蒙脱石具有良好的可改造性,其加工产物具有优良的理化性能,这都取决于蒙脱石结构的特珠性及其优良的阳离子交换性.从蒙脱石层间域具有可改造性出发,揭示了蒙脱石层间域具有可改造性的本质.结合钠化、有机化、插层化合物、原位聚合反应及纳米化处理的试验研究,讨论了层间域可改造的几种主要方式和类型、层间物改造后层间域的变化及国内外相关研究的进展.将蒙脱石钠化、有机化、无机化合物柱撑、有机聚合插层处理等上升为蒙脱石层间域的可改造性研究具有重要的理论和实际意义.
Montmorillonite has well alterability and its processeing products have fine physicochemical proper-ties which depend on the particularity and the fine cation exchange performance of montmorillonite structure. It is re-vealed that the montmorillonite interlayer space has the essence of alterability based on the alterability of montmoril-lonite interlayer space. It is discussed that some main methods and types of interlayer transformed and the research progress at home and abroad and change of interlayer after the interlayer thing alteration combined with the experimen-tal studied on sodium modification, organification, intercalation compound, situ anionic polymerization and nanometer treatment. It has the important theoretic and practical meaning that the research is developed from sodium modifica-tion, organification, pillared by inorganic compound, intercalation treatment by organic polymer and so on to the study about the montmorillonite interlayer reconstruct.
参考文献
| [1] | 曹明礼,于阳辉,袁继祖.膨润土的钠化改型研究[J].矿冶工程,2001(02):24-26. |
| [2] | 周佳荣,易发成,侯莉.钙基膨润土的钠化改型方法研究[J].中国矿业,2007(03):84-87. |
| [3] | 康玉茹,宋国勇,杨涛,杨立明.钙基膨润土锂改性工艺研究[J].化工矿物与加工,2006(05):16-18,22. |
| [4] | 李静静,吕宪俊.锂基蒙脱石制备工艺研究[J].非金属矿,2006(06):29-31. |
| [5] | 胡智荣;钟旭东;李玉平 .锂基膨润土在高温涂料中的应用[J].非金属矿,1999,22(06):22. |
| [6] | 黄振辉;苏明迪;陈立泉.锂型蒙脱石的离子导电性[J].地质科学,1992(01):71. |
| [7] | 何卓立 .锌蒙脱石隔离层性能的研究[J].电池,1993,23(05):206. |
| [8] | 王仪珍,王大志,张道元,赵建兴,何祥勇.四价锡离子导体-锡蒙脱石[J].物理学报,1991(11):1893-1896. |
| [9] | 李博文,肖清华.载银膨润土的抗菌性能研究[J].非金属矿,2001(05):17-18. |
| [10] | 夏枚生,胡彩虹,赵文艳.载铜蒙脱石的抗菌机理研究[J].微生物学报,2006(03):432-435. |
| [11] | 朱建喜,何宏平,郭九皋,杨丹,谢先德.不同链长烷基季铵离子在蒙脱石层间域内排列方式的对比[J].矿物学报,2003(03):193-198. |
| [12] | Xi Yunfei;Zhou Qin;Frost Ray L .Thermal stability of octadecyltrimethylammonium bromide modified montmorillonite organoclay[J].Journal of Colloid and Interface Science,2007,311:347. |
| [13] | Xi Yunfel;Frost Ray L;He Hongping .Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyl trimethyl,dialkyl dimethyl,and trialkyl methy ammonium bromides[J].Journal of Colloid and Interface Science,2007,305:150. |
| [14] | Monique A M Lawrence;Ravi K Kukkadapu;Stephen A Boyd .Adsorption of phenol and chlorinated phenols from aqueous solution by tetramethylammonium-and tetramethylphosphonium-exchanged montmorillonite[J].Applied Clay Science,1998,13(01):13. |
| [15] | Giora Rytwo;Mordechai Tavasi;Shmuel Afuta;Shlomo Nir .Adsorption of difenzoquat on montmorillonite: model calculations and increase in hydrophobicity[J].Applied clay science,2004(3/4):149-157. |
| [16] | 曾少雁,吴平霄.C10TAB,C14TAB,C18TAB柱撑蒙脱石层间域有机柱排布研究[J].矿物岩石,2005(03):58-62. |
| [17] | 刘子阳.羟基金属聚合物交联蒙脱土（临安）及其催化特性[J].吉林大学自然科学学报,1990(04):98-102. |
| [18] | 吴平霄,张惠芬,肖文丁,吴金平.柱撑蒙脱石制备与表征[J].矿物学报,1997(02):200-207. |
| [19] | 刘云,吴平霄,唐剑文,曾少雁.聚羟基铝柱撑蒙脱石吸附重金属离子实验研究[J].矿物岩石,2005(03):122-126. |
| [20] | Karamanis D;Assimakopoulos P A.Efficiency of aluminum-pillared montmorillonite on the removal of cesium and copper from aqueous solutions[J].Water Research,2007(41):1897. |
| [21] | 田淑贵,王冠鑫,林传易.氧化铬柱支撑蒙脱石的制备研究[J].矿物学报,1998(04):390-395. |
| [22] | 袁鹏,王辅亚,肖万生,吴大清,杨丹,何宏平.铁层离-柱撑蒙脱石的结构初探[J].矿物岩石,2005(03):37-40. |
| [23] | 周春晖,李庆伟,葛忠华,李小年,倪哲明.介孔硅层柱蒙脱石材料合成的新方法与表征[J].高等学校化学学报,2003(08):1351-1355. |
| [24] | 孙伶,邵红.铝-钛交联改性膨润土在处理废水中的应用研究[J].辽宁化工,2006(05):271-273. |
| [25] | 邵红,孙伶.镍钛交联改性膨润土处理工业废水的实验[J].岩矿测试,2006(02):147-150. |
| [26] | 丁述理,李萍,杜振川,史长林,罗忠.Al/Ce柱撑蒙脱石的制备与结构特征[J].河北建筑科技学院学报,2000(04):55-58. |
| [27] | 曹明礼,于阳辉,袁继祖,余永富.Al-Mn柱撑蒙脱石的制备和微结构变化研究[J].硅酸盐学报,2002(01):86-90. |
| [28] | 田淑贵,王冠鑫,林传易,陈国玺.氧化铬-铝混杂柱支撑蒙脱石的制备和性能[J].矿物学报,2000(02):108-111. |
| [29] | Han Yangsu;Shoji Yamanak .Preparation and characterization of microporous SiO_2-ZrO_2 pillared montmorillonite[J].Journal of Solid State Chemistry,2006,179:1146. |
| [30] | Kojima Y;Usuki A;Kawasumi M et al.Mechanical properties of nylon 6-clay hybrid[J].Journal of Materials Research,1993,8:1185. |
| [31] | Kojima Y;Usuki A;Kawasumi M et al.Sorption of water in nylon 6-clay hybrid[J].Journal of Applied Polymer Science,1993,49:1259. |
| [32] | Mehrotra V;Gianelis E P.Polymer based molecular composites[A].,1990 |
| [33] | 李田,曾幸荣,许均.聚吡咯/有机蒙脱土纳米复合材料制备水性环氧抗静电涂料研究[J].高分子材料科学与工程,2006(02):251-253. |
| [34] | Pluta M;Jeszka JK;Boiteux G .Polylactide/montmorillonite nanocomposites: Structure, dielectric, viscoelastic and thermal properties[J].European Polymer Journal,2007(7):2819-2835. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%