液流式电容法作为一种新型脱盐水处理技术,基于大比表面积的电极材料,通过外接直流电压的施加,达到去除水中无机盐离子的脱盐目的.详细地从理论角度介绍了液流式电容脱盐技术,概括了炭材料在除盐工艺具有较大优势,并介绍了当前主要的电极成型方法,最后论述了该技术的优势与不足.可以预见,在不久的将来,该项技术一定会得到广泛的应用.
参考文献
[1] | Mark A. Shannon;Paul W. Bohn;Menachem Elimelech;John G. Georgiadis;Benito J. Marinas;Anne M. Mayes .Science and technology for water purification in the coming decades[J].Nature,2008(7185):301-310. |
[2] | R. Semiat;Y. Galperin .Effect of non-condensable gases on heat transfer in the tower MED seawater desalination plant[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2001(1):27-46. |
[3] | Sayed E;Yehia M .Thermoeconomics of some options of large mechanical vapor-compression units[J].Desalination,1999,125(1-3):251. |
[4] | Demircioglu M et al.Demineralization by electrodialysis (ED) separation performance and cost comparison for mono-valent salts[J].Desalination,2003,153(1-3):329. |
[5] | Grundisch A;Schneider B .Optimising energy consumption in SWRO systems with brine concentrators[J].Desalination,2001,138(1-3):223. |
[6] | Mark Wilf;Kenneth Klinko .Optimization of seawater RO systems design[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2001(1/3):299-306. |
[7] | Andelman M D .Flow-through capacitor[P].US,5192432,1993. |
[8] | 代凯,施利毅,方建慧,张登松,张云竹.基于纳米碳管导电材料的研究进展[J].材料导报,2005(z2):63-65,70. |
[9] | Villar I;Roldan S;Ruiz V et al.Capacitive deionization of NaCl solutions with modified activated carbon electrodes[J].Energy & Fuels,2010,24(06):3329. |
[10] | 赵雪娜,倪文,林庚,韩剑宏.电吸附技术在含盐水除盐中的应用与研究进展[J].工业水处理,2008(03):5-8. |
[11] | 杨红生,周啸,冯天富,汤孝平.电化学电容器最新研究进展I.双电层电容器[J].电子元件与材料,2003(02):13-16,19. |
[12] | 代凯 .纳米碳管基电极的电化学和脱盐性能研究[D].上海大学,2007. |
[13] | Biesheuvel P M;Limpt B V;Wal A V D .Dynamic adsorption/desorption process model for capacitive deionization[J].Journal of Physical Chemistry C,2009,113:5636. |
[14] | Xing W;Ngo HH;Kim SH;Guo WS;Hagare P .Adsorption and bioadsorption of granular activated carbon (GAC) for dissolved organic carbon (DOC) removal in wastewater[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2008(18):8674-8678. |
[15] | Zhang DS;Shi LY;Fang