采用硫酸钛与氨水反应制备掺氮TiO2.UV-Vis漫反射谱研究表明掺氮的TiO2在紫外区的吸收边明显红移(约20 nm),并且在400nm~530 nm出现新的吸收区域,光吸收阈值从380 nm扩展到530 nm.XPS分析表明,在TiO2掺杂的N为间隙态,而且还存在大量的氧空位.氧空位在导带下形成的窄带使得掺氮的TiO2在400nm~530 nm出现新的吸收区域.用MTT法测量了掺氮TiO2杀伤白血病HL60细胞的活性.结果显示,无论有无可见光照射,掺氮TiO2对白血病肿瘤细胞杀灭效果明显好于未掺杂TiO2.
参考文献
[1] | 王浩,赵文宽,方佑龄,王润帮,李莉.二氧化钛光催化杀灭肿瘤细胞的研究[J].催化学报,1999(03):373-374. |
[2] | Asahi R et al.[J].Science,2001,293:269. |
[3] | Irie H et al.[J].Journal of Physical Chemistry B,2003,107(23):5483. |
[4] | Sano T.;Negishi N.;Koike K.;Takeuchi K.;Matsuzawa S. .Preparation of a visible light-responsive photocatalyst from a complex of Ti4+ with a nitrogen-containing ligand[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(3):380-384. |
[5] | Yin S et al.[J].Journal of Materials Chemistry,2003,13:2996. |
[6] | Yin S et al.[J].Chemistry Letters,2003,32(04):358. |
[7] | Morikawa T et al.[J].Japanese Journal of Applied Physics,2001,40:561. |
[8] | Miao L et al.[J].Journal of Crystal Growth,2004,260:118. |
[9] | 熊予莹 et al.[J].材料科学技术,2006,22(03):353. |
[10] | 王建琪.电子能谱学引论[M].北京:国防工业出版社,1992:544. |
[11] | Justicia I et al.[J].Advanced Materials,2002,14(19):1399. |
[12] | 沈学础.半导体光谱和光学性质[M].北京:科学出版社,2002:50. |
[13] | Karvaly B et al.[J].Naturforsch A,1971,26:245. |
[14] | Tauc J et al.[J].Physica Status Solidi,1966,15:627. |
[15] | Sakthivel S et al.[J].Angewandte Chemie International Edition,2003,42(40):4908. |
[16] | Nakamura I.;Kutsuna S.;Ihara T.;Sugihara S.;Takeuchi E.;Negishi N. .Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal[J].Journal of molecular catalysis, A. Chemical,2000(1/2):205-212. |
[17] | Bilmes S A et al.[J].Journal of Physical Chemistry B,2000,104:9851. |
[18] | Ihara T et al.[J].Applied Catalysis,2003,42(04):403. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%