将水热法合成的LiFePO_4粉体作为原料,通过浸渍-提拉法制备了LiFePO_4纳米薄膜.观察了热处理温度对薄膜折射率和透光率等光学性能的影响.结果表明,在120~450℃范围内,随着热处理温度的升高,薄膜折射率和透射率(在可见光区)增大,并膜厚减小.
The LiFePO_4 powder that prepared by hydrothermal method were using as the precursors,the nano-LiFePO_4 thin films were fabricated by dip-coating methods.The effect of heat treating temperature on refractive index and transmittance of thin films were studied.The results show that,At the range of 120-450℃,with increase of heat treating temperature,the thin film change from non-crystal to crystal,the refractive index and transmittance (in the visual spectra area)were increases gradually,meanwhile,thickness was decrease.
参考文献
[1] | 鲁圣国 等.[J].科学通报,1997,42(01):106. |
[2] | Abliz Yimit et al.[J].ELECTROCHEMISTRY,2001,69:182-186. |
[3] | 钟胜奎,王健,肖新和,李伟.锂离子电池正极材料LiFePO4的研究现状及展望[J].化工新型材料,2008(05):4-6. |
[4] | Huang H;Yin S C;Naz I F et al.[J].Electrochemical and Solid-State Letters,2001,4(10):A170-A172. |
[5] | 杨蓉,赵铭姝,汪飞,宋晓平.锂离子电池正极材料LiFePO4的研究现状[J].电池,2004(06):460-461. |
[6] | 桑俊利;王巧娟;郭西凤 等.[J].技术无机盐工业,2008,4(02):13-17. |
[7] | 韩翀,沈湘黔,周建新.LiFePO4/Ni复合微球的制备[J].硅酸盐学报,2008(04):559-564. |
[8] | 谭显艳,胡国荣,高旭光,彭忠东,陈召勇,禹筱元.掺杂Mg的LiFePO4电化学性能研究[J].电池,2004(05):344-345. |
[9] | Wang G X;Yang L;Bewlay S L et al.[J].Journal of Power Sources,2005,146(1-2):521-524. |
[10] | Ma J;Qin Q Z et al.[J].Journal of Power Sources,2005,148:66. |
[11] | 赵灵智,胡社军,李伟善,李黎明.真空气相沉积法制备LiFePO4薄膜的研究进展[J].广东化工,2007(10):56-58,63. |
[12] | 薛明喆,傅正文.脉冲激光沉积LiFePO4阴极薄膜材料及其电化学性能[J].物理化学学报,2005(07):707-710. |
[13] | Sauvage F;Baudrin E;Gengembre L;Tarascon JM .Effect of texture on the electrochemical properties of LiFePO4 thin films[J].Solid state ionics,2005(23/24):1869-1876. |
[14] | Wang Jiazhao;Chou Shulei;Chen Jun et al.[J].Electrochemistry Communications,2008,10:1781-1784. |
[15] | Subba Reddy C V et al.[J].Journal of Applied Electrochemistry,2007,37:637-642. |
[16] | W. C. West;J. F. Whitacre;B. V. Ratnakumar .Radio Frequency Magnetron-Sputtered LiCoPO_4 Cathodes for 4.8 V Thin-Film Batteries[J].Journal of the Electrochemical Society,2003(12):A1660-A1666. |
[17] | 黄艳,李慧勤,安百江,张欣娟.电化学法制备薄膜材料研究进展[J].陶瓷,2007(10):54-57. |
[18] | 庄大高,赵新兵,曹高劭,米常焕,涂健,涂江平.水热法合成LiFePO4的形貌和反应机理[J].中国有色金属学报,2005(12):2034-2039. |
[19] | Cho Yungda;Fey G T K et al.[J].Solid State Electrochemistry,2008,12:815-823. |
[20] | 朱小平,于长凤,凌青,张脉官,戴静.制备工艺对SnO2:Sb透明导电膜性能的影响[J].中国陶瓷工业,2006(05):1-5. |
[21] | 李德增,吴广明,王爱荣,肖锟,沈军,周斌,张志华.热处理对TiO2-V2O5纳米复合薄膜结构及性能的影响[J].材料热处理学报,2007(03):14-18. |
[22] | 杨振宇,朱大庆,陆冬生,张爱卿,赵茗,宁娜,刘拥军.纳米孔隙薄膜中孔隙率与折射率关系的研究[J].光学学报,2003(11):1366-1369. |
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