采用电子束蒸发法,以高纯CdS块料为膜料在玻璃基底上制备了CdS薄膜,设计了L9(34)正交实验,研究了各工艺参数对薄膜光电性能的影响.结果表明,随着基底温度,蒸发速率的提高,薄膜的电阻值呈降低趋势达到最小值后稍有升高;薄膜的阻值随真空度的降低而降低,达到一定程度后阻值基本保持不变.薄膜的暗亮电阻比即光敏性,随基底温度的增大先增大达到最大值后开始减小;而随蒸发速率的提高光敏性先缓后急的增加;真空度对光敏性的影响与蒸发速率对光敏性的影响正好相反,表现为随真空度的增加光敏性先急后缓的降低.正交实验表明:当基底温度为150℃,蒸发速率为1 nm·s-1,真空度为3×10-3 Pa时,薄膜的光电性能最好.CdS薄膜的光敏性达到7.7×102,其中亮电阻的最小值为1350Ω/□.
参考文献
[1] | Krishnan, S;Sanjeev, G;Pattabi, M;Mathew, X .Effect of electron irradiation on the properties of CdTe/CdS solar cells[J].Solar Energy Materials and Solar Cells,2009(1):2-5. |
[2] | 焦静,沈鸿烈,王威,江丰.化学浴法制备CdS薄膜及其光电性能研究[J].人工晶体学报,2013(07):1299-1304. |
[3] | 王智平,赵静,王克振.化学沉积参数对CdS薄膜前驱物利用率的影响[J].功能材料与器件学报,2012(01):75-81. |
[4] | Bagdare, PB;Patil, SB;Singh, AK .Phase evolution and PEC performance of Zn_xCd_(1-x)S nanocrystalline thin films deposited by CBD[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):120-124. |
[5] | S.Thanikaikarasan;T. Mahalingam;Soonil Lee .Electrosynthesis and studies on Cadmium-Iron-Sulphide thin films[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2010(1/3):231-235. |
[6] | 黄帅,李晨辉,孙宜华,柯文明.基底温度对直流溅射Nb掺杂TiO2薄膜性能的影响[J].无机材料学报,2012(01):64-68. |
[7] | 罗坚义,周洋洋,陈润明,曾庆光,张梅.高质量WO3薄膜的制备及其电致变色数码显示器件[J].人工晶体学报,2013(01):124-128. |
[8] | 乔琦,季静佳,张光春,施正荣,李果华.用真空蒸镀法制备Al背场的研究[J].太阳能学报,2008(05):555-559. |
[9] | Senthil K.;Narayandass SK.;Mangalaraj D. .Structural and optical properties of CdS thin films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(0):476-479. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%