欢迎登录材料期刊网

材料期刊网

中国科学院金属研究所 科学出版社
高级检索
  1. 首页
  2. 期刊
  3. 材料保护
  4. 三价铬电镀的研究进展

材料保护, 2013, 46(9): 38-43.

三价铬电镀的研究进展

张伟 1, , 吴承伟 2,

1.大连理工大学运载工程与力学学部工业装备结构分析国家重点实验室,辽宁大连116024

2.大连理工大学运载工程与力学学部工业装备结构分析国家重点实验室,辽宁大连116024

基金项目:   国家自然科学基金资助项目(51105051,11272080)   中央高校基本科研业务费专项资金资助项目(DUT11RC(3)79)  

关键词： 三价铬镀铬 , 离子液 , 配位剂 , 碳纳米管 , 发展方向

镀铬层应用广泛,常用的Sargent镀液含毒性六价铬离子,三价铬替代六价铬电镀是近年来研究的热点之一.从离子液、添加剂(配位剂、共镀金属及金属氧化物)及引入碳纳米管等方面简述了三价铬电镀近期的研究进展,并分析了存在的问题及未来发展方向.

参考文献

[1] 屠振密,杨哲龙.甲酸盐-乙酸盐体系三价铬电镀工艺[J].材料保护,1985(06):8.
[2] 何湘柱,龚竹青,蒋汉瀛.Cr（Ⅲ）水溶液电沉积非晶态铬的电化学[J].中国有色金属学报,2000(01):95-100.
[3] 三价铬水溶液电镀非晶态铬工艺[J].中国有色金属学报,1999(03):646.
[4] Andrew P.Abbott;Glen Capper;David L.Davies;Raymond K.Rasheed .Ionic Liquid Analogues Formed from Hydrated Metal Salts[J].Chemistry: A European journal,2004(15):3769-3774.
[5] Abbott A P;Capper G;Davies D L et al.Electrodeposition of chromium black from ionic liquids[J].TIMF,2004,82(1/2):14-17.
[6] A. P. Abbott;K. S. Ryder;U. Konig .Electrofinishing of metals using eutectic based ionic liquids[J].Transactions of the Institute of Metal Finishing: The International Journal for Surface Engineering and Coatings,2008(4):196-204.
[7] Benaben P .Ionmet products and processes:New ionic liquid solvent technology to transform metal finishing[OL].www.ionmet.eu/fileadmin/ionmet/Dissemination/IONMET-brochure-200711.pdf
[8] Joo-Yul LEE,Man KIM,Sik-Chol KWON.Effect of polyethylene glycol on electrochemically deposited trivalent chromium layers[J].中国有色金属学报（英文版）,2009(04):819-823.
[9] M.R. Bayati;M.H. Shariat;K. Janghorban .Design of chemical composition and optimum working conditions for trivalent black chromium electroplating bath used for solar thermal collectors[J].Renewable energy,2005(14):2163-2178.
[10] Phuong, N.V.;Kwon, S.-C.;Lee, J.-Y.;Shin, J.;Huy, B.T.;Lee, Y.-I. .Mechanistic study on the effect of PEG molecules in a trivalent chromium electrodeposition process[J].Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science,2011(1):7-14.
[11] Surviliene, S.S.;Eugénio, S.;Vilar, R. .Chromium electrodeposition from [BMIm][BF4] ionic liquid[J].Journal of Applied Electrochemistry,2011(1):107-114.
[12] Eugénio S;Rangel C M;Vilar R .Electrodeposition of black chromium from Cr (Ⅲ)-ionic liquid solution[J].THIN SOLID FILMS,2011,519(06):1845-1850.
[13] Endres F;El Abedin SZ .Air and water stable ionic liquids in physical chemistry[J].Physical chemistry chemical physics: PCCP,2006(18):2101-2116.
[14] Andrew P.Abbott;John C.Barron;Karl S.Ryder .Eutectic-Based Ionic Liquids with Metal-Containing Anions and Cations[J].Chemistry: A European journal,2007(22):6495-6501.
[15] Liu Y S;Pan G B.Ionic Liquids:Applications and Perspectives[M].Janeza Trdine:InTech,2011:627-643.
[16] Baral A;Engelken R .Modeling, optimization, and comparative analysis of trivalent chromium electrodeposition from aqueous glycine and formic acid baths[J].Journal of the Electrochemical Society,2005(7):C504-C512.
[17] Zeng Z X;Chen Y M;Wang D A et al.Tribological behaviors of amorphous Cr coatings electrodeposited from Cr(Ⅲ) baths under ionic liquid lubrication[J].Electrochemical and Solid State Letters,2007,10(08):D85-D87.
[18] Y. B. Song;D. -T. Chin .Current efficiency and polarization behavior of trivalent chromium electrodeposition process[J].Electrochimica Acta,2002(4):349-356.
[19] Kwon SC;Kim A;Park SU;Kim DY;Kim D;Nam KS;Choi Y .Characterization of intermediate Cr-C layer fabricated by electrodeposition in hexavalent and trivalent chromium baths[J].Surface & Coatings Technology,2004(2/3):151-156.
[20] S. Ghaziof;M.A. Golozar;K. Raeissi .Characterization of as-deposited and annealed Cr-C alloy coatings produced from a trivalent chromium bath[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1/2):164-168.
[21] M.J.L. GINES;F.J. WILLIAMS;C.A. SCHUH .Strategy to Improve the High-Temperature Mechanical Properties of Cr-Alloy Coatings[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2007(6):1367-1370.
[22] D. B. Lee .Oxidation of Cr-C electroplating between 400 and 900℃ in air[J].Materials and Corrosion,2008(7):598-601.
[23] Zhixiang Zeng;Liping Wang;Aimin Liang .Fabrication of a nanocrystalline Cr-C layer with excellent anti-wear performance[J].Materials Letters,2007(19/20):4107-4109.
[24] Protsenko;Gordiienk V O;Danilov F I et al.Thick chromium electrodeposition from trivalent chromium bath containing carbamide and formic acid:An investigation into current efficiency,electrodeposition rate and surface morphology[J].Metal Finishing,2011,109(4/5):33-37.
