与六价铬电镀铬相比，三价铬电镀具有很多优异特性，但在实际应用中也存在一些问题，其可镀性和镀厚性受到一定限制。因此，三价铬功能性电镀铬还没有被广泛应用。介绍了三价铬电镀存在的主要问题及其解决途径，提出了有待深入研究的问题以及今后的发展方向。
参考文献
| [1] | 屠振密,李宁,于元春.电镀清洁生产的途径[J].电镀与精饰,2005(05):30-34. |
| [2] | 屠振密,郑剑,李宁,李永彦.三价铬电镀铬现状及发展趋势[J].表面技术,2007(05):59-63,87. |
| [3] | M.El-Sharif .Replacing hexavalent chromium in electroplating[J].Transactions of the Institute of Metal Finishing,1997(6):B143-B147. |
| [4] | 胡晓谮,屠振密,李永彦,孙化松,李宁.氯化物三价铬电镀液中六价铬离子的去除方法及效果[J].材料保护,2009(02):74-76. |
| [5] | 胡晓赞;屠振密;李永彦 等.硫酸盐体系三价铬镀液中六价铬离子的积累与去除[J].电镀与涂饰,2009,28(04):4-7. |
| [6] | 王秋红,胡光辉,潘湛昌,古晓雁,肖楚民,徐波.三价铬电镀液中金属杂质离子浓度对镀层质量的影响及其处理效果[J].材料保护,2011(03):60-61,80. |
| [7] | 孙化松 .实用硫酸盐电镀工艺研制及阴极过程的探讨[D].哈尔滨:哈尔滨工业大学,2009. |
| [8] | 孙化松,屠振密,李炳江,李宁,李永彦.Fe2+对硫酸盐三价铬镀液镀铬的影响[J].电镀与精饰,2009(09):5-8. |
| [9] | Snyder D L .Distinguishing trivalent deposits by color[J].Plating and Surface Finishing,2003,90(11):34-39. |
| [10] | 李永彦 .硫酸盐体系电镀三价铬工艺特性及阴极过程的研究[D].哈尔滨工业大学,2008. |
| [11] | 屠振密;李宁;胡会利.绿色环保电镀技术[M].北京:化学工业出版社,2012:144. |
| [12] | 李宁,屠振密,毕四富,胡会利,李炳江,孙化松.环保型三价铬电镀新工艺(TRI-08)特性及维护[C].2009年全国电子电镀及表面处理学术交流会论文集,2009:235-238. |
| [13] | Y. B. Song;D. -T. Chin .Current efficiency and polarization behavior of trivalent chromium electrodeposition process[J].Electrochimica Acta,2002(4):349-356. |
| [14] | 杜荣斌,刘涛,姜效军.氟化物电沉积铬中十八烷基三甲基氯化铵的阻氢作用[J].电镀与涂饰,2009(08):6-8. |
| [15] | Tu Z M;Yang Z L .Cathode Polarization in Trivalent Chro- mium Plating[J].Plating and Surface Finishing,1993,80(09):78-82. |
| [16] | Ibrahim S K;Waston A;Gawne D T .The Role of Formic Acid and Methanol on Speciation Rate and Quality in the Electrodeposition of Chromium from Trivalent Electrolytes[J].Transactions of the Institute of Metal Finishing,1997,75(05):181-188. |
| [17] | Tomaszewski T W;Tremmel R A;Rudolph L T .Trivalent chromium electroplating process[P].US,4466865,1984-08-21. |
| [18] | 李保松,林安,甘复兴.三价铬电沉积的动力学数学模型[J].武汉大学学报（理学版）,2007(02):184-188. |
| [19] | G. Hong;K.S.Siow;G.Zhiqiang .Hard Chromium Plating From Trivalent Chromium Solution[J].Plating & Surface Finishing,2001(3):69-75. |
| [20] | Tu Z M;Yang Z L;Zhang J S .Pulse Plating with a Tri- valent Chromium Plating Bath[J].Plating and Surface Finishing,1990,77(10):55-57. |
| [21] | R.P. Renz;J.J. Fortman;E.J. Taylor .Electrically Mediated Process For Functional Trivalent Chromium To Replace Hexavalent Chromium: Scale-up for Manufacturing Insertion[J].Plating & Surface Finishing,2003(6):52-58. |
| [22] | Ibrahim S K;Gawne D T;Watson A .Corrosion and Wear Resistance of Thick Chromium Deposits from Accelerated Cr(III ) Electrolytes[J].Transactions of the Institute of Metal Finishing,1998,76(04):156-161. |
| [23] | Nam K S;Lee K H;Kwon S C et al.Improved wear and corrosion resistance of chromium(III) plating by oxynitro- carburising and steam oxidation[J].Materials Letters,2004,58(27/28):3540-3544. |
| [24] | Hamid ZA;Ghayad IM;Ibrahim KM .Electrodeposition and characterization of chromium-tungsten carbide composite coatings from a trivalent chromium bath[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2005(6):573-579. |
| [25] | 江琳才.铬（Ⅲ）离子的阴极还原过程研究[J].高等学校化学学报,1989(05):551. |
| [26] | 凌莫育;江琳才.一种含双络合剂的三价铬镀液研究[J].华南师范大学学报,1985(01):140-146. |
| [27] | 李国华,赖奂汶,黄清安.三价铬镀液中配体的作用[J].材料保护,2005(12):44-46. |
| [28] | 屠振密.三价铬电镀机理的研究--铬层不能增厚的原因[J].材料保护,1985(03):14. |
| [29] | 杜登学.甲酸盐-乙酸盐体系三价镀铬的再研究[J].材料保护,1998(05):14. |
| [30] | Szynkarczuk J;Drela I;Kubicki J .Electrochemical be- haviour of chromium(III ) in the presence of formic acid[J].Electrochimica Acta,1989,34(03):399-403. |
| [31] | Hsieh A K;Ee Y H;Chen K N .Electrochemistry of chromium deposition from thiocyanate trivalent system[J].Metal Finishing,1993,91(04):53-57. |
| [32] | 屠振密;李宁;胡会利.电沉积纳米晶材料技术[M].北京:国防工业出版社,2008:10. |
| [33] | Zhixiang Zeng;Liping Wang;Aimin Liang;Junyan Zhang .Tribological and electrochemical behavior of thick Cr-C alloy coatings electrodeposited in trivalent chromium bath as an alternative to conventional Cr coatings[J].Electrochimica Acta,2006(3):1366-1373. |
| [34] | 张胜利,朱玉法,冯绍彬,夏守禄,王茂林.三价铬体系铬-镍合金电镀工艺及镀层性能的研究[J].材料保护,2005(05):35-37. |
| [35] | 李惠东;李敏;李惠琪 .电沉积非晶态Cr-Fe合金镀层研究[J].材料保护,1997,30(07):7-9. |
| [36] | 于元春,屠振密,郝照辉,李宁,毕四富.三价铬镀液电沉积装饰性铬-磷合金层的特性[J].材料保护,2011(01):46-48. |
| [37] | Li BS;Lin A;Gan FX .Preparation and characterization of Cr-P coatings by electrodeposition from trivalent chromium electrolytes using malonic acid as complex[J].Surface & Coatings Technology,2006(6):2578-2586. |
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