The effects of carbonate on the exchangeability and the bioavailability of exogenous neodymium in soil were studied by 147Nd isotopic tracer method. Exchangeable Nd was extracted by 1 mol*L-1 NaAc (pH8.2) in the experiment. The results indicate that whether carbonate exists in soil or not, beyond 99% of exogenous Nd is adsorbed by soil. Low-concentration carbonate (0.8~1.6 g*kg-1) can reduce exchangeable Nd concentration in soil, while high-concentration carbonate (4.0 g*kg-1) impacts little on the exchangeable Nd concentration. In addition, carbonate of 0.8~1.6 g*kg-1 in soil can inhibit wheat seedlings to absorb Nd. However, when the carbonate concentration rises to 4.0 g*kg-1, the inhibition will become indistinct.
参考文献
[1] | WU Zhao-ming;TANG Xi-ke;GAO Xiao xia et al.Studies on the effect of rare earth elements on the increase of yield in agriculture I: Preliminary studies on the distribution and content of rare earth elements in plants[J].中国稀土学报,2002,1(01):70-75. |
[2] | GUOBo-sheng .Recent research advance of rare earth in the field of biology[J].Chinese Rare Earths,2002,20(01):64-68. |
[3] | CANTRELL K J;BYRNE R H .Rare earth element complexation by carbonate and oxalate ions[J].Geochimica et Cosmochimica Acta,1987,51:597-605. |
[4] | Lee J H;BYRNE R H .Complexation of trivalent rare earth elements (Ce, Eu, Gd, Tb, Yb) by carbonate ions[J].Geochimica et Cosmochimica Acta,1993,57:295-302. |
[5] | Department of M;Zhongshan University.Physical and Chemical Constants of Rare Earths (in Chin[M].北京:冶金工业出版社,2002:332. |
[6] | CHEN Zhao-xi;WANG Xiao-rong;TIAN Li qing .Speciation and availability of soluble rare earths added in soil[J].中国稀土学报,2002,13(01):74-77. |
[7] | anjing Institute of Soil;Chinese Academy of Sciences.Physical and Chemical Analysis of Soil (in Chin )[M].北京:中国农业出版社,1980 |
[8] | CAO Xin-de;ZHAO Gui-wen .Study development of available rare earth elements in soils[J].Chinese Rare Earths,2002,18(04):18. |
[9] | LIU Ya-li;LIU Jun-hua;WANG Zi-jian et al.Speciation transformation of added rare earth elements in soil[J].Environmental Chemistry,18(05):393-397. |
[10] | De Baar H J W;SCHIJF J;BYRNE R H .Solution chemistry of the rare earth elements in seawater[J].European Journal of Solid State and Inorganic Chemistry,1991,28:357-373. |
[11] | WANG Li-gang;YU Xue-yuan;ZHAO Zhen hua.Rare Earth Elements Geochemistry[M].北京:科学出版社,2002:15-17. |
[12] | ZHANG Ruo-hua.Rare Earth Elements Chemistry[M].天津:天津科学技术出版社,1987:115-117. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%