综述了高容量稀土镁镍基A2B7型超晶格贮氢合金的发展历程,其大致可以分为1997～2004年、2005～2007年和2008年至今的3个阶段.目前,A2B7型合金可实现最大放电容量高于380 mAh/g、循环寿命超过500周期,国内已进入产业化试制阶段.对于A2B7型合金,PuNi3、Ce2Ni7、Pr5Co19型等超晶格结构相的定量识别、产业化关键技术突破及其在高容量密封二次电池中的集成应用是未来几年需要重视并解决的问题.
参考文献
| [1] | Fetcenko M A et al.[J].Journal of Power Sources,2007,165(02):544. |
| [2] | Kadir K et al.[J].Journal of Alloys and Compounds,1997,257:115. |
| [3] | Kadir K et al.[J].Journal of Alloys and Compounds,1999,287:264. |
| [4] | Kadir K et al.[J].Journal of Alloys and Compounds,2000,302:112. |
| [5] | Chen J et al.[J].Electrochemical and Solid State Letters,2000,3(06):249. |
| [6] | Kohno T et al.[J].Journal of Alloys and Compounds,2000,311:L5. |
| [7] | Pan Hongge et al.[J].International Journal of Hydrogen Energy,2003,28(01):113. |
| [8] | Pan Hongge et al.[J].Journal of Alloys and Compounds,2003,351(1-2):228. |
| [9] | Liu Yongfeng et al.[J].International Journal of Hydrogen Energy,2004,29(03):297. |
| [10] | Liu Yongfeng et al.[J].Journal of Alloys and Compounds,2004,376(1-2):296. |
| [11] | Liu Yongfeng et al.[J].Journal of Alloys and Compounds,2010,509(03):675. |
| [12] | Bin Liao et al.[J].Journal of Alloys and Compounds,2004,376(1-2):186. |
| [13] | 王大辉,罗永春,闫汝煦,兴长策,康龙.La0.67Mg0.33Ni2.5Co0.5贮氢合金的制备和MH电极性能研究[J].稀有金属材料与工程,2004(12):1283-1286. |
| [14] | 腾鑫 .[D].Lanzhou:Lanzhou University of Technology,2005. |
| [15] | Zhang Y H et al.[J].Journal of Alloys and Compounds,2004,379:298. |
| [16] | Han Shumin;Liu Baozhong;Zhang Zhong .Phase Structure and Electrochemical Properties of RE-Mg Based Composite Hydrogen Storage Alloys[J].Journal of Rare Earths,2004(6):878-881. |
| [17] | 张海昌,墨伟,申元,杨化滨,周作祥,周杏弟.La0.7Mg0.3（Ni1-xCox）3.5 （0≤x≤0.5）储氢合金电化学性能[J].中国稀土学报,2004(05):712-714. |
| [18] | 刘丽琴,唐睿,柳永宁.稀土元素对La0.8 Mg0.2 Ni2.8 Co0.6 储氢合金性能的影响[J].中国有色金属学报,2003(04):871-875. |
| [19] | 王兆松 et al.[P].中国专利,200410024775.9,2004. |
| [20] | Yartys V A et al.[J].Journal of Alloys and Compounds,2002,330-332:132. |
| [21] | Yartys V A et al.[J].Journal of Alloys and Compounds,2003,356-357:109. |
| [22] | Yasuoka S et al.[J].Journal of Power Sources,2006,156(02):662. |
| [23] | Zhang F L et al.[J].Journal of Power Sources,2006,150:247. |
| [24] | 周增林,宋月清,崔舜,林晨光,曲选辉.Nd替代La对La-Mg-Ni系A2B7型贮氢电极合金性能的影响[J].中国有色金属学报,2007(01):45-52. |
| [25] | Ishida J et al.[P].中国专利,200510003672.9,2005. |
| [26] | Hongge Pan;Ni Chen;Mingxia Gao .Effects of annealing temperature on structure and the electrochemical properties of La_(0.7)Mg_(0.3)Ni-(2.45)Co_(0.75)Mn_(0.1)Al_(0.2) hydrogen storage alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):306-312. |
| [27] | Cheng L F et al.[J].Journal of Power Sources,2008,185:1519. |
| [28] | Zhong Zhang;Shumin Han;Yuan Li .Electrochemical properties of Ml_(1-x)Mg_xNi_(3.0)Mn_(0.10)Co_(0.55)Al_(0.10) (x = 0.05-0.30) hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(1/2):208-211. |
