采用水热法制备了负载Ag的Zns纳米线,通过XRD,TEM以及UV-Vis对所合成的纳米线的相结构、形貌以及光学性能进行了表征.并以甲基橙为目标降解物,评价了所制备的复合纳米线在紫外光下的光催化性能.研究结果表明,水热法制备的ZnS纳米线对甲基橙溶液的光催化活性比商业ZnS粉体更高,并且银的负载对ZnS纳米线的光催化活性有显著的提高作用.这是由于银粒子复合ZnS纳米线能促进光生电子空穴对分离,增多ZnS纳米线的反应活性点,从而提高其光催化活性.
参考文献
[1] | Kamat P V;Huehn R;Nicolaescu R .[J].Journal of Physical Chemistry B,2002,106(04):788. |
[2] | Marion L;Reinhard N .[J].Environmental Science and Technology,2002,36(24):5342. |
[3] | Nagaveni K;Sivalingam G;Hegde M S et al.[J].Environmental Science and Technology,2004,38(05):1600. |
[4] | Liau L C K;Tung M T .[J].Industrial and Engineering Chemistry Research,2006,45(07):2199. |
[5] | Dai J;Jiang Z J;Li W et al.[J].Materials Letters,2002,55(06):383. |
[6] | Yin H;Da Y;Kitamura T et al.[J].Environmental Science and Technology,2001,35(01):227. |
[7] | Torres-Martinez C L;Kho R;Mian O I et al.[J].Journal of Colloid and Interface Science,2001,240(02):525. |
[8] | Wada Y;Kitamura T;Yanagida S et al.[J].Chemical Communications,1998(24):2683. |
[9] | Wang X L;Pehkonen S O;Ray A K .[J].Industrial and Engineering Chemistry Research,2004,43(07):1665. |
[10] | 冯守爱,赵江红,朱珍平.通过碳纳米管与硫化锌纳米晶体复合提高硫化锌的光催化活性[J].新型炭材料,2008(03):228-234. |
[11] | Stroyukl A L;Shvalaginl V V;Kuchmii S Y .[J].Theoretical and Experimental Chemistry,2004,40(02):98. |
[12] | 罗妮,王宁,张昭.多孔Ag/TiO2的制备及其光催化性研究[J].功能材料,2007(07):1143-1145,1148. |
[13] | Subramanian V;Wolf E;Kamat P V .[J].Journal of Physical Chemistry B,2001,105(22):11439. |
[14] | 孟阿兰,岑伟,李镇江,李荣先.ZnO/Ag纳米复合材料光催化性能研究[J].稀有金属材料与工程,2007(z2):299-302. |
[15] | Chen XJ.;Xu HF.;Xu NS.;Zhao FH.;Lin WJ.;Lin G.;Fu YL.;Huang ZL. Wang HZ.;Wu MM. .Kinetically controlled synthesis of wurtzite ZnS nanorods through mild thermolysis of a covalent organic-inorganic network[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(9):3100-3106. |
[16] | Wang YW.;Zhang LD.;Liang CH.;Wang GZ.;Peng XS. .Catalytic growth and photoluminescence properties of semiconductor single-crystal ZnS nanowires[J].Chemical Physics Letters,2002(3-4):314-318. |
[17] | Li Q;Wang C R .[J].Applied Physics Letters,2003,83(02):359. |
[18] | Spontaneous growth and luminescence of zinc sulfide nanobelts[J].Applied physics letters,2003(11):1769-1771. |
[19] | Wang X D;Gao P;Li J et al.[J].Advanced Materials,2002,14:1732. |
[20] | 李国平,罗运军.水热法制备ZnS纳米线[J].无机化学学报,2007(11):1864-1868. |
[21] | Rozman M;Drofenik M .[J].Journal of the American Ceramic Society,1995,78(09):2449. |
[22] | Jiang Y;Meng X M;Liu J et al.[J].Advanced Materials,2003,15(04):323. |
[23] | Renjis T T;Sreekumaran Nair A;Navinder S et al.[J].Langmuir,2003,19(08):3439. |
[24] | He C.;Yu Y.;Hu XF.;Larbot A. .Influence of silver doping on the photocatalytic activity of titania films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2002(1/4):239-247. |
[25] | Zanella R;Giorgio T S;Henry C R et al.[J].Journal of Physical Chemistry B,2002,106(31):7634. |
[26] | Chen W;Wang Z G;Lin Z J et al.[J].Journal of Applied Physics,1977,82(06):3111. |
[27] | 石稳建;郑经堂;胡燕 et al.[J].太阳能学报,2007,28(10):1120. |
[28] | Sopyan Ⅰ;Watanabe M;Murasawa S et al.[J].Journal of Photochemistry and Photobiology A:Chemistry,1996,98(1-2):79. |
[29] | 刘祥志,徐明霞,李顺,张念星.掺杂TiO2纳米线及其可见光催化性能[J].武汉理工大学学报,2007(10):173-177. |
[30] | Tada H.;Inubushi Y.;Ito S.;Teranishi K. .Ag nanocluster loading effect an TiO2 photocatalytic reduction of bis(2-dipyridyl)disulfide to 2-mercaptopyridine by H2O[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(7):3304-3309. |
[31] | Ryu J;Choi W .[J].Environmental Science and Technology,2004,8(10):2928. |
[32] | Goto H;Hanada Y;Ohno T et al.[J].Journal of Catalysis,2004,225(01):223. |
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