研究了碳纳米管高频电磁波的屏蔽性能.碳纳米管经微波处理后在丙酮中经高速剪切分散,再加入到硅橡胶中经超声和搅拌分散制成试样.采用扫描电镜(SEM)观测碳纳米管在基体中的分散状况,采用AV3620型矢量网络分析仪检测电磁屏蔽性能.研究显示,随着碳纳米管加载量的增加,试样的导电性能和电磁屏蔽性能均得到 改善.碳纳米管加载量达到12%(质量分数,下同)时,试样的表面电阻率下降9个数量级,减小到103Ω,电磁屏蔽性能大幅提高.在1~6GHz频率范围内,屏蔽效能达到-30~-42dB.
参考文献
[1] | Lozano K .Vapor-grown carbon-fiber composites:Processing and electrostatic dissipative applications[J].Journal of the Minerals,Metals & Materials Society,2000,52(03):34. |
[2] | Sumio Iijima .Helical microtubules of graphitic carbon[J].Nature,1991,354:56. |
[3] | Ebbesen T W;Lezec H J;Hiura H et al.Electrical conductivity of individual carbon[J].Nature,1996,382:54. |
[4] | D.D.L.Chung .Electromagnetic interference shielding effectiveness of carbon materials[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(2):279-285. |
[5] | Salvetat J.-P.;Thomson N.H.;Kulik A.J.;Forro L.;Benoit W.;Zuppiroli L.;Bonard J.-M. .Mechanical properties of carbon nanotubes[J].Applied physics, A. Materials science & processing,1999(3):255-260. |
[6] | Demczyk BG.;Wang YM.;Cumings J.;Hetman M.;Han W.;Zettl A.;Ritchie RO. .Direct mechanical measurement of the tensile strength and elastic modulus of multiwalled carbon nanotubes[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2002(1/2):173-178. |
[7] | Ebbesen T W;Lezec H J;Hiura H et al.Electrical conductivity of individual carbon[J].Nature,1996,382:54. |
[8] | Tang Z K;Zhang L Y;Wang N et al.Superconductivity in 4 angstrom single-walled carbon nanotubes[J].Science,2001,292:3462. |
[9] | So HH;Cho JW;Sahoo NG .Effect of carbon nanotubes on mechanical and electrical properties of polyimide/carbon nanotubes nanocomposites[J].European Polymer Journal,2007(9):3750-3756. |
[10] | P. Miaudet;C. Bartholome;A. Derre .Thermo-electrical properties of PVA-nanotube composite fibers[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(14):4068-4074. |
[11] | Simon R M .EMI shielding through conductive plastics[J].Polymer-Plastics Technology and Engineering,1981,17(01):1. |
[12] | Lu G;Li X;Jiang H .Electrical and shielding properties of ABS resin filled with nickel-coated carbon fibers[J].Composites Science and Technology,1996,56(02):193. |
[13] | 刘顺华;刘军民;董星龙.电磁波屏蔽及吸波材料[M].北京:化学工业出版社,2007:83. |
[14] | Zhao D L;Li X;Shen Z M .Microwave absorbing property and complex permittivity and permeability of epoxy composites containing Ni-coated and Ag filled carbon nanotubes[J].Composites Science and Technology,2008,68:2902. |
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