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以Zn(CH3COO)2·2H2O(ZnAc2)为原料,采用晶种诱导生长法制备了单分散性的球形纳米ZnO,并通过种子生长法在上面负载一层纳米Au.利用透射电镜(TEM)分析了纳米ZnO@Au的形貌、并用X射线衍射(XRD)分析了其物相组成,利用紫外-可见光谱(UV-Vis)和光致发光光谱(PL)研究了其光谱特征,以罗丹明B(RB)模型污染物,在紫外光照射下评价了纳米ZnO@ Au的光催化活性.结果表明:ZnO为纤锌矿型结构,表面沉积一层金纳米微粒,形成核壳结构ZnO@Au;光催化结果显示,金沉积提高了ZnO的光催化活性.

参考文献

[1] Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96.
[2] Sun TJ;Qiu JS;Liang CH .Controllable fabrication and photocatalytic activity of ZnO nanobelt arrays[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(3):715-721.
[3] J.M. Monteagudo;A. Durán;M. Aguirre;I. San Martín .Optimization of the mineralization of a mixture of phenolic pollutants under a ferrioxalate-induced solar photo-Fenton process[J].Journal of hazardous materials,2011(1):131-139.
[4] Kwangsuk Park;Qifeng Zhang;Betzaida Batalla Garcia .Effect of Annealing Temperature on TiO2-ZnO Core-Shell Aggregate Photoelectrodes of Dye-Sensitized Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(11):4927-4934.
[5] 氧化锌空心球的制备及其光催化性能研究[J].人工晶体学报,2012(06):1722-1725.
[6] 杜锦阁,汪应灵,袁建梅.Ni2+/TiO2纳米管的光催化活性[J].人工晶体学报,2012(05):1405-1409.
[7] S. J. Pearton;D. P. Norton;K. Ip;Y. W. Heo;T. Steiner .Recent progress in processing and properties of ZnO[J].Superlattices and microstructures,2003(1/2):3-32.
[8] Eue Soon Jang;Jung-Hee Won;Seong-Ju Hwang;Jin-Ho Choy .Fine Tuning of the Face Orientation of ZnO Crystals to Optimize Their Photocatalytic Activity[J].Advanced Materials,2006(24):3309-3312.
[9] Ye CH;Bando Y;Shen GZ;Golberg D .Thickness-dependent photocatalytic performance of ZnO nanoplatelets[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(31):15146-15151.
[10] JIAGUO YU;XIAOXIAO YU .Hydrothermal Synthesis and Photocatalytic Activity of Zinc Oxide Hollow Spheres[J].Environmental Science & Technology: ES&T,2008(13):4902-4907.
[11] Lu, F;Cai, WP;Zhang, YG .ZnO hierarchical micro/nanoarchitectures: Solvothermal synthesis and structurally enhanced photocatalytic performance[J].Advanced Functional Materials,2008(7):1047-1056.
[12] Sakthivel S.;Neppolian B.;Shankar MV.;Arabindoo B.;Palanichamy M. Murugesan V. .Solar photocatalytic degradation of azo dye: comparison of photocatalytic efficiency of ZnO and TiO2[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(1):65-82.
[13] Yuanzhi Li;Wei Xie;Xuelei Hu;Guofang Shen;Xi Zhou;Ye Xiang;Xiujian Zhao;Pengfei Fang .Comparison of Dye Photodegradation and its Coupling with Light-to-Electricity Conversion over TiO_2 and ZnO[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(1):591-597.
[14] Wang CY.;Zheng X.;Chen J.;Shen T.;Liu CY. .The surface chemistry of hybrid nanometer-sized particles - I. Photochemical deposition of gold on ultrafine TiO2 particles[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1998(1/3):271-280.
[15] J. -M. Herrmann;H. Tahiri;Y. Ait-Ichou;G. Lassaletta;A. R. Gonzalez-Elipe;A. Fernandez .Characterization and photocatalytic activity in aqueous medium of TiO_2 and Ag-TiO_2 coatings on quartz[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1997(3/4):219-228.
[16] 王英连,YE Jun-yao,吴汉水,HU Yue-hui.Ag掺杂ZnO薄膜光催化降解苯酚的试验研究[J].人工晶体学报,2008(04):1033-1036.
[17] Zhengrong R.Tian;James A.Voigt;Jun Liu;Bonnie Mckenzie;Matthew J.Mcdermott;Mark A.Rodriguez;Hiromi Konishi;Huifang Xu .Complex and oriented ZnO nanostructures[J].Nature materials,2003(12):821-826.
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