Liang Zhan .Effect of template and precursor chemistry on pore architectures of triblock copolymer-templated mesoporous carbons[J].Microporous and Mesoporous Materials,2009(1/3):58-66. |
| [49] | Guang-Ping Hao;Wen-Cui Li;Shuai Wang .Lysine-assisted rapid synthesis of crack-free hierarchical carbon monoliths with a hexagonal array of mesopores[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(12):3762-3772. |
| [50] | Hao, G.-P.;Li, W.-C.;Qian, D.;Wang, G.-H.;Zhang, W.-P.;Zhang, T.;Wang, A.-Q.;Schüth, F.;Bongard, H.-J.;Lu, A.-H. .Structurally designed synthesis of mechanically stable poly(benzoxazine-co- resol)-based porous carbon monoliths and their application as high-performance CO_2 capture sorbents[J].Journal of the American Chemical Society,2011(29):11378-11388. |
| [51] | Fidelis Hubertson Simanjuntak;Jin Jin;Norikazu Nishiyama .Ordered mesoporous carbon films prepared from 1,5- dihydroxynaphthalene/triblock copolymer composites[J].Carbon,2009(10):2531-2533. |
| [52] | Jin J;Nishiyama N;Egashira Y.Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a softtemplating method[J].Chemical Communications,2009(11):1371-1373. |
| [53] | Jin, J.;Mitome, T.;Egashira, Y.;Nishiyama, N. .Phase control of ordered mesoporous carbon synthesized by a soft-templating method[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2011(1/3):58-61. |
| [54] | Xufang Qian;Hexing Li;Ying Wan .Structure design of mesoporous carbons by blending PEO-PPO-PEO-type and PPO-PEO-PPO-type amphiphilic block copolymers in organic-organic self-assembly[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2011(1/3):26-37. |
| [55] | Antti Soininen;Sami Valkama;Antti Nykanen .Functional Carbon Nanoflakes with High Aspect Ratio by Pyrolysis of Cured Templates of Block Copolymer and Phenolic Resin[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(13):3093-3095. |
| [56] | Dong Gu;Hans Bongard;Yonghui Deng;Dan Feng;Zhangxiong Wu;Yin Fang;Jianjiang Mao;Bo Tu;Ferdi Schueth;Dongyuan Zhao .An Aqueous Emulsion Route to Synthesize Mesoporous Carbon Vesicles and Their Nanocomposites[J].Advanced Materials,2010(7):833-837. |
| [57] | Dan Liu;Jia-Heng Lei;Li-Ping Guo .Simple hydrothermal synthesis of ordered mesoporous carbons from resorcinol and hexamine[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(6):2113-2119. |
| [58] | Joanna Gorka;Mietek Taroniec .Tailoring Adsorption and Framework Properties of Mesoporous Polymeric Composites and Carbons by Addition of Organosilanes during Soft-Templating Synthesis[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(14):6298-6303. |
| [59] | Song L Y;Feng D;Lee H J et al.Stabilizing surfactant ternplated cylindrical mesopores in polymer and carbon films through composite formation with silica reinforcement[J].Journal of Physical Chemistry C,2010,114(21):9618-9626. |
| [60] | Gorka, J;Fenning, C;Jaroniec, M .Influence of temperature, carbon precursor/copolymer ratio and acid concentration on adsorption and structural properties of mesoporous carbons prepared by soft-templating[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2009(1/3):113-117. |
| [61] | Sho Kataoka;Takuji Yamamoto;Yuki Inagi .Synthesis of ordered mesoporous carbon thin films at various temperatures in vapor infiltration method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(10):1358-1360. |
| [62] | Xiqing Wang;Qing Zhu;Shannon M. Mahurin .Preparation of free-standing high quality mesoporous carbon membranes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(2):557-560. |
| [63] | 魏国丽,张学军.中孔碳孔径及有序性影响因素[J].过程工程学报,2009(01):181-185. |
| [64] | Wang ZY;Li F;Stein A .Direct synthesis of shaped carbon nanoparticles with ordered cubic mesostructure[J].Nano letters,2007(10):3223-3226. |
| [65] | Shunsuke Tanaka;Yugo Katayama;Michael P.Tate .Fabrication of continuous mesoporous carbon films with face-centered orthorhombic symmetry through a soft templating pathway[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(34):3639-3645. |
| [66] | Gu D;Bongard H;Meng Y et al.Growth of single-crystal mesoporous carbons with im (3) over-barm symmetry[J].Chemistry of Materials,2010,22(16):4828-4833. |
