以戊二醛为交联剂,制备了黄原胶/聚乙烯醇(XG/PVA)互穿聚合物网络水凝胶,并研究了其吸水率、力学性能和电刺激响应行为.结果表明,在NaCl溶液中,该水凝胶的平衡溶胀比随NaCl溶液离子强度增大而减小,随pH值的增大而增大,当pH≥7时基本保持不变;经离子强度为0.01 mol/L NaCl溶液充分溶胀的XG/PVA互穿聚合物网络水凝胶其弹性模量为0.9844 MPa,拉伸强度为1.5691 MPa,断裂伸长率为1.60;在非接触的直流电场作用下,于NaCl溶液中,该水凝胶发生弯曲,凝胶的弯曲速度和弯曲偏转程度随外加电场的增加而增大;NaCl溶液离子强度对凝胶弯曲行为产生影响,当溶液离子强度I≤0.05时,凝胶向电场负极弯曲,当溶液离子强度I≥0.05时凝胶向电场正极弯曲;在循环电场作用下,其弯曲响应行为具有良好的可逆性.
参考文献
[1] | 刘根起,赵晓鹏,唐韬.明胶水凝胶电刺激响应行为的研究[J].高分子学报,2003(03):398-402. |
[2] | SHIWEN YANG;GENQI LIU;YONGQING CHENG;YUNHUA ZHENG .Electroresponsive Behavior of Sodium Alginate-g-Poly(acrylic acid) Hydrogel Under DC Electric Field[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2009(10/12):1078-1082. |
[3] | Genqi Liu;Jinyue Song .Electroresponsive behavior of 2-hydroxypropyltrimethyl ammonium chloride chitosan/poly(vinyl alcohol) interpenetrating polymer network hydrogel[J].Polymer international,2012(4):596-601. |
[4] | Kaewpirom S;Boonsang S .Electrical response characterisation of poly(ethylene glycol) macromer (PEGM)/chitosan hydrogels in NaCl solution[J].European Polymer Journal,2006(7):1609-1616. |
[5] | Raghavendra V. Kulkarni;Biswanath Sa .Electroresponsive Polyacrylamide-grafted -xanthan Hydrogels for Drug Delivery[J].Journal of Bioactive and Compatible Polymers,2009(4):368-384. |
[6] | Alireza Shalviri;Qiang Liu;Mohammad J. Abdekhodaie .Novel modified starch-xanthan gum hydrogels for controlled drug delivery: Synthesis and characterization[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2010(4):898-907. |
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