采用溶胶凝胶法制备Si/TiO2复合材料具有操作简单、包覆层致密均匀、电化学性能稳定等优点,成为目前最常用Si/TiO2的制备方法之一.本文综述了Si/TiO2复合结构对电化学性能的影响,论述了溶胶凝胶制备过程中影响该复合材料电化学性能的影响因素.为进一步提高Si/TiO2复合材料的电化学性能的研究提供了理论依据和建议.
参考文献
| [1] | 张瑞;姜训勇.金属硅的储锂性能[J].硅酸盐学报,2013(2):159-164. |
| [2] | Titirici MM;Antonietti M;Thomas A.A generalized synthesis of metal oxide hollow spheres using a hydrothermal approach[J].Chemistry of Materials: A Publication of the American Chemistry Society,200616(16):3808-3812. |
| [3] | Wagemaker M.;Kearley GJ.;van Well AA.;Mutka H.;Mulder FM..Multiple li positions inside oxygen octahedra in lithiated TiO2 anatase[J].Journal of the American Chemical Society,20033(3):840-848. |
| [4] | Wang DH;Choi DW;Yang ZG;Viswanathan VV;Nie ZM;Wang CM;Song YJ;Zhang JG;Liu J.Synthesis and Li-Ion insertion properties of highly crystalline mesoporous rutile TiO2[J].Chemistry of Materials: A Publication of the American Chemistry Society,200810(10):3435-3442. |
| [5] | Chan CK;Peng HL;Liu G;McIlwrath K;Zhang XF;Huggins RA;Cui Y.High-performance lithium battery anodes using silicon nanowires[J].Nature nanotechnology,20081(1):31-35. |
| [6] | 杨依隆;辛秀兰;胡代强;秦省军.溶胶-凝胶法制备TiO2凝胶的影响因素及方法改进[J].北京工商大学学报（自然科学版）,2007(3):9-13. |
| [7] | Xiaoge Li;Ying Bai;Dong Yan;Caiyan Yu;Kai Jiang;Ning Wan;Qing Wu;Shuwei Sun;Weifeng Zhang.Preparation and electrochemical properties of TiO_2/C/Si composites for lithium ion batteries[J].Materials Letters,2014Jul.1(Jul.1):295-298. |
| [8] | Yuanqing Yang;Ying Bai;Sen Zhao.Electrochemical performances of Si/TiO_2 composite synthesized by hydrothermal method[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2013:7-11. |
| [9] | 李晓歌 .硅基复合锂离子电池负极材料的制备与电化学性能研究[D].河南大学,2014. |
| [10] | Zhen Wei;Ruoshi Li;Tao Huang;Aishui Yu.Fabrication and electrochemical properties of Si/TiO_2 nanowire array composites as lithium ion battery anodes[J].Journal of Power Sources,2013Sep.15(Sep.15):165-172. |
| [11] | 魏臻 .TiO2纳米线阵列的合成及在太阳能电池、锂离子电池领域的应用[D].复旦大学,2013. |
| [12] | 麦凯光 .Si@TiO2复合蛋黄-蛋壳结构锂离子电池负极材料研究[D].浙江大学,2014. |
| [13] | Elmira Memarzadeh Lotfabad;Peter Kalisvaart;Alireza Kohandehghan.Si nanotubes ALD coated with TiO2, TiN or Al2O3 as high performance lithium ion battery anodes[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20148(8):2504-2516. |
| [14] | Elmira Memarzadeh Lotfabad;Peter Kalisvaart;Kai Cui.ALD TiO2 coated silicon nanowires for lithium ion battery anodes with enhanced cycling stability and coulombic efficiency[J].Physical chemistry chemical physics: PCCP,201332(32):13646-13657. |
| [15] | Zheng Huang;Pin-Ching Maness;Daniel M. Blake;Edward J. Wolfrum;Sharon L. Smolinski;William A. Jacoby.Bactericidal mode of titanium dioxide photocatalysis[J].Journal of Photochemistry and Photobiology, A. Chemistry,20002/3(2/3):163-170. |
| [16] | Kibum Kang;Hyun-Seung Lee;Dong-Wook Han;Gil-Sung Kim;Donghun Lee;Geunhee Lee;Yong-Mook Kang;Moon-Ho Jo.Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery[J].Applied physics letters,20105(5):053110-1-053110-3. |
| [17] | Vijay A. Sethuraman;Kristin Kowolik;Venkat Srinivasan.Increased cycling efficiency and rate capability of copper-coated silicon anodes in lithium-ion batteries[J].Journal of Power Sources,20111(1):393-398. |