| [67] | Zhang FQ;Gu D;Yu T;Zhang F;Xie SH;Zhang LJ;Deng YH;Wan Y;Tu B;Zhao DY .Mesoporous carbon single-crystals from organic-organic self-assembly[J].Journal of the American Chemical Society,2007(25):7746-7747. |
| [68] | Yin Fang;Dong Gu;Ying Zou .A Low-Concentration Hydrothermal Synthesis of Biocompatible Ordered Mesoporous Carbon Nanospheres with Tunable and Uniform Size[J].Angewandte Chemie,2010(43):7987-7991. |
| [69] | Yan Yan;Fuqiang Zhang;Yan Meng;Bo Tu;Dongyuan Zhao .One-step synthesis of ordered mesoporous carbonaceous spheres by an aerosol-assisted self-assembly[J].Chemical communications,2007(27):2867-2869. |
| [70] | Long DH;Lu F;Zhang R;Qiao WM;Zhan L;Liang XY;Ling LC .Suspension assisted synthesis of triblock copolymer-templated ordered mesoporous carbon spheres with controlled particle size[J].Chemical communications,2008(23):2647-2649. |
| [71] | Takuji Yamamoto;Akira Endo;Apiluck Eiad-ua .Synthesis of Monodisperse Carbon Beads with Developed Mesoporosity[J].AIChE Journal,2007(3):746-749. |
| [72] | Jintawat Chaichanawong;Takuji Yamamoto;Sho Kataoka .Synthesis of monodisperse carbonaceous beads with ordered mesoporous structure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(3):929-932. |
| [73] | Fan Li;Zhiyong Wang;Andreas Stein .Shaping Mesoporous Silica Nanoparticles by Disassembly of Hierarchically Porous Structures[J].Angewandte Chemie,2007(11):1885-1888. |
| [74] | Wang ZY;Stein A .Morphology control of carbon, silica, and carbon/silica nanocomposites: From 3D ordered Macro-/Mesoporous monoliths to shaped mesoporous particles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):1029-1040. |
| [75] | Jorg Schuster;Ralf Kohn;Andreas Keilbach .Two-Dimensional-Hexagonal Periodic Mesoporous Polymer Resin Thin Films by Soft Templating[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(24):5754-5762. |
| [76] | Rachel A. Segalman .Patterning with block copolymer thin films[J].Materials Science & Engineering, R. Reports: A Review Journal,2005(6):191-226. |
| [77] | Song, L.;Feng, D.;Fredin, N.J.;Yager, K.G.;Jones, R.L.;Wu, Q.;Zhao, D.;Vogt, B.D. .Challenges in fabrication of mesoporous carbon films with ordered cylindrical pores via phenolic oligomer self-assembly with triblock copolymers[J].ACS nano,2010(1):189-198. |
| [78] | Tanaka S;Nishiyama N;Hayashi Y;Egashira Y;Ueyama K .Ultrathin silica films with a nanoporous monolayer[J].Chemistry Letters,2004(11):1408-1409. |
| [79] | Koganti VR;Dunphy D;Gowrishankar V;McGehee MD;Li XF;Wang J;Rankin SE .Generalized coating route to silica and titania films with orthogonally tilted cylindrical nanopore arrays[J].Nano letters,2006(11):2567-2570. |
| [80] | Chia-Hung Hou;Xiqing Wang;Chengdu Liang .Molecular-Sieving Capabilities of Mesoporous Carbon Membranes[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2008(29):8563-8570. |
| [81] | Shunsuke Tanaka;Anna Doi;Norihito Nakatani .Synthesis of ordered mesoporous carbon films, powders, and fibers by direct triblock-copolymer-templating method using an ethanol/water system[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(11):2688-2698. |
| [82] | Shunsuke Tanaka;Norihito Ndkatani;Anna Doi .Preparation of ordered mesoporous carbon membranes by a soft-templating method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(10):3184-3189. |
| [83] | Martin Steinhart;Chengdu Liang;Gary W. Lynn .Direct Synthesis of Mesoporous Carbon Microwires and Nanowires[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(10):2383-2385. |
| [84] | Kaixue Wang;Wenhua Zhang;Richard Phelan .Direct Fabrication of Well-Aligned Free-Standing Mesoporous Carbon Nanofiber Arrays on Silicon Substrates[J].Journal of the American Chemical Society,2007(44):13388-13389. |
| [85] | Kaixue Wang;Pavels Birjukovs;Donats Erts .Synthesis and characterisation of ordered arrays of mesoporous carbon nanofibres[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(9):1331-1338. |
| [86] | Rong Kou;Qingyuan Hu;Donghai Wang;Vijay T. John;Zhenzhong Yang;Yunfeng Lu .Direct synthesis of ordered mesoporous polymer/carbon nanofilaments with controlled mesostructures[J].Journal of porous materials,2009(3):315-319. |
