研究了不同固溶工艺条件对Cu-1.4Ni-1.2Co-0.6Si合金显微组织的影响,对合金固溶-时效后的显微硬度和导电率进行了分析,并采用电子衍射及透射电镜分析其显微组织.结果表明:合金铸态组织以等轴晶为主,热轧变形组织中存在许多细小析出相.热轧合金在固溶处理过程中基体变形组织发生再结晶和晶粒长大,且随着固溶温度升高,析出相固溶量增加,至975℃时,析出相粒子基本回溶到基体中.合金中的析出相与Cu-Ni-Si合金具有相同的结构和形貌,与Cu基体的位向关系为:[001]Cu//[(1)10]p,(010)Cu//(001)p;[(1)12]Cu//[32(4)]p,(110)Cu//(2 (1)1)p.合金最佳固溶-时效处理工艺为975℃×1.5h+500℃×4 h时效,在此工艺条件下,合金显微硬度为232 HV,相对导电率为49%IACS.
参考文献
[1] | Hiroshi M,Tomohiko U,HisanoriT .Anomalous elastic properties ofamorphousalloys suggesting a collective motion of many atoms[J].Journal of NonCrystalline Solids,2002,312 |
[2] | 李本贵,于艳,曹志强,方园,李廷举.铜基合金的强化机理和研制现状[J].铸造,2005(10):948-952. |
[3] | 孙建春,刘筱薇,周安若.弹性合金的研究现状及趋势[J].热加工工艺,2006(18):52-56. |
[4] | 李国俊.高弹性合金的现状与发展趋势[J].材料导报,1993(4):15-17.LI Guo-jun.Present status and development trend of high elastic alloy[J].Materials Review,1993 (4):15-17.,1993. |
[5] | 王深强.高强高导铜合金的研究概述[J].材料工程,1995(07):3. |
[6] | 谢水生,李彦利,朱琳.电子工业用引线框架铜合金及组织的研究[J].稀有金属,2003(06):769-776. |
[7] | Fujiwara H,Kamio A .Effect of alloy composition on precipitation behavior in Cu-Ni-Si alloys[J].Journal of Japan Institute of Metals,1998,62 |
[8] | Lockyer S A,Noble F W .Precipitate structure in a Cu-Ni-Si alloy[J].Journal of Materials Science,1994,29 |
[9] | Corson M G .Electrical conductor alloy[J].Electrical World,1927,89 |
[10] | Rdzawski Z,StobrawaJ.Mechanical processing of Cu-Ni-Si-Cr-Mg alloy[J].Materials Science and Technology,1993 (2):142-149.,1993. |
[11] | Witusiewicz V T,Arpshofen I,Seifert H J,et al .Enthalpy of mixing of liquid and undercooled liquid ternary and quaternary Cu-Ni-Si-Zralloys[J].Journal of Alloys and Compounds,2002,337(2):155-167.,2002. |
[12] | Kim Y G,Seong T Y,Han J H .Effect of heat treatment on precipitation behavior in a Cu-Ni-Si-P alloy[J].Materials Science,1986,21(4):1357-1362.,1986. |
[13] | 赵冬梅,董企铭,刘平,康布熙,金志浩.超高强度Cu-Ni-Si合金时效过程研究[J].材料热处理学报,2002(02):20-23. |
[14] | Srivastava V C,Schneider A,Uhenwinkel V,et al .Age-hardening characteristics of Cu-2.4Ni-0.6Si alloy produced by the spray forming process[J].Journal of Materials Processing Technology,2004,147(2):174-180.,2004. |
[15] | 林高用,张胜华.Cu-Ni-Si-Cr-Fe合金时效强化特性的研究[J].金属热处理,2001(04):28-30. |
[16] | 程建奕,汪明朴,李周,徐根应,王艳辉,洪斌,肖从文.Cu-1.5Ni-0.27Si合金形变热处理[J].中国有色金属学报,2003(05):1061-1066. |
[17] | XIAO Xiang-peng,XIONG Bai-qing,WANG Qiang-song .Effect of thermomechanical treatments on microstructure and properties of CuNiSiZr alloy[J].Rare Metals,2013,32(2):144-149.,2013. |
[18] | Zhao D M,Dong Q M,Liu P,et al .Structure and strength of the age hardened Cu-Ni-Si alloy[J].Materials Chemistry and Physics,2003,79(2):81-84.,2003. |
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