[25] F.I.Danilov;V.S.Protsenko;V.O.Gordiienko;S.C.Kwon;J.Y.Lee;M.Kim .Nanocrystalline hard chromium electrodeposition from trivalent chromium bath containing carbamide and formic acid: Structure, composition, electrochemical corrosion behavior, hardness and wear characteristics of deposits[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(18):8048-8053.
[26] Safonov V A;Vykhodtseva L N;Polukarov Y M et al.Valence-to-core X-ray emission spectroscopy identification of carbide compounds in nanocrystalline Cr coatings deposited from Cr(Ⅲ) electrolytes containing organic substances[J].Journal of Physical Chemistry B,2006,110(46):23192-23196.
[27] Li BS;Lin A;Gan FX .Preparation and characterization of Cr-P coatings by electrodeposition from trivalent chromium electrolytes using malonic acid as complex[J].Surface & Coatings Technology,2006(6):2578-2586.
[28] Safonova O V;Vykhodtseva L N;Polyakov N A et al.Chemical composition and structural transformations of amorphous chromium coatings electrodeposited from Cr(Ⅲ) electrolyte[J].Electrochimica Acta,2010,56(01):145-153.
[29] Zeng Z X;Liang A M;Zhang J Y .A review of recent patents on trivalent chromium plating[J].Recent Patents on Materials Science,2009,2(01):50-57.
[30] P. Leisner;I. Belov .Influence of process parameters on crack formation in direct current and pulse reversal plated hard chromium[J].Transactions of the Institute of Metal Finishing,2009(2):90-96.
[31] Giovanardi, R.;Orlando, G. .Chromium electrodeposition from Cr(III) aqueous solutions[J].Surface & Coatings Technology,2011(15):3947-3955.
[32] Wang F.;Watanabe T. .Preparation and characterization of the electrodeposited Fe-Cr alloy film[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):183-190.
[33] Xu L;Zuo Y;Tang J et al.Chromium-palladium films on 316L stainless steeland theircorrosion resistance in hot sulfuric acid solutions[J].Corrosion Science,2011,53(11):3788-3795.
[34] Guo He;Jurgen Eckert;Wolfgang Loser;Ludwig Schultz .Novel Ti-base nanostructure-dendrite composite with enhanced plasticity[J].Nature materials,2003(1):33-37.
[35] Cang Fan;R. T. Ott;T. C. Hufnagel .Metallic glass matrix composite with precipitated ductile reinforcement[J].Applied physics letters,2002(6):1020-1022.
[36] Zeng ZX;Zhang JY .Electrodeposition and tribological behavior of amorphous chromium-alumina composite coatings[J].Surface & Coatings Technology,2008(12):2725-2730.
[37] 舒绪刚,何湘柱,黄慧民,李大光,谢绍俊,雷华山,赵国鹏.电沉积Cr/ZrO2复合镀层的结构和摩擦性能[J].中南大学学报（自然科学版）,2010(03):871-875.
[38] E. G. Vinokurov;A. M. Arsenkin;K. V. Grigorovich .Electrodeposition and Physico-Mechanical Properties of Chromium Coatings Modified with Disperse Particles[J].Protection of Metals,2006(3):290-294.
[39] Leonhard A;Xing L Q;Heilmaier M .Effect of crystalline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys[J].Nanostructured Materials,1998,10(05):805-817.
[40] Hays CC.;Johnson WL.;Kim CP. .Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions[J].Physical review letters,2000(13):2901-2904.
[41] Wong EW. Sheehan PE. Lieber CM. .NANOBEAM MECHANICS - ELASTICITY, STRENGTH, AND TOUGHNESS OF NANORODS AND NANOTUBES[J].Science,1997(5334):1971-1975.
[42] Treacy M M J;Ebbesen T W;Gibson J M .Exceptionally high Young' s modulus observed for individual carbon nanotubes[J].NATURE,1996,381(6 584):678-680.
[43] Dujardin E;Ebbesen T W;Hiura H et al.Wetting and nanocapillary of CNTs[J].SCIENCE,1994,265(5 180):1850-1852.
[44] S. Khabazian;S. Sanjabi .The effect of multi-walled carbon nanotube pretreatments on the electrodeposition of Ni-MWCNTs coatings[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(13):5850-5856.
[45] Zeng Z;Yu Y;Zhang J .Electrochemical corrosion behavior of carbon nanotubes-doped hard chromium coatings electrodeposited from Cr(Ⅲ) baths[J].Journal of the Electrochemical Society,2009,156(04):C123-C126.
[46] Liu, Bin;Zeng, Zhixiang;Lin, Yimin .Mechanical properties of hard Cr-MWNT composite coatings[J].Surface & Coatings Technology,2009(23):3610-3613.
[47] Molina JM;Saravanan RA;Narciso J;Louis E .Surface modification of 2014 aluminium alloy - Al2O3 particles composites by nickel electrochemical deposition[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(2):299-306.
[48] Belin T;Epron R .Characterization methods of carbon nanotubes: a review[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2005(2):105-118.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
作者相关
文章评分
  • 您的评分：
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%

版权所有©2010中国科学院金属研究所中国科技出版传媒股份有限公司

本系统由北京仁和汇智信息技术有限公司设计开发

技术支持：info@rhhz.net