本文采用基于特征值分析的骨架机理简化方法,对于航空煤油替代燃料正癸烷(118组分527反应)和正丙基环己烷(106组分382反应)氧化反应机理进行了简化,分别得到68组分302反应和67组分250反应骨架机理.采用骨架机理进行了着火延迟和火焰传播速度动力学模拟,并与详细机理计算结果进行了对比,结果表明,骨架机理具有较高的计算精度,该方法对于高碳氢燃料的详细机理简化具有较好的效果.
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