本文借助Olympus光学显微镜、扫描电子显微镜(SEM)和原子力显微镜(AFM)对高温高压合成的含硼金刚石单晶表面形貌进行了分析.研究发现,含硼金刚石表面存在蚀坑、球形颗粒集团、平行台阶、花瓣状生长丘和三角形螺旋台阶等多种表面形貌.这些形貌与晶体内部的缺陷有关,硼原子的进入使金刚石晶体生长速度增加,位错增多,进而导致不同表面形貌的形成,螺旋位错生长是含硼金刚石的主要生长方式.
参考文献
[1] | 魏俊俊,贺琦,高旭辉,吕反修,陈广超,朱秀萍,倪晋仁.MPCVD掺硼金刚石薄膜的制备及Ti/BDD 电极上对硝基酚的阳极氧化测试[J].人工晶体学报,2009(02):422-425. |
[2] | Kalish R. .Doping of diamond[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(5):781-785. |
[3] | 魏俊俊,贺琦,高旭辉,郭会斌,石绍渊,吕反修,唐伟忠,陈广超.硼掺杂金刚石薄膜研究[J].人工晶体学报,2007(03):569-572. |
[4] | H.S. Li;Y.X. Qi;J.H. Gong .High-pressure synthesis and characterization of thermal-stable boron-doped diamond single crystals[J].International Journal of Refractory Metals & Hard Materials,2009(3):564-570. |
[5] | Ohta Y;Shirakawa T;Horiuchi S;Fukuyama H .B-doped diamond: Superconductivity without Fermi surface[J].Physica, C. Superconductivity and its applications,2007(1):121-124. |
[6] | Ye H;Tumilty N;Bevilacqua M;Curat S;Nesladek M;Bazin B;Bergonzo P;Jackman RB .Electronic properties of homoepitaxial (111) highly boron-doped diamond films[J].Journal of Applied Physics,2008(5):054503-1-054503-7-0. |
[7] | J. Isberg;J. Hammersberg;D. J. Twitchen .Single crystal diamond for electronic applications[J].Diamond and Related Materials,2004(2):320-324. |
[8] | Ekimov E A;Sidorovl V A;Bauer E D .Superconductivity in Diamond[J].Nature,2004,428:542-545. |
[9] | El Feninat F;Elouatik S;Ellis T H et al.Quantitative Assessment of Surface Roughness as Measured by AFM:Application to Polished Human Dentin[J].Applied Surface Science,2001,183:205-215. |
[10] | S. Gsell;M. Schreck;G. Benstetter .Combined AFM-SEM study of the diamond nucleation layer on Ir(001)[J].Diamond and Related Materials,2007(4/7):665-670. |
[11] | A. Bogus;I.C. Gebeshuber;A. Pauschitz .Micro- and nanomechanical properties of diamond film with various surface morphologies[J].Diamond and Related Materials,2008(12):1998-2004. |
[12] | Y. Mokuno;A. Chayahara;H. Yamada .Synthesis of large single crystal diamond plates by high rate homoepitaxial growth using microwave plasma CVD and lift-off process[J].Diamond and Related Materials,2008(4/5):415-418. |
[13] | T.E. Derry;Nic van der Berg;N.W. Makau .Diamond surfaces polished both mechanically and manually; an atomic force microscopy (AFM) study[J].Diamond and Related Materials,2008(2):127-136. |
[14] | 郝兆印;陈宇飞;邹广田.人工合成金刚石[M].长春:吉林大学出版社,1996 |
[15] | 张克丛;张乐惠.晶体生长科学与技术[M].北京:科学出版社,1997:214-216. |
[16] | V.D. Blank;M.S. Kuznetsov;S.A. Nosukhin .The influence of crystallization temperature and boron concentration in growth environment on its distribution in growth sectors of type IIb diamond[J].Diamond and Related Materials,2007(4/7):800-804. |
[17] | J. Q. Zhang;H. A. Ma;Y. P. Jiang;Z. Z. Liang;Y. Tian;X. Jia .Effects of the additive boron on diamond crystals synthesized in the system of Fe-based alloy and carbon at HPHT[J].Diamond and Related Materials,2007(2):283-287. |
[18] | Yu.V.Babich;B.N.Feigelson .Spatial Distribution of the Nitrogen Defects in Synthetic Diamond Monocrystals:Data of IR Mapping[J].Geochemistry International,2009(1):94-98. |
[19] | Yin L W;Li M S;Li F Z .Defect Formation in Diamond Single Crystals Grown from the Fe-Ni-C System at High Temperature and High Pressure[J].Materials Research Bulletin,2001,13:2283-2288. |
[20] | L. -W. Yin;M. -S. Li;J.-J. Cui .Atom force microscopy study on HTHP as-grown diamond single crystals[J].Applied physics, A. Materials science & processing,2001(5):653-657. |
[21] | Yin LW.;Li MS.;Xu B.;Song YJ.;Hao ZY. .Step bunching behavior on (111) surface of diamond single crystal[J].Chemical Physics Letters,2002(5-6):498-504. |
[22] | Hoogers G.;King DA.;Lesiakorlowska B. .DIFFUSION ON A STEPPED SURFACE - H AND D ON RH(332)[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,1995(1/2):47-52. |
[23] | Uwaha M.;Sato M.;Saito Y. .FLUCTUATIONS AND INSTABILITIES OF STEPS IN THE GROWTH AND SUBLIMATION OF CRYSTALS[J].Journal of Crystal Growth,1995(1/4):164-170. |
[24] | Frank F C.Growth Perfection of Crystals[M].Berlin:Wiley,1958 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%