用水热法合成了具有良好结晶度和大层间距的α-磷酸钛晶体(记为α-TiP),并用XRD,HREM,IR及TG/DSC等方法对其进行了表征.得到的晶体形貌规整并具有较高的热稳定性.本实验对水热法合成α-磷酸钛的实验条件进行了系统研究,给出了优化的合成条件.研究表明,当反应体系的磷酸浓度为5 M～10 M时在180℃下反应6 h即可获得良好的α-TiP晶体.
参考文献
| [1] | Clearfield A;Stynas J A.[J].Journal of Radioanalytical and Nuclear Chemistry,1964(26):117. |
| [2] | Clearfield A;Smith G D .[J].Inorganic Chemistry,1969,8(03):431. |
| [3] | Hasegawa Y;Akinoto T;Kojima D.[J].Journal of Inclusion Phenomena and Molecular Recognition in Chemistry,1995(20):1. |
| [4] | Okuno S.;Matsubayashi GE. .PREPARATION AND SPECTROSCOPIES OF LAYERED ZIRCONIUM ORGANOPHOSPHONATES CONTAINING PYRIDINIUM AND ITS DERIVATIVE CATIONS[J].Inorganica Chimica Acta,1995(1/2):173-177. |
| [5] | Espina A.;Khainakov SA.;Trobajo C.;Garcia JR.;Rodriguez J.;Jaimez E. .Synthesis of new n-alkylamines intercalation compounds with alpha-titanium phosphate. Process selectivity and structural and morphological characterization[J].Chemistry of Materials,1998(9):2490-2496. |
| [6] | Clearfield A;Roberts B D.[J].Inorganic Chemistry,1988(27):3237. |
| [7] | Marieles-Torres P;Olivera-Pastor P;Rodriguez-Castellon E.[J].Journal of Materials Chemistry,1991(01):319,739. |
| [8] | Albert G;Gardini-Galli P;Costantino U.[J].Journal of Radioanalytical and Nuclear Chemistry,1967(29):571. |
| [9] | Albert G;Torracca E.[J].Journal of Radioanalytical and Nuclear Chemistry,1968(30):317. |
| [10] | Gerard Demazeau.[J].Journal of Materials Chemistry,1999(09):15. |
| [11] | Robert C T Slade;Jamer A Knowles .[J].Deborah J Jones et al Solid State Ionics,1997,96:9. |
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