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采用了N-乙酰-L-半胱氨酸为稳定剂,通过水热法制备了荧光发射峰可调、粒径均匀且结晶性能良好的ZnxCd1-xSe合金量子点,并采用紫外-可见光吸收光谱(UV-Vis)、荧光光谱(PL)、X射线衍射(XRD)、高分辨透射电镜(HRTEM)等对其结构和性能进行了表征。重点研究了Cd2+/Zn2+比值、初始溶液pH值、水热反应温度和时间等实验条件对ZnxCd1-xSe量子点荧光性能的影响。研究表明所制备的量子点荧光量子产率高(35%),荧光发射谱半峰宽窄(FWHM〈50nm),有望作为生物荧光标记物。

In this paper,ZnxCd1-xSe quantum dots with tunable photoluminescence emission,uniform particle size and good crystallinity were synthesized by hydrothermal method,in which N-acetyl-L-crysteine was used as a stabilizer.UV-Vis absorption spectroscopy(UV-Vis),photoluminescence(PL) spectroscopy,X-ray diffraction(XRD) spectroscopy,and high-resolution transmission electron microscopy were used to characterize their structures and properties.The effects of Cd2+/Zn2+ ratio,pH of the precursor solution,hydrothermal temperature and time on the photoluminescence properties of ZnxCd1-xSe quantum dots were significantly investigated in the present work.The results showed that the obtaining quantum dots possessed high photoluminescence yield(up to 35%) and narrow fluorescence full-width(FWHM50nm).Therefore,the ZnxCd1-xSe quantum dots would be a promising fluorescent probe for biological and biomedical imaging.

参考文献

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[2] 李众,祝欣,董朝青,黄香宜,陈虹锦,任吉存.荧光量子点的水相合成及其在化学和生物分析中的应用[J].高等学校化学学报,2010(10):1905-1915.
[3] Kirchner C;Liedl T;Kudera S;Pellegrino T;Javier AM;Gaub HE;Stolzle S;Fertig N;Parak WJ .Cytotoxicity of colloidal CdSe and CdSe/ZnS nanoparticles[J].Nano letters,2005(2):331-338.
[4] 谢万兴,王德平,吴立功,姚爱华,黄文旵,郁美娟.CdS/CdSe核壳结构半导体纳米晶结构及光谱特性[J].硅酸盐学报,2009(02):219-224.
[5] 吴立功,王德平,姚爱华,谢万兴,黄文旵.水热法制备细胞标记用CdSe半导体量子点材料[J].硅酸盐学报,2009(09):1580-1584.
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