以季戊四醇为"核",与1,2,4-偏苯三酸酐和环氧氯丙烷反应合成超支化聚合物,并通过马来酸酐进行端基改性,合成了以羟基和/或羧基为末端基的水溶性超支化聚物(HBPs),通过FT-IR、1H-NMR对结构进行了表征.然后将该超支化聚合物(HBPs)应用于BA/VAc/AA丙烯酸共聚物压敏胶粘剂(PSAc)乳液中.发现超支化聚合物的加入提高了胶粘剂的稳定性和粘接性能.以羧基为末端基的超支化聚合物(HBP-B)加入量为0.5%时,胶粘剂互相矛盾的两个性能--持粘力与剥离强度同时达到最大值.
参考文献
| [1] | Yates CR;Hayes W .Synthesis and applications of hyperbranched polymers[J].European Polymer Journal,2004(7):1257-1281. |
| [2] | 岳俊秋,曹元,杜宇,王跃川.末端接液晶基元的超支化聚酯液晶的合成及表征[J].高分子材料科学与工程,2006(04):56-59. |
| [3] | 胡晖,曹中林,范晓东.环境敏感性超支化聚合物的合成及药物的控制释放[J].高分子材料科学与工程,2005(02):102-105. |
| [4] | Wang XX;Lai GQ;Jiang ZG;Zhang YF .Synthesis of water-soluble hyperbranched polymer and its application in acrylic latex[J].European Polymer Journal,2006(2):286-291. |
| [5] | Jovanovic, R;Dube, MA .Screening experiments for butyl acrylate/vinyl acetate pressure-sensitive adhesives[J].Industrial & Engineering Chemistry Research,2005(17):6668-6675. |
| [6] | Roberge S;Dube MA .The effect of particle size and composition on the performance of styrene/butyl acrylate miniemulsion-based PSAs[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(3):799-807. |
| [7] | A.Aymonier;E.Papon;J.-J.Villenave;Ph.Tordjeman;R.Pirri;P.Gerard .Design of Pressure-Sensitive Adhesives by Free-Radical Emulsion Copolymerization of Methyl Methacrylate and 2-Ethylhexyl Acrylate.1.Kinetic Study and Tack Properties[J].Chemistry of Materials,2001(8):2562-2566. |
| [8] | 冯宗财,李琳.末端环氧化超支化荧光聚合物的合成[J].高分子材料科学与工程,2006(06):36-39. |
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