| [87] | Mingbo Zheng;Jieming Cao;Xingfei Ke .One-step synthesis of new mesoporous carbon nanofibers through an easy template method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(5):1111-1113. |
| [88] | Schuster, J.;Keilbach, A.;K?hn, R.;D?blinger, M.;D?rfler, T.;Dennenwaldt, T.;Bein, T. .Cubic and hexagonal mesoporous carbon in the pores of anodic alumina membranes[J].Chemistry: A European journal,2011(34):9463-9470. |
| [89] | Haijing Liu;Ling-Hua Jin;Ping He;Congxiao Wang;Yongyao Xia .Direct synthesis of mesoporous carbon nanowires in nanotubes using MnO2 nanotubes as a template and their application in supercapacitors[J].Chemical communications,2009(44):6813-6815. |
| [90] | Hai-Jing Liu;Xiao-Ming Wang;Wang-Jun Cui .Highly ordered mesoporous carbon nanofiber arrays from a crab shell biological template and its application in supercapacitors and fuel cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(20):4223-4230. |
| [91] | Kaixue Wang;Yonggang Wang;Yarong Wang .Mesoporous Carbon Nanofibers for Supercapacitor Application[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(3):1093-1097. |
| [92] | 杨桦,孙德慧,任慧娟,崔振峰.介孔碳纳米纤维为载体的铂催化剂的制备及电化学性质[J].高等学校化学学报,2011(08):1876-1880. |
| [93] | Lei Liu;Feng-Yun Wang;Gao-Song Shao .A low-temperature autoclaving route to synthesize monolithic carbon materials with an ordered mesostructure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):2089-2099. |
| [94] | Huang Y;Cai HQ;Feng D;Gu D;Deng YH;Tu B;Wang HT;Webley PA;Zhao DY .One-step hydrothermal synthesis of ordered mesostructured carbonaceous monoliths with hierarchical porosities[J].Chemical communications,2008(23):2641-2643. |
| [95] | Xue C F;Tu B;Zhao D Y .Facile fabrication of hierarchically porous carbonaceous monoliths with ordered mesostructure via an organic-organic self-assembly[J].Nano Res,2009,2(03):242-253. |
| [96] | Qian, X.-F.;Wang, Z.;Wan, Y. .From polymeric "plasticine" to shape-controlled mesoporous carbon[J].Journal of Colloid and Interface Science,2009(2):222-227. |
| [97] | Lee J;Kim J;Hyeon T .Recent progress in the synthesis of porous carbon materials[J].Advanced Materials,2006(16):2073-2094. |
| [98] | Jinwoo Lee;Jaeyun Kim;Taeghwan Hyeon .Synthesis of new nanostructured carbon materials using silica nanostructured templates by Korean research groups[J].International Journal of Nanotechnology,2006(2/3):253-279. |
| [99] | Jerzy Choma;Joanna Gorka;Mietek Jaroniec .Development of Microporosity in Mesoporous Carbons[J].Topics in Catalysis,2010(3/4):283-290. |
| [100] | Zakhidov AA;Baughman R H;Iqbal Z et al.Carbon structures with three-dimensional periodicity at optical wavelengths[J].Science,1998,282(5390):897-901. |
| [101] | Holland B T;Blanford C F;Stein A .Synthesis of macroporous minerals with highly ordered three-dimensional arrays of spheroidal voids[J].Science,1998,281(5376):538-540. |
| [102] | Lukens WW.;Stucky GD. .Synthesis of mesoporous carbon foams templated by organic colloids[J].Chemistry of Materials,2002(4):1665-1670. |
| [103] | Lee KT;Lytle JC;Ergang NS;Oh SM;Stein A .Synthesis and rate performance of monolithic macroporous carbon electrodes for lithium-ion secondary batteries[J].Advanced functional materials,2005(4):547-556. |
| [104] | Yonghui Deng;Chong Liu;Ting Yu .Facile Synthesis of Hierarchically Porous Carbons from Dual Colloidal Crystal/Block Copolymer Template Approach[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(13):3271-3277. |
| [105] | 周颖,王志超,王春雷,王六平,许钦一,邱介山.大孔-介孔分级孔结构炭材料制备及性能研究[J].无机材料学报,2011(02):145-148. |
| [106] | Wang ZY;Kiesel ER;Stein A .Silica-free syntheses of hierarchically ordered macroporous polymer and carbon monoliths with controllable mesoporosity[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(19):2194-2200. |
| [107] | Chun-hsien Huang;Ruey-an Doong;Dong Gu .Dual-template synthesis of magnetically-separable hierarchically-ordered porous carbons by catalytic graphitization[J].Carbon: An International Journal Sponsored by the American Carbon Society,2011(9):3055-3064. |
