Al_2O_3气凝胶以其独特性质受到人们的广泛关注.本文就Al_2O_3气凝胶的结构、性质和制备方法进行了综述,制备方法包括铝醇盐的一步法、两步法和无机铝盐的滴加环氧丙烷法,其中滴加环氧丙烷法是制备高性能Al_2O_3气凝胶非常有发展潜力的方法之一.同时还介绍了纤维增强气凝胶、多组分及掺杂改性气凝胶.
Alumina aerogel had been paid great attention for its unique properties. The structure and various preparation methods of alumina aerogels had been summarized in this paper. The preparation methods included alumina alkoxide one step,two steps method and addition of propylene oxide method. The addition of propylene oxide method is one of the most potential route for the synthesis of high performance alumina aerogels. Fiber-reinforced, multiple cornponent and doped aerogels were also introduced.
参考文献
| [1] | Gesser H D;Goswami P C .Aerogels and related porous materials[J].Chemical Reviews,1989,89:765-788. |
| [2] | Kister S S .Coherent expanded aerogels and jellies[J].Nature,1931,127:741-743. |
| [3] | Peri J B .Infrared study of OH and NH2 groups on the surface of a dry silica aerogel[J].Journal of Chemical Physics,1966,70(09):2937-2945. |
| [4] | Tewari P H;Hunt A J;Lofftus K D .Ambient temperature supercritical drying of tansparent silica aerogels[J].Materials Letters,1985,3(10):363-367. |
| [5] | J.E. Fesmire .Aerogel insulation systems for space launch applications[J].Cryogenics,2006(2/3):111-117. |
| [6] | Rao AV;Bhagat SD;Hirashima H;Pajonk GM .Synthesis of flexible silica aerogels using methyltrimethoxysilane (MTMS) precursor[J].Journal of Colloid and Interface Science,2006(1):279-285. |
| [7] | 杨海龙,倪文,孙陈诚,胡子君,陈淑祥.硅酸钙复合纳米孔超级绝热板材的研制[J].宇航材料工艺,2006(02):18-22. |
| [8] | Poco JF.;Hrubesh LW.;Satcher JH. .Synthesis of high porosity, monolithic alumina aerogels[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(1/3):57-63. |
| [9] | Yoldas B E .Atransparent prous alumina[J].Ceramic Bulletin,1975,54(03):86-88. |
| [10] | Gesser H D;Goswami P C .Aerogels and related porous materials[J].Chemical Reviews,1989,89(04):765-788. |
| [11] | Yasuyuki;Mizushima;MakotoHori .Propertiers of alumina aerogels prepared under different conditions[J].Journal of Non-Crystalline Solids,1994,167:1-8. |
| [12] | Yasuyuki;Mizushima;Makoto Hori .Preparation of heat-resistant alumina aerogels[J].Materials Researeh,1993,8(11):2993-2999. |
| [13] | Hirushima H;HiroakiImai .Application of alumina aerogels as catalysts[J].Journal of Sol-Gel Science and Technology,1997,8:843-846. |
| [14] | 高庆福,张长瑞,冯坚,武纬,冯军宗,姜勇刚.低密度、块状氧化铝气凝胶制备[J].无机化学学报,2008(09):1456-1460. |
| [15] | Gash AE.;Satcher JH.;Hrubesh LW.;Simpson RL.;Tillotson TM. .New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(1/3):22-28. |
| [16] | 张长栓;赵峰;张继军 等.不同制各因素对超细纳米氧化铝结构的影响[J].化学物理学报,1999,12(03):321-325. |
| [17] | Gash AE.;Satcher JH.;Poco JF.;Hrubesh LW.;Simpson RL.;Tillotson TM. .Use of epoxides in the sol-gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts[J].Chemistry of Materials,2001(3):999-1007. |
| [18] | Gash AE.;Satcher JH.;Simpson RL. .Strong akaganeite aerogel monoliths using epoxides: Synthesis and characterization[J].Chemistry of Materials,2003(17):3268-3275. |
| [19] | Baumann F T;Gash E A;ChinnC S et al.Synthesis of high-surface-aera alumina aerogels without the use of alkoxide precursors[J].Chemistry of Materials,2005,17:395-401. |
| [20] | 徐子颉,甘礼华,庞颖聪,陈龙武.常压干燥法制备Al2O3块状气凝胶[J].物理化学学报,2005(02):221-224. |
| [21] | 冯颖 .Al<,2>O<,3>气凝胶的制备及其表征[D].同济大学,2004. |
| [22] | Nicolaon G A;Teichner S J.New preparation process for silica xerogels and aerogels,and their textural properties[J].Bulletin De La Societe Chimique De France,1968:1906. |
| [23] | Tillotson T M;Hrubesh W .Transparent ultralow-density silica aerogels prepared by a two-step Sol-gel process[J].Journal of Non-Crystalline Solids,1992,145:44-50. |
| [24] | 高庆福,张长瑞,冯坚,武纬,冯军宗.氧化铝气凝胶复合材料的制备与隔热性能[J].国防科技大学学报,2008(04):39-42. |
| [25] | 陈龙武;甘礼华.气凝胶[J].化学通报(印刷版),1997(08):21-27. |
| [26] | Al-Yassir N;Van Mao RL .Thermal stability of alumina aerogel doped with yttrium oxide, used as a catalyst support for the thermocatalytic cracking (TCC) process: An investigation of its textural and structural properties[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):275-283. |
| [27] | Horiuchi T.;Sugiyama T.;Suzuki K.;Mori T.;Osaki T. .Maintenance of large surface area of alumina heated at elevated temperatures above 1300 degrees C by preparing silica-containing pseudoboehmite aerogel[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(3):187-198. |
| [28] | 张义民.溶胶--凝胶法制备耐热Al2O3气凝胶[J].河南科学,2002(03):239-241. |
| [29] | 许峥,张鎏,张继炎,徐亦飞,王道宏.NiO-La2O3-Al2O3气凝胶催化剂的制备[J].应用化学,2000(04):366-370. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%