金相、X射线电子能谱和显微硬度等实验表明,Si在Al-0.35wt-%Si合金氧化膜下的过饱和空位造成的空位坑中有Si的偏聚.这种偏聚只能用空位-Si原子复合体扩散导致的非平衡偏聚理论来解释。
Si segregation was observed in the vacancy condensation pits, formed by supersaturated vacancies below the oxidation layer of Al—0.35 wt-%Si alloy, by optical microscopy, X-ray photoeletron spectroscopy and microhardness test. This phenomenon could only be explained by diffusion of vacancy-Si complex inducing non-equilibrium segregation.
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