| [18] | Sang-Eun PARK;Bo-Eun KIM;Sang-Wha LEE;Joong-Kee LEE.Employment of encapsulated Si with mesoporous TiO2 layer asanode material for lithium secondary batteries[J].中国有色金属学报（英文版）,2009(04):1023-1026. |
| [19] | Zhijia Du;Shichao Zhang;Yi Liu.Facile fabrication of reticular polypyrrole-silicon core-shell nanofibers for high performance lithium storage[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201223(23):11636-11641. |
| [20] | Shan Fang;Laifa Shen;Guiyin Xu.Rational Design of Void-Involved Si@TiO2 Nanospheres as High-Performance Anode Material for Lithium-Ion Batteries[J].ACS applied materials & interfaces,20149(9):6497-6503. |
| [21] | 曾志远 .锂离子电池硅基纳米复合薄膜负极材料的制备、结构和电化学性能[D].浙江大学材料与化学工程学院,2008. |
| [22] | Bo Eun Kim;Sang Eun Park;Sangwha Lee.Porous TiO_2 Layer Encapsulated Silicon as the Anode Material for Lithium Secondary Batteries[J].Materials Science Forum,2009:29-32. |
| [23] | 王瑶 .硅基复合锂离子电池负极材料的制备及性能研究[D].湘潭大学,2014. |
| [24] | Hiroyuki Usui;Kuniaki Wasada;Masahiro Shimizu;Hiroki Sakaguchi.TiO_2/Si composites synthesized by sol-gel method and their improved electrode performance as Li-ion battery anodes[J].Electrochimica Acta,2013:575-580. |
| [25] | Hu J;Li H;Huang XJ.Influence of micropore structure on Li-storage capacity in hard carbon spherules[J].Solid state ionics,200511/12(11/12):1151-1159. |
| [26] | Zeng, ZY;Tu, JP;Huang, XH;Wang, XL;Zhao, XB;Li, KF.Electrochemical properties of a mesoporous Si/TiO2 nanocomposite film anode for lithium-ion batteries[J].Electrochemical and solid-state letters,20086(6):A105-A107. |
| [27] | Hemeryck A;Richard N;Esteve A;Djafari Rouhani M.Diffusion of oxygen atom in the topmost layer of the Si(100) surface: Structures and oxidation kinetics[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,200711(11):2339-2343. |
| [28] | 刘蓉芳 .锂离子电池负极材料TiO2纳米管阵列和TiO2@Si薄膜的制备及电化学性能研究[D].南开大学,2011. |
| [29] | 杨元青 .锂离子电池Si基复合材料Si/TiO2及Si/TiO2/C的制备和电化学性能研究[D].河南大学,2013. |
| [30] | Qingliu Wu;Toan Tran;Wenquan Lu;Ji Wu.Electrospun silicon/carbon/titanium oxide composite nanofibers for lithium ion batteries[J].Journal of Power Sources,2014Jul.15(Jul.15):39-45. |
| [31] | 魏来;刘开宇;李艳;吕美玉;钟剑剑.锂离子电池负极硅/碳复合材料的制备及其性能研究[J].湖南师范大学自然科学学报,2014(2):33-39. |
| [32] | Mizuhata, Minoru;Katayama, Akihito;Maki, Hideshi.On-site fabrication and charge-discharge property of TiO2 coated porous silicon electrode by the liquid phase deposition with anodic oxidation[J].Journal of Fluorine Chemistry,2015:62-69. |
| [33] | Edward Buiel;J. R. Dahn.Li-insertion in hard carbon anode materials for Li-ion batteries[J].Electrochimica Acta,19991/2(1/2):121-130. |
| [34] | 闫冬 .锂离子电池Si-TiO2纳米复合负极材料的结构设计与优化[D].河南大学,2014. |
| [35] | Masashi Uematsu;Marika Gunji;Masaru Tsuchiya;Kohei M. Itoh.Enhanced oxygen exchange near the oxide/silicon interface during silicon thermal oxidation[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,200716(16):6596-6600. |
| [36] | 董素芳;赵素梅.溶胶-凝胶法制备二氧化钛凝胶的影响因素分析[J].现代技术陶瓷,2005(3):10-12. |
| [37] | 张锐;秦丹丹;王海龙;许红亮.溶胶凝胶法制备SiO2工艺[J].郑州大学学报（工学版）,2006(3):119-122. |
| [38] | 孟瑞晋;侯宏英;刘显茜;段继祥;刘松.煅烧温度对二氧化钛纳米管阵列的微观结构及锂电性能的影响[J].硅酸盐学报,2015(6):817-822. |
| [39] | Yoon Seok Jung;Kyu T. Lee;Seung M. Oh.Si-carbon core-shell composite anode in lithium secondary batteries[J].Electrochimica Acta,200724(24):7061-7067. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%