欢迎登录材料期刊网

材料期刊网

高级检索

将纳米TiO2和微米ZnO机械搅拌,制备了纳米TiO2/ZnO复合粒子.通过硬脂酸对其改性,于200℃下烘烤15 min,在钢试片上得到纳米TiO2/ZnO复合超疏水涂层.采用扫描电镜、红外光谱和接触角分析仪对涂层表面的形貌和疏水性进行了表征.结果表明,复合粒子经硬脂酸表面改性后引入了疏水性的甲基,形成微/纳米双重粗糙结构.当硬脂酸含量为9%时,所得涂层表面与水的静态接触角为165.3,滚动角4°.该涂层具有优异的耐溶解性、耐温性及自清洁性.

参考文献

[1] Lingling Wang;Xintong Zhang;Bing Li .Superhydrophobic and Ultraviolet-Blocking Cotton Textiles[J].ACS applied materials & interfaces,2011(4):1277-1281.
[2] 勾昱君,刘中良,王皆腾,程水源.自然对流条件下仿生超疏水表面的抑霜研究[J].工程热物理学报,2007(04):631-633.
[3] 张友法,余新泉,周荃卉,李康宁.超疏水低粘着铜表面制备及其防覆冰性能[J].物理化学学报,2010(05):1457-1462.
[4] XI J M;JIANG L .Biomimic superhydrophobic surface with hígh adhesive forces[J].Industrial and Engineering Chemistry Research,2008,47(17):6354-6357.
[5] Lin Feng;Shuhong Li;Yingshun Li;Huanjun Li;Lingjuan Zhang;Jin Zhai;Yanlin Song;Biqian Liu;Lei Jiang;Daoben Zhu .Super-Hydrophobic Surfaces: From Natural to Artificial[J].Advanced Materials,2002(24):1857-1860.
[6] Darmanin, T.;De Givenchy, E.T.;Amigoni, S.;Guittard, F. .Hydrocarbon versus fluorocarbon in the electrodeposition of superhydrophobic polymer films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(22):17596-17602.
[7] Song XY;Zhai J;Wang YL;Jiang L .Fabrication of superhydrophobic surfaces by self-assembly and their water-adhesion properties[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(9):4048-4052.
[8] Huan Liu;Lin Feng;Jin Zhai;Lei Jiang;Daoben Zhu .Reversible Wettability of a Chemical Vapor Deposition Prepared ZnO Film between Superhydrophobicity and Superhydrophilicity[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(14):5659-5661.
[9] 狄志勇,何建平,周建华,孙盾,王涛.有机-无机自组装制备类荷叶结构超疏水涂层及其性能研究[J].无机材料学报,2010(07):765-769.
[10] Qinwen Gao;Quan Zhu;Yuliang Guo .Formation of Highly Hydrophobic Surfaces on Cotton and Polyester Fabrics Using Silica Sol Nanoparticles and Nonfluorinated Alkylsilane[J].Industrial & Engineering Chemistry Research,2009(22):9797-9803.
[11] Hsieh CT;Chen JM;Kuo RR;Lin TS;Wu CF .Influence of surface roughness on water- and oil-repellent surfaces coated with nanoparticles[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/4):318-326.
[12] Guo, Z.;Chen, X.;Li, J.;Liu, J.-H.;Huang, X.-J. .ZnO/CuO hetero-hierarchical nanotrees array: Hydrothermal preparation and self-cleaning properties[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(10):6193-6200.
[13] A single TiO2-coated side-glowing optical fiber for photocatalytic wastewater treatment[J].科学通报(英文版),2005(18):1979-1984.
[14] A. Perez-Larios;R. Lopez;A. Hernandez-Gordillo;F. Tzompantzi;R. Gomez;L.M. Torres-Guerra.Improved hydrogen production from water splitting using TiO_2-ZnO mixed oxides photocatalysts[J].Fuel,2012:139-143.
[15] 吴洁,余新泉,张友法,周荃卉.铝合金表面构建超疏水性的化学改性机理[J].东南大学学报(自然科学版),2011(05):1036-1041.
[16] Wang, Y.;Li, B.;Xu, C. .Fabrication of superhydrophobic surface of hierarchical ZnO thin films by using stearic acid[J].Superlattices and microstructures,2012(1):128-134.
[17] 赵宁,卢晓英,张晓艳,刘海云,谭帅霞,徐坚.超疏水表面的研究进展[J].化学进展,2007(06):860-871.
[18] 郑燕升,何易,青勇权,卓志昊,莫倩.SiO_2/聚四氟乙烯杂化超疏水涂层的制备[J].化工进展,2012(07):1562-1566.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%