液相法是低成本、工业化制备TiO2纳米粉较理想的方法.本文较系统的综述了目前TiO2纳米粉的各种液相制备方法,并对各种制备方法进行了比较,着重分析了各制备方法的技术关键和优缺点,最后对制备TiO2纳米粉液相的进一步发展进行了展望.以微波作为加热方式,均匀沉淀结合液相一步合成,将是低成本工业化制备纳米TiO2的发展趋势.
参考文献
| [1] | 李国华,王大伟,徐铸德,黄志良,陈卫祥.不同沉淀剂制备的纳米氧化钛粉体晶相控制[J].硅酸盐学报,2003(03):272-277,299. |
| [2] | 赵旭,王子忱,赵敬哲.球形二氧化钛的制备[J].功能材料,2000(03):303. |
| [3] | Nam HD.;Kim SJ.;Jung CH.;Lee JH.;Park S.;Lee BH. .Preparation of ultrafine crystalline TiO2 powders from aqueous TiCl4 solution by precipitation[J].Japanese Journal of Applied Physics,1998(8):4603-4608. |
| [4] | 何超,于云,周彩华,胡行方,Ande LARBOT.Ag掺杂对TiO2粉末结构的影响[J].无机材料学报,2003(02):457-464. |
| [5] | Zhang X;Zhang F;Chan KY .Synthesis of titania-silica mixed oxide mesoporous materials, characterization and photocatalytic properties[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):193-198. |
| [6] | 张莉,褚道葆.酸度对偏钛酸水热法合成纳米TiO2的影响[J].安徽师范大学学报(自然科学版),2002(01):46-48. |
| [7] | Kaifeng Yu;Jingzhe Zhao;Xu Zhao .Self-assembly and oriented organization of shape-controlled nanocrystalline TiO_2[J].Materials Letters,2005(21):2676-2679. |
| [8] | 黄晖,罗宏杰,杨明,刘江.水热沉淀法制备TiO2纳米粉体的研究[J].硅酸盐通报,2000(04):8-12. |
| [9] | Ovenstone J. .Preparation of novel titania photocatalysts with high activity[J].Journal of Materials Science,2001(6):1325-1329. |
| [10] | 郭文华,张军剑,李钢.溶胶-凝胶法及其制备纳米TiO2粉体的原理和研究进展[J].中国陶瓷工业,2006(05):26-29. |
| [11] | 苗利利,王水利.纳米二氧化钛制备工艺的研究[J].纳米科技,2006(05):47-50. |
| [12] | 廖东亮,肖新颜,张会平,万彩霞,陈焕钦.溶胶-凝胶法制备纳米二氧化钛的工艺研究[J].化学工业与工程,2003(05):256-260. |
| [13] | 吴腊英,李长江.纳米二氧化钛粉末的溶胶-凝胶法合成及晶相转化[J].无机化学学报,2002(04):399-403. |
| [14] | Sakulkhaemaruethai S;Pavasupree S;Suzuki Y et al.Photocatalytic activity of titania nanocrystals prepared by surfactant-assisted templatin method-effect of calcination conditions[J].Materials Letters,2005,59:2965-2968. |
| [15] | Senthilkumaar S;Porkodi K;Vidyalakshmi R .Photodegradation of a textile dye catalyzed by sol-gel derived nanocrystalline TiO2 via ultrasonic irradiation[J].Journal of Photochemistry and Photobiology, A. Chemistry,2005(3):225-232. |
| [16] | 徐建春,储伟,王安,邱发礼.受控水解法制备纳米TiO2光催化剂及其结构性能[J].化学研究与应用,2005(03):389-391. |
| [17] | 陈文新,黄浪欢,刘应亮,王朋,张静娴,容建华,汤丽娜.微波法制备纳米TiO2[J].化学研究与应用,2004(05):661-663. |
| [18] | 范金山.微乳液法制备TiO2纳米粉体及其光催化性能研究[J].人工晶体学报,2006(02):347-350. |
| [19] | Stallings WE.;Lamb HH. .Synthesis of nanostructured titania powders via hydrolysis of titanium isopropoxide in supercritical carbon dioxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(7):2989-2994. |
| [20] | Lee M S;Park S S;Lee G D et al.Synthesis of TiO2 particles by reverse microemulsion method using nonionic surfactants with different hydrophilic and hydrophobic group and their photocatalytic activity[J].Catalysis Today,2005,101:283-290. |
| [21] | Yang SF.;Liu YH.;Guo YP.;Zhao JZ.;Xu HF.;Wang ZC. .Preparation of rutile titania nanocrystals by liquid method at room temperature[J].Materials Chemistry and Physics,2003(2):501-506. |
| [22] | Li Y Z;Lee N H;Lee E G et al.The characterization and photocatalytic properties of mesoporous rutile TiO2 powder synthesized through selfassembly of nanocrystals[J].Chemical Physics Letters,2004,389:124-128. |
| [23] | 陈华.TiO2纳米粉体的制备与表征[J].化工之友,2006(01):47-48. |
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