| [108] | Yan Yan;Jing Wei;Fuqiang Zhang .The pore structure evolution and stability of mesoporous carbon FDU-15 under CO2, O2 or water vapor atmospheres[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2008(1/3):305-314. |
| [109] | Wu D;Liang Y;Yang XQ;Zou C;Li ZH;Lv GF;Zeng XH;Fu R .Preparation of activated ordered mesoporous carbons with a channel structure[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(7):2967-2969. |
| [110] | W. Xing;C.C. Huang;S.P. Zhuo .Hierarchical porous carbons with high performance for supercapacitor electrodes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(7):1715-1722. |
| [111] | Xiqing Wang;Je Seung Lee;Costas Tsouris .Preparation of activated mesoporous carbons for electrosorption of ions from aqueous solutions[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(22):4602-4608. |
| [112] | Joanna Gorka;Aleksandra Zawislak;Jerzy Choma .KOH activation of mesoporous carbons obtained by soft-templating[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(8):1159-1161. |
| [113] | Jin Jin;Shunsuke Tanaka;Yasuyuki Egashira .KOH activation of ordered mesoporous carbons prepared by a soft-templating method and their enhanced electrochemical properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):1985-1989. |
| [114] | Ruili Liu;Yifeng Shi;Ying Wan .Triconstituent Co-assembly to Ordered Mesostructured Polymer-Silica and Carbon-Silica Nanocomposites and Large-Pore Mesoporous Carbons with High Surface Areas[J].Journal of the American Chemical Society,2006(35):11652-11662. |
| [115] | Bo You,Jun Yang,Guo-ping Yong,Shao-min Liu,Wei Xie,Qing-de Su.Influence of Preparation Conditions on Structural Stability of Ordered Mesoporous Carbons Synthesized by Evaporation-induced Triconstituent Co-assembly Method[J].化学物理学报,2011(03):365-372. |
| [116] | Mictek Jaroniec;Joanna Gorka;Jerzy Choma .Synthesis and properties of mesoporous carbons with high loadings of inorganic species[J].Carbon,2009(13):3034-3040. |
| [117] | Jinwoo Lee;Jaeyun Kim;Youjin Lee;Songhun Yoon;Seung M.Oh;Taeghwan Hyeon .Simple Synthesis of Uniform Mesoporous Carbons with Diverse Structures from Mesostructured Polymer/Silica Nanocomposites[J].Chemistry of Materials,2004(17):3323-3330. |
| [118] | Lin, HP;Chang-Chien, CY;Tang, CY;Lin, CY .Synthesis of p6mm hexagonal mesoporous carbons and silicas using Pluronic F127-PF resin polymer blends[J].Microporous and Mesoporous Materials,2006(1/3):344-348. |
| [119] | Mingzhi Dai;Lingyan Song;Jeffrey T. LaBelle .Ordered Mesoporous Carbon Composite Films Containing Cobalt Oxide and Vanadia for Electrochemical Applications[J].Chemistry of Materials: A Publication of the American Chemistry Society,2011(11):2869-2878. |
| [120] | Wan Y;Qian X;Jia NQ;Wang ZY;Li HX;Zhao DY .Direct triblock-copolymer-templating synthesis of highly ordered fluorinated mesoporous carbon[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):1012-1018. |
| [121] | Yu, T;Deng, YH;Wang, L;Liu, RL;Zhang, LJ;Tu, B;Zhao, DY .Ordered mesoporous nanocrystalline titanium-carbide/carbon composites from in situ carbothermal reduction[J].Advanced Materials,2007(17):2301-2306. |
| [122] | Yaokang Lv;Mmgxian Liu;Lihua Gan .Synthesis of Sodium-vanadate-doped Ordered Mesoporous Carbon Foams as Capacitor Electrode Materials[J].Chemistry Letters,2011(3):236-238. |
| [123] | Jingyuan Yao;Lixia Li;Huaihe Song .Synthesis of magnetically separable ordered mesoporous carbons from F127/[Ni(H2O)6](NO3)2/resorcinol-formaldehyde composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(2):436-444. |
| [124] | Shinji IMAIZUMI .Phenolic Resin-Based Carbon Thin Fibers Prepared by Electrospinning:Additive Effects of Poly(vinyl butyral) and Electrolytes[J].Polymer Journal,2009(12):1124-1128. |
| [125] | Kenichi SUZUKI;Hidetoshi MATSUMOTO;Mie MlNAGAWA .Preparation of Carbon Fiber Fabrics from Phenolic Resin by Electrospray Deposition[J].Polymer Journal,2007(11):1128-1134. |
| [126] | Ming-Xi Wang;Zheng-Hong Huang;Feiyu Kang;Kaiming Liang .Porous carbon nanofibers with narrow pore size distribution from electrospun phenolic resins[J].Materials Letters,2011(12):1875-1877. |
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