Synthesis and Fluorescence Properties of Europium, Terbium Doped Zn2+, Cd2+ and Cr3+ Complexes

稀土学报(英文版), 2007, 25(6): 679-683.

^1, , ^2, , ^3, , ^4, , ^5,

1.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

2.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China;State Key Laboratory of Rare Earth Materials Chemistry and Applications,Peking University,Beijing 100871,China

3.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

4.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

5.Wuppertal University,Wuppertal 42119,Germany

基金项目: 教育部春晖计划项目(Z2004-2-15029) 国家自然科学基金(20461002)

Synthesis and Fluorescence Properties of Europium, Terbium Doped Zn2+, Cd2+ and Cr3+ Complexes

Wen Xiaochun ^1, , Zhao Yongliang ^2, , Wang Lianmeng ^3, , Zhang Mei ^4, , Gao Deqing ^5,

1.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

3.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

4.College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010021,China

5.Wuppertal University,Wuppertal 42119,Germany

Keywords： europium complex

Europium and terbium complexes with strong fluorescence intensity and long fluorescence lifetime were prepared.By replacing half of the europium or terbium ion with M (M=Zn2+, Cd2+, and Cr3+) using the doped method, and then incorporating it with 18-crown-6 ether and terephthalic acid, six heteronuclear samples EuZnLL'Cl3·3H2O(1), EuCdLL2'Cl3·5H2O(2), EuCrLL'Cl4·4H2O(3), TbZnLL'Cl3·4H2O(4), TbCdLL'2Cl3·4H2O(5), and TbCrLL'2Cl4·4H2O(6) (L=terephthalic acid, L'=18-Crown-6 ether) were obtained.The elemental analysis, molar conductivities, rare earth complexometry, Fourier Transform Infrared Spectroscopy (FT-IR), ultraviolet (UV), TGA, fluorescence intensity, and fluorescence lifetime of the samples were measured.The results showed that there were good luminescence properties for heteronuclear complexes (1), (2), (4), and (5), which were even stronger than those of the homonuclear complexes Eu2LL'2Cl4·4H2O and Tb2LL'2Cl4·4H2O, but the luminescence properties of EuCrLL'Cl4·4H2O, TbCrLL'Cl4·4H2O were very weak.A possible luminescence mechanism was suggested by the organic-inorganic doped mechanism and the law of intramolecular energy transfer.

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Synthesis and Fluorescence Properties of Europium, Terbium Doped Zn2+, Cd2+ and Cr3+ Complexes

参考文献