具有黄铜矿结构的CuInSe2 (CIS)类薄膜太阳电池随着其转换效率的进一步提高,受到日益广泛的关注.相对于CIS材料,Cu(InAl) Se2(CIAS)具有更高的禁带宽度,可用比Ga合金更小的相对浓度来实现更可观的带隙,CIAS有望取代CIS成为薄膜太阳电池的新型材料.结合最新研究进展论述了CIAS薄膜材料的不同制备方法及合成机理,并讨论了目前CIAS太阳电池研究中存在的问题和今后的发展方向.
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