传统足金的硬度很低,制约了首饰的艺术价值.采用钴、锑、钪对纯金进行微合金化处理,研究了改性足金的显微组织和硬化行为.试验结果表明,改性足金(含金量99.31 mass%)的铸态硬度可达到62 HV,经700℃固溶处理后组织呈现单一固溶体结构,硬度可达到51 HV.固溶态材料经冷变形处理时,形变量为80%时硬度达到121 HV,再经250℃时效处理后出现了弥散分布的沉淀析出相,晶粒组织比传统足金显著细化,硬度达到了138 HV.改性足金的硬化行为是合金元素固溶强化、细晶强化、形变强化和析出强化综合作用的结果.
参考文献
[1] | Corit C W .Metallurgy of microalloyed 24 carat golds[J].Gold Bulletin,1999,32(02):39-47. |
[2] | 赵怀志;宁远涛.金[M].长沙:中南大学出版社,2003 |
[3] | 杨青青,熊惟皓,张杰.Au-Ti足金的强化机理研究[J].稀有金属材料与工程,2006(12):1904-1907. |
[4] | 宁远涛.合金元素对Au的强化效应与应用[J].贵金属,2002(03):51-56. |
[5] | Yuantao Ning .Alloying and Strengthening of Gold via Rare Earth Metal Additions[J].Gold Bulletin,2001(3):77-87. |
[6] | Madeleine du Toit;Elma van der Lingen;Lizelle Glaner .The development of a novel gold alloy with 995 fineness and increased hardness[J].Gold Bulletin,2002(2):46-52. |
[7] | 宋维锡.金属学[M].北京:冶金工业出版社,2004 |
[8] | 宁远涛.贵金属与稀土金属的相互作用(Ⅰ)Au-RE系[J].贵金属,2000(01):42-51. |
[9] | Slater J C .Atomic radii in crystals[J].The Journal of Chemical Physics,1964,41(10):3199-3204. |
[10] | Chou Y T .Dislocation pileups and the Hall-Petch relation[J].Canadian Journal of Physics,1967,45(02):559-566. |
[11] | Yuantao Ning .Properties and applications of some gold alloys modified by rare earth additions[J].Gold Bulletin,2005,38(01):3-8. |
[12] | Wright J C;Corit C W.Strong 24 carat golds:the metallurgy of microalloying[A].New Mexico:Met-Chem Research Publishing Co,1998:27-34. |
[13] | Narutani T;Takamura J .Grain-size strengthening in terms of dislocation density measured by resistivity[J].ACTA METALLURGICA ET MATERIALIA,1991,39(08):2037-2049. |
[14] | 梁基谢夫 Н П;郭青蔚.金属二元系相图手册[M].北京:化学工业出版社,2010 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%