The main results obtained from the experimental and engineering investigation on the heat evolution and cracking risk of a furnace concrete block were presented. The heat evolution of experimental mortars containing micro-slag under different environmental temperatures was instrumented in order to investigate the self-catalyzed effect, which was discovered in engineering. Moreover, the thermal stress of the furnace concrete due to heat temperature rise was calculated to evaluate the cracking risk of mass concrete containing micro-slag due to self-catalyzed effect. The experimental results illustrate that with the development of hydration and initial temperature of mixture, the hydration can be also accelerated and temperature of concrete will be continued to rise, which was the self-catalyzed effect. And the thermal stress due to self-catalyzed effect could not result in the cracking of furnace concrete.
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