欢迎登录材料期刊网

材料期刊网

高级检索

富勒烯以其独特的物理化学性质吸引了众多研究者的关注.但富勒烯在水中的溶解度十分有限,成为其应用在生物系统中的瓶颈.最近发现,将富勒烯制备成纳米颗粒水悬液是一种能有效改善富勒烯水溶性的方法.介绍了目前采用的4种制备方法,即四氢呋喃-丙酮法、甲苯超声法、四氢呋喃法、直接搅拌法,同时还介绍了水中纳米富勒烯颗粒可能形成的机制以及纳米富勒烯颗粒的细胞毒性和抗菌活性等方面的研究进展.

参考文献

[1] Kroto H W;Heath J R;Smalley R E et al.C60:Buckminsterfullerene[J].Nature,1985,318:162.
[2] Kratschmer W;Lamb L D;Huffman D R et al.Solid C60:a new form of carbon[J].Nature,1990,347:354.
[3] Tagmatarchis N;Shinohara H .Fullerenes in medicinal chemistry and their biological applications[J].Mini-reviews In Medicinal Chemistry,2001,1:339.
[4] Yang X L;Fan C H;Zhu H S .Photo-induced cytotoxicity of malonic acid[C60]fullerene derivatives and its mechanism[J].Toxicology in Vitro,2002,16:41.
[5] Scrivens W A;Tour J M .Synthesis of 14C-labled C60,Its suspension in water,and its uptake by Human Keratinocytes[J].Journal of the American Chemical Society,1994,116:4517.
[6] Andrievsky G V;Kosevich M V;Vovk O M et al.On the production of an aqueous colloidal solution of fullerenes[J].Chemistry Communications,1995,12:1281.
[7] Deguchi S;Rossitza G A;Tsujii K .Stable dispersions of fullerenes,G60 and G70 in water.Preparation and characterization[J].Langmuir,2001,17:6013.
[8] Fiorito S;Serafino A;Andreola F;Togna A;Togna G .Toxicity and biocompatibility of carbon nanoparticies[J].Journal of nanoscience and nanotechnology,2006(3):591-599.
[9] Nel A;Xia T;Madler L;Li N .Toxic potential of materials at the nanolevel.[J].Science,2006(5761):622-627.
[10] Guzman KAD;Taylor MR;Banfield JF .Environmental risks of nanotechnology: National nanotechnology initiative funding, 2000-2004[J].Environmental Science & Technology: ES&T,2006(5):1401-1407.
[11] Andrievsky G V;Klochkov V K;Mchedlov Petrossyan N O et al.Studies of aqueous colloidal solutions of fullerene C60 by electron microscopy[J].Chemical Physics Letters,1999,300:392.
[12] Fortner J D;Lyon D Y;Hughes J B et al.C60 in water:Nanocrystal formation and microbial response[J].Environmental Science and Technology,2005,39:4307.
[13] Cheng X;Kan A T;Tomson M B .Naphthalene adsorption and desorption from aqueous C60 fullerene[J].Journal of Chemical and Engineering Data,2004,49:675.
[14] Lyon DY;Adams LK;Falkner JC;Alvarez PJJ .Antibacterial activity of fullerene water suspensions: Effects of preparation method and particle size[J].Environmental Science & Technology: ES&T,2006(14):4360-4366.
[15] Chen KL;Elimelech M .Aggregation and deposition kinetics of fullerene (C-60) nanoparticles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(26):10994-11001.
[16] Alargova R G;Deguchi S;Tsujii K .Stable colloidal deispersions of fullerenes in polar organic solvents[J].Journal of the American Chemical Society,2001,123:10460.
[17] Scharff P;Risch K;Durov S S et al.Structure of C60 fullerene in water:spectroscopic data[J].CARBON,2004,42:1203.
[18] Sayes C;Former J;Colvin V L et al.The differential cytotoxicity of water-soluble fullerenes[J].Nano Letters,2004,4:1881.
[19] Sayes CM;Gobin AM;Ausman KD;Mendez J;West JL;Colvin VL .Nano-C-60 cytotoxicity is due to lipid peroxidation[J].Biomaterials,2005(36):7587-7595.
[20] Isakovic A;Markovic Z;Todorovic Markovic B;Nikolic N;Vranjes Djuric S;Mirkovic M;Dramicanin M;Harhaji L;Raicevic N;Nikolic Z;Trajkovic V .Distinct cytotoxic mechanisms of pristine versus hydroxylated fullerene.[J].Toxicological sciences: An official journal of the Society of Toxicology,2006(1):173-183.
[21] Dhawan A;Taurozzi J S;Tarabara V V.Stable colloidal dispersions of C60 fullerenes in water:evidenee for genotoxicity[J].Environmental Science and Technology,2006
[22] Andrievsky G;Klochkov V;Derevyanchenko L .Is the C-60 fullerene molecule toxic?![J].Fullerenes, nanotubes, and carbon nanostructures,2005(4):363-376.
[23] Rouse JG;Yang J;Barron AR;Monteiro-Riviere NA .Fullerene-based amino acid nanoparticle interactions with human epidermal keratinocytes.[J].Toxicology in vitro: an international journal published in association with BIBRA,2006(8):1313-1320.
[24] 杨新林,乔新歌,朱张广,程福永,朱鹤孙,范楼珍.单加成环丙烷富勒烯膦酸酯衍生物的合成与电化学性能[J].有机化学,2006(11):1557-1561.
[25] 陈霖,杨新林,彭鲲鹏,程福永,朱鹤孙.水溶性C60衍生物的光致细胞膜毒性的动态研究[J].高技术通讯,2001(02):17-20.
[26] Cheng F Y;Yang X L;Zhu H S .Synthesis and optical properties of tetraethyl methano[60]fullerenediphosphoante[J].Tetrahedron Letters,2000,41:3947.
[27] Cheng F Y;Yang X L;Fan C H et al.Organophosphorus chemistry of fullerene:synthesis and biological effects of organophosphorus compounds of C60[J].Tetrahedrom,2001,57:7331.
[28] MENG Xianmei,CHEN Zhe,LI Bo,ZHANG Yufei,ZHAO Dongxu,YANG Xinlin.Inhibition of M-MuLV reverse transcriptase activity by fullerene derivatives[J].科学通报(英文版),2006(20):2550-2552.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%