| [29] | Ying Wang et al.[J].Journal of Rare Earths,2006,24(01):340. |
| [30] | 周增林 et al.[P].中国专利,200810116233.2,2008. |
| [31] | 张法亮,罗永春,张永超,邓安强,康龙,陈剑虹.La-Mg-Ni系A2B7型贮氢合金的结构与电化学性能[J].中国稀土学报,2006(05):592-598. |
| [32] | 王大辉 et al.[J].稀有金属材料与工程,2005,35(09):1379. |
| [33] | 张羊换,任慧平,李保卫,董小平,赵小龙,王新林.La0.7Mg0.3Ni2.55-xCo0.45Alx（x=0～0.4）贮氢合金的循环稳定性[J].中国有色金属学报,2006(08):1320-1325. |
| [34] | Liu Yongfeng et al.[J].International Journal of Hydrogen Energy,2008,33(01):124. |
| [35] | Liu Yongfeng et al.[J].Journal of Alloys and Compounds,2005,388(1-2):147. |
| [36] | Chu Hailiang et al.[J].Journal of Alloys and Compounds,2008,457(1-2):90. |
| [37] | Zhao Yu et al.[J].Journal of Alloys and Compounds,2010,496(1-2):454. |
| [38] | Zhang F L et al.[J].Journal of Alloys and Compounds,2006,424(1-2):218. |
| [39] | Cerny R.;Latroche M.;Percheron-Guegan A.;Yvon K.;Joubert JM. .Anisotropic diffraction peak broadening and dislocation substructure in hydrogen-cycled LaNi5 and substitutional derivatives[J].Journal of Applied Crystallography,2000(4):997-1005. |
| [40] | Pan Hongge et al.[J].International Journal of Hydrogen Energy,2006,31:517. |
| [41] | Zhang Yanghuan et al.[J].Journal of Alloys and Compounds,2006,398:178. |
| [42] | Akiba E et al.[J].Journal of Alloys and Compounds,2006,408-412:280. |
| [43] | Hayakawa H et al.[J].Materials Transactions,2005,46(06):1393. |
| [44] | Yaroslav E Filinchuk et al.[J].Inorganic Chemistry,2007,46(07):2914. |
| [45] | Ute Ch Rodewald et al.[J].Journal of Solid State Chemistry,2007,180(05):1720. |
| [46] | Zhang F L et al.[J].Journal of Power Sources,2005,150(04):247. |
| [47] | Li F et al.[J].Journal of Alloys and Compounds,2009,471(1-2):371. |
| [48] | Denys, RV;Riabov, AB;Yartys, VA;Sato, M;Delaplane, RG .Mg substitution effect on the hydrogenation behaviour, thermodynamic and structural properties of the La2Ni7-H(D)(2) system[J].Journal of Solid State Chemistry,2008(4):812-821. |
| [49] | 周增林 et al.[P].中国专利,200610088905.4,2006. |
| [50] | 肖方明 et al.[P].中国专利,200510101899.7,2005. |
| [51] | 廖彬,雷永泉,吕光烈,陈立新,葛红卫,潘洪革.La-Mg-Ni系AB3型贮氢电极合金的相结构与电化学性能[J].金属学报,2005(01):41-48. |
| [52] | 郭靖洪 et al.[P].中国专利,200710157452.0,2007. |
| [53] | 罗永春 et al.[P].中国专利200610042875.3,2006. |
| [54] | Dong Xiaoping et al.[J].International Journal of Hydrogen Energy,2007,32:4949. |
| [55] | Zhang Yanghuan et al.[J].International Journal of Hydrogen Energy,2009,34:6335. |
| [56] | Zhang Yanghuan et al.[J].Journal of Alloys and Compounds,2009,480(02):547. |
| [57] | 彭能,梁振锋,肖方明,王英,卢其云,唐仁衡.纳米晶AB3型稀土镁基贮氢合金研究[J].材料研究与应用,2007(01):23-26. |
| [58] | 肖方明 et al.[J].中国有色金属学报,2007,17:963. |
| [59] | 黄长庚 et al.[P].中国专利,200810116238.5,2008. |
| [60] | Chai Yujun et al.[J].Journal of Alloys and Compounds,2010,485(1-2):174. |
| [61] | Li Yuan et al.[J].Electrochimica Acta,2007,52:5945. |
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