采用多弧离子镀技术和Ti-Al合金靶及Zr单质靶的组合,在高速钢基体上制备了(Ti,Al,Zr)N多元N梯度硬质反应膜.分别用扫描电镜、X射线衍射仪观察测定(Ti,Al,Zr)N梯度膜膜层的表面、断面形貌、成分以及相结构,研究了(Ti,Al,Zr)N多元氮梯度硬质反应膜的组织结构和性能.结果表明,与TiN、(Ti,Al)N、(Ti,Zr)N及(Ti,Al,Zr)N等单层硬质膜相比,采用Ti-Al合金靶及单质Zr靶组合方式制备的(Ti,Al,Zr)N多元氮梯度硬质反应膜具有较高的硬度和膜/基附着力,硬度最高可达HV6000,膜/基附着力大于180 N.同时,膜层还具有良好的抗热震性能.
参考文献
[1] | L.A.Dobrza(n)ki,L.W.Zkowska,J.Mikula,K.Golombek,D.Pakul,M.Pancielejko,Structure and mechanical properties of gradient PVD coatings,Journal of Materials Processing Technology,201(1-3),310(2008) |
[2] | WEN Lishi,HUANG Rongfang,New progress in TiNbased protective coatings deposited by arc ion plating,Vacuum,(1),1(2000)(闻立时,黄荣芳,离子镀硬质膜技术的最新进展和展望,真空,(1),1(2000)) |
[3] | GAO Meng,LI Qiang,DENG Xiangyun,LI Dejun,Effect of ion bombarding energy on the properties of ZrN/TiAlN nanometer multilayered coatings,Chinese Journal of Materials Research,21(6),627(2007)(曹猛,李强,邓湘云,李德军,离子轰击能量对ZrN/TiAlN纳米多层膜性能的影响,材料研究学报,21(6),627(2007)) |
[4] | J.C.Oliveria,A.Manaia,Hard amorphous Ti-Al-N coatings deposited by sputtering,Thin Solid Film,516(15),5032(2008) |
[5] | V.V.Uglov,V.M.Anishchik,S.V.Zlotski,I.D.Feranchuk,T.A.Alexeeva,A.Ulyanenkov,J.Brechbuehl,A.P.Lazar,Composition and phase stability upon annealing of gradient nitride coatings,Surface and Coatings Technology,202(11),2389(2008) |
[6] | Jun Zhang,Wengying Guo,Yu Zhang,Qiang Guo,Chuang Wang,Lipeng Zhang,Mechanical properties and phase structure of (TiAlZr)N films deposited by multi arc ion plating,Thin Solid Films,517(17),4830(2009) |
[7] | CUI Guanying,ZHANG Jun,LV Huimin,Microstructure and properties of (Cr,Ti,Al,Zr)N multi-component super-hard gradient films deposited by multi-arc ion plating,Journal of Materials Protection,43(6),24(2010)(崔贯英,张钧,吕会敏,多弧离子镀(Cr,Ti,Al,Zr)N多组元超硬梯度膜的结构及性能,材料保护,43(6),24(2010)) |
[8] | ZHANG Haoyang,ZHOU Lanying,TIAN Jianchao,Effect of substrate-bias on the characteristic of tiain coatings,Surface Technology,35(6),15(2006)(张皓扬,周兰英,田建朝,基体偏压对TiAlN涂层性能的影响,表面技术,35(6),15(2006)) |
[9] | A.Rizzo,M.A.Signore,M.F.De Riccardis,L.Capodieci,D.Dimaio,T.Nocco,Influence of growth rate on the structural and morphological properties of TiN,ZrN and TiN/ZrN multilayers,Thin Solid Films,515(17),6665(2007) |
[10] | G.Abadias.Stress and preferred orientation in nitridebased PVD coatings,Surface and Coatings Technology,202(11),2223(2008) |
[11] | Youn J.Kim,Ho Y.Lee,Tae J.Byun,Jeon G.Han,Microstructure and mechanical properties of TiZrAlN nanocomposite thin films by CFUBMS,Thin Solid Films,516(11),3651(2008) |
[12] | A.Hoerling,J.Sj(o)lén,H.Willmann,T.Larsson,M.Odén,T.Larsson,M.Odén,L.Hultman.Thermal stability,microstructure and mechanical properties of Ti1-xZrx N thin films,Thin Solid Films,516(18),6421(2008) |
[13] | YANG Honggang,LI Shu,ZHANG Ronglu,Influence of bias voltage and N2 partial pressure on structure of TiN film and performance of film/substrate,China Surface Engineering,22(2),20(2009)(杨洪刚,李曙,张荣禄,偏压和氮分压对TiN膜层结构和膜/基体系性能的影响,中国表面工程,22(2),20(2009)) |
[14] | Jong-Keuk Park,Young-Joon Baik.Increase of hardness and thermal stability of TiAlN coating by nanoscale multi-layered structurization with a BN phase,Thin SolidFilms,516(11),3661(2008) |
[15] | PAN Xiaolong,WANG Shaopeng,LI Zhengxian,HUANG Chunliang,WANG Baoyun,YAN Peng,JI Shouchang,Thermal fatigue and oxidation resistance of TiAlN coating grown by arc ion plating,Journal of Vacuum Science and Technology,28(S),60(2008)(潘晓龙,王少鹏,李争显,黄春良,王宝云,严鹏,姬寿长,电弧离子镀TiAlN涂层的热疲劳及抗氧化性能,真空科学与技术学报,28(增刊),60(2008)) |
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