以钨粉为主要原料,采用过氧化法及提拉技术制备WO3薄膜,通过SiO2纳米颗粒复合改性提高了WO3薄膜的气致变色稳定性.测试并研究了SiO2复合掺杂对溶胶颗粒分布、气致变色稳定性等的影响,通过测试薄膜循环中红外振动吸收的演变,深入研究了SiO2纳米复合对WO3薄膜气致变色性能影响的内在机制.研究结果表明,SiO2的掺杂抑制了WO3薄膜内的共角聚合,将薄膜的致/褪色循环次数由20次提高到500次以上,WO3-SiO2复合薄膜的稳定网络结构是提高其气致变色循环稳定性的主要原因.
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