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壳聚糖是一种具有生物相容性、无毒性、抑菌性等诸多优良性能的成膜材料,吸附性的壳聚糖微滤(MF)膜和超滤(UF)膜已在废水污染物的分离方面展示出巨大的应用潜力.但是,壳聚糖膜的机械性能较差、遇酸易水解等缺点限制了它的应用范围.基于壳聚糖分子表面含有丰富的羟基、氨基等活性基团而易于改性的特点,近年来研究人员采用多种方法改变壳聚糖的化学组成及其表面性质,以便使壳聚糖膜适合特定的应用需要.对在废水处理领域有特殊应用的5种改性壳聚糖膜(交联壳聚糖膜、壳聚糖季铵盐复合膜、壳聚糖共混膜、有机-无机杂化壳聚糖膜、香草醛改性壳聚糖膜)的制备方法、原理和应用效果进行了综述,并提出了进一步研究的方向.

参考文献

[1] 郎雪梅,侯有军,赵建青.壳聚糖作为分离膜材料的研究进展[J].化工进展,2005(07):737-742.
[2] Ge J J;Cui Y F;Yan Y et al.The effect of structure on pervaporation of chitosan membrane[J].Journal of Membrane Science,2000,165:75.
[3] 胡宗智,张堃,林木良,林少琨.壳聚糖改性膜材料的研究(Ⅰ)--壳聚糖与聚乙烯醇共混[J].广州化工,2002(04):5-7.
[4] 刘文辉,刘晓亚,杨成,陈明清.光交联壳聚糖/聚乙烯醇共混膜的制备与性能[J].无锡轻工大学学报,2002(04):384-388.
[5] Rodrigo S V;Marisa M B .Interaction of natural and crosslinked chitosan membranes with Hg (Ⅱ) ions[J].Colloids and Surfaces A:Physicochemical and Engineering,2006,279:196.
[6] 郑化,杜予民,余家会,肖玲.交联壳聚糖膜的制备及其性能的研究[J].高等学校化学学报,2000(05):809-812.
[7] 陈晓.交联壳聚糖膜对偶氮染料的吸附性能研究[J].福建师范大学学报(自然科学版),2006(03):59-62,108.
[8] 周亚光;翟秀静;祝立英 .壳聚糖交联膜电渗析法分离氟、氯、砷的研究[J].分子科学学报,1998,14(01):40.
[9] 李铭,葛英勇.甲壳素、壳聚糖的改性研究[J].杭州化工,2004(02):1-7.
[10] 汪玉庭,刘玉红,张淑琴.甲壳素、壳聚糖的化学改性及其衍生物应用研究进展[J].功能高分子学报,2002(01):107-114.
[11] 叶筠,蔡伟民,沈雄飞.壳聚糖季铵盐的合成及其对炼油废水的絮凝和灭菌性能[J].福州大学学报(自然科学版),2000(04):108-111.
[12] 曾振辉 .对pH值敏感的聚氨酯系共混膜的制备与表征[D].福州大学,2005.
[13] Huang RH;Chen GH;Sun MK;Hu YM;Gao CJ .Studies on nanofiltration membrane formed by diisocyanate cross-linking of quaternized chitosan on poly (acrylonitrile) (PAN) support[J].Journal of Membrane Science,2006(1/2):237-244.
[14] 徐伟伟 .多孔壳聚糖膜的性能表征及其应用[D].保定:河北大学,2006.
[15] 周宏伟 .壳聚糖季铵盐的制备及其膜透气性的研究[D].广西大学,2004.
[16] Nan Li;Renbi Bai .Copper adsorption on chitosan-cellulose hydrogel beads:behaviors and mechanisms[J].Separation and Purification Technology,2005(3):237-247.
[17] 杜春慧,陈建勇.丝素--壳聚糖共混膜物性的研究[J].丝绸,2002(01):9-11.
[18] Liu CX;Bai RB .Adsorptive removal of copper ions with highly porous chitosan/cellulose acetate blend hollow fiber membranes[J].Journal of Membrane Science,2006(1/2):313-322.
[19] Han W;Liu C;Bai R .A novel method to prepare high chitosan content blend hollow fiber membranes using a non-acidic dope solvent for highly enhanced adsorptive performance[J].Journal of Membrane Science,2007(1/2):150-159.
[20] Liu C X;Bai R B .Preparation of chitosan/cellulose acetate blend hollow fibers for adsorptive performance[J].Journal of Membrane Science,2005,267:68.
[21] 张广禄.1997年世界活性炭概况[J].林产化工通讯,1999(01):7.
[22] 陈桂娥;许振良;施亚钧 .湿法纺制PEI/PES中空纤维气体分离共混膜[J].华东理工大学学报,1999,125(02):208.
[23] 强志斌 .壳聚糖的制备与应用初步[D].上海:东华大学,2006.
[24] Zheng J P;Wang C Z;Wang X X et al.Preparation of biomimetic three-dimensional gelatin/montmorillonite-chitosan scaffold for tissue engineering[J].Reactive and Functional Polymers,2007,67:780.
[25] 沈锋,杨丽芳,成国祥,董向红,姚康德,吕晓龙,魏建敏.壳聚糖-聚醚共混超滤膜的制备与性能[J].天津大学学报,2000(03):404-406.
[26] Nakajima K;Tomita I;Hara M et al.Stable and highly active Ph-SO3 functionalized hybrid mesoporous acid catalyst[J].Studies in surface science and catalysis,2005,158(02):1485.
[27] Xi FN;Wu JM;Lin XF .Novel nylon-supported organic-inorganic hybrid membrane with hierarchical pores as a potential immobilized metal affinity adsorbent[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2006(1):38-51.
[28] Nagarale R K;Gohil G S;Shahi V et al.Preparation and electrochemical characterizations of cation-exchange membranes with different functional groups[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,251:133.
[29] Antonio R;Eunice F;Vieira J et al.Determination of kinetic parameters of Cu(Ⅱ) interaction with chemically modified thin chitosan membranes[J].Journal of Colloid and Interface Science,2005,285:288.
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