选取柠檬酸钠(Na3C6H5O7)为碳酸钙生长的控制剂,通过气体扩散的方法仿生合成了不同形貌的碳酸钙,并考察矿化时间对碳酸钙晶型和形貌的调控作用.采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅立叶变换红外光谱(FT-IR)以及X射线衍射(XRD)对所得产物进行了表征.结果表明,随着矿化时间的改变所得碳酸钙粒子的形貌发生了显著的变化,出现哑铃状、高尔夫球状、球状等形貌.
参考文献
| [1] | Slavkin H;Price P.Chemistry and Biology of Mineralized Tissues[J].Excerpa Medica,1992:158-162. |
| [2] | 李纠,陈华雄.以氯化镁为晶型控制剂制备碳酸钙晶须[J].硅酸盐学报,2005(09):1153-1156. |
| [3] | Manoli F;Dalas E .Spontaneous Precipitation of Calcium Carbonate in the Presence of Ethanol,Isopropanol and Diethylene Glycol[J].Journal of Crystal Growth,2000,218:359-364. |
| [4] | 朱万诚,陈建峰,王玉红.旋转填充床中合成微细晶须碳酸钙的试验研究[J].材料科学与工艺,2005(01):30-33,37. |
| [5] | 韩志华,曹林.CaCO3纳米线的制备及表征[J].无机材料学报,2005(06):1349-1352. |
| [6] | Chengyu Wang .Control the polymorphism and morphology of calcium carbonate precipitation from a calcium acetate and urea solution[J].Materials Letters,2008(15):2377-2380. |
| [7] | 陈先勇;唐琴;胡卫兵 .均匀大颗粒球形碳酸钙的防生合成[J].应用化学,2008,26(05):562-565. |
| [8] | Nishida I .Precipitation of calcium carbonate by ultrasonic irradiation[J].Ultrasonics sonochemistry,2004(6):423-428. |
| [9] | H. Monma;M. Nakashima;S. Takahashi;T. Okura .Properties and Interface Observation of Electrodeposited Calcium Carbonate[J].Key engineering materials,2003(253):197-204. |
| [10] | Pai RK;Pillai S .Water-soluble terpolymer directs the hollow triangular cones of packed calcite needles[J].Crystal growth & design,2007(2):215-217. |
| [11] | 赵丽娜,王秀艳,孔治国,王子忱.枝状文石型碳酸钙的仿生合成及在PVC中的应用[J].高等学校化学学报,2010(12):2329-2333. |
| [12] | 胡艳丽,马拥军,罗庆平,周勇,裴重华.L-天冬氨酸诱导叠层碳酸钙微晶的形成[J].人工晶体学报,2010(03):802-806,812. |
| [13] | Chemov A A.Modem Crystallography Ⅲ[J].Journal of Crystal Growth,1984 |
| [14] | Chemov A A .Formation of Crystal in Solutions[J].Contemporary Physics,1989,30:251-276. |
| [15] | Dean J A;McGraw H.Lange's Handbook of Chemistry[M].New York:McGraw-Hill,1985 |
| [16] | Williams E D;Bartlet N C .Thermodynamics of Surface Morphology[J].Science,1991,251:393-400. |
| [17] | 崔福斋.生物矿化[M].北京:清华大学出版社,2007 |
| [18] | Richard Compton;Stephen G Davies;John Evans .[D].Oxford Chemistry,2011. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%