以金属粉末、粘结剂为原料,经炼料制成膏状挤压料,通过挤压模成型为蜂窝状,再经高温烧结制备成316L不锈钢蜂窝。研究了烧结气氛、烧结温度对蜂窝烧结组织结构的影响,并对烧结后的蜂窝进行力学性能测试。结果表明,在氢气中烧结的316L蜂窝组织,金属颗粒间形成烧结颈,呈网状连接在一起,并随温度升高颗粒合并长大成晶粒,基体组织为Fe-Cr-Ni-C(γ-Fe)固溶体,第二相球形颗粒为富含硅的低熔点化合物;在真空中烧结,金属颗粒表面形成氧化物Fe2 Cr4 O4、Cr2 O3,以及SiO2,大量的表面氧化物阻碍了金属粉末颗粒的结合,直接影响烧结蜂窝的强度,致使烧结蜂窝强度远低于氢气中烧结的蜂窝。在氢气中烧结的316L金属蜂窝,其径向抗压强度可达40~50 MPa,远高于目前广泛应用的陶瓷蜂窝载体,是作为载体材料的一种理想选择。
Pure 316L powder is used to mix with an additive to prepare a powder mixed paste by which the 316L stainless honeycombs are extruded through a die, then dried and sintered at high temperature. The effect of sintering atmosphere and sintering temperature on the microstructure of honeycombs has been studied, and mechanical property is measured by radial compression. The results show that the metal particles sintered in hydrogen atmosphere contact to form sintering neck, and with the temperature increase, the particles merge into a grain, the microstructure of sintering honeycombs is composed of γ-Fe matrix and second phase of spherical particles of low melting point compounds containing silicon. If sintered in vacuum, the oxides of Fe2 Cr4 O4 , Cr2 O3 , and SiO2 form on the surface of metal particles to stop the combination of metal powder particles, so the honeycomb strength is much lower than that in the hydrogen atmosphere. The strength of 316L metal honeycomb sintered in hydrogen atmosphere reaches 40~50 MPa, far higher than that of ceramic honeycomb used current widely. The 316L metal honeycomb is a kind of ideal material for catalytic carrier.
参考文献
[1] | 章海峰.汽油车催化器载体技术的研究进展[J].内燃机,2013(02):1-4,7. |
[2] | 金家敏, 包伟芳 .再论载体材料与贵金属催化剂[J].材料导报,2012,26(3):52-61. JIN Jiamin, BAO Weifang. Further discussion on the relation between support materials and noble metal catalysts[J].Materials Review, 2012,26(3):52-61.,2012. |
[3] | 王建强,王远,刘双喜,高继东,马杰,高海洋.柴油车氧化催化技术研究进展[J].科技导报,2012(25):68-73. |
[4] | TAKASHITsuchiya,TADASHIGoto,NOBUYUKIKakiya, et al. Metal honeycomb-shaped catalyzer carrier [P]. US Patent:No7947624, 2011-05-24.,2011. |
[5] | 刘玉凤.蜂窝密封结构在小型汽轮机上的应用[J].炼油与化工,2012(04):52-52,53. |
[6] | 樊卓志,孙勇,彭明军,王堃.基于ANSYS的金属蜂窝板热性能模拟研究[J].航空材料学报,2012(05):70-74. |
[7] | JAKUSA,FREDENBURGA,THADHANIN .High-strain-rate behavior of mar aging steel linear cellular alloys:Mechanical deformations[J].Materials Science and Engineering A,2012,534 |
[8] | 李宇,李永峰,吴青青,刘祖超,余林,余倩.金属基体整体式催化剂的制备及在VOCs催化燃烧中的应用研究进展[J].化工进展,2011(04):759-765,776. |
[9] | YUKIHITOIchikawa,TOSHIHIKOHijikata,MAKO-TO Miyazaki. Corrugated wall honeycomb structure and productionmethod thereof [P]. EP Patent:No 1125704B2, 2011-05-10.,2011. |
[10] | 张振强,桓源峰,贺小昆,赵云昆.预处理条件对摩托车尾气催化剂金属载体负载活性涂层的影响[J].贵金属,2009(01):26-33. |
[11] | CORBETT D W. MILLER T M. Honeycomb extrusion die apparatus [P]. US Patent. No 8435025, 2013-05-07.,2013. |
[12] | FABER M K. LAWRENCE R G. Durable honeycomb structures [P]. US Patent. No 8454886, 2013-06-04.,2013. |
[13] | MERKEL G A. Fine porosity low-microcracked ceramic honeycombs and methods thereof [P]. US Patent, No 8377370, 2013-02-19.,2013. |
[14] | DIAL Laura C, Thomas SANDERS H Jr, COCHRAN Joe K. The gas carburization of linear cellular alloys as a novel alloy development tool [J]. Metallurgical and Materials Transactions, 2012, 43:1303-1311.,2012. |
[15] | CHURCH B C, SANDERS T, COCHRAN J, et al. Interconnect thermal expansion matching to solid of oxide fuel cells [J]. Journals of Materials Science, 2005, 40(18):4893-4898.,2005. |
[16] | 杜玉洁,周芸,左孝青.汽车尾气净化器载体的研究现状及发展[J].材料导报,2012(21):66-69. |
[17] | YUN Zhou, HUANG Peng, MENG Xuan, et al . The Microstructure and properties of 304L stainless honeycombs fabricated by extruding and sintering[J].Advanced Materials Research,2012,393 |
[18] | 王芙蓉,孙凤礼,高山.汽车尾气净化用蜂窝状催化剂的研究[J].材料工程,2003(02):41-42,47. |
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