以碳化钙为原料、新鲜氯气为刻蚀剂,在400～700℃范围内制备碳化钙骨架碳作为锂离子电池新型负极材料.用X射线衍射(XRD)、扫描电镜(SEM)、氮气吸附实验、恒流充放电、交流阻抗(EIS)等对碳化钙骨架负极材料进行表征及电化学性能测试,并探讨制备温度对碳化钙骨架碳结构和电化学性能的影响.结果表明:所有温度下制备的碳化钙骨架碳均为无定形碳材料,但随着制备温度的升高,材料出现部分石墨化倾向；600℃制备的碳化钙骨架碳具有良好的电化学性能,在0.1 C充放电时,首次放电比容量为890.9 mA·h/g,可逆容量为335.4mA·h/g,循环30次后的可逆容量为266.8 mA·h/g.
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