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在微波场作用下,首次合成了蓝色长余辉发光材料Sr2Al6O11: Eu2+, Er3+,利用XRD对其进行晶相分析,用荧光光度计测其激发光谱和发射光谱及余辉衰减曲线,利用热释光剂量仪测定其热释光谱.结果表明:该产品为正交晶系,Pnnm空间群,a= 2.191 827 nm,b=0.840 857 nm,c=0.488 175 nm,该产品激发和发射谱均为宽带谱,在270和340 nm处有2个主激发峰,主发射峰位于460 nm,Sr2Al6O11: Eu2+,Er3+的发光余辉可持续14 h以上,Sr2Al6O11: Eu2+,Er3+中存在2个热释峰,一个位于49.1 ℃,另一个位于140 ℃左右.2个陷阱能级分别为0.585 eV和0.806 eV.

参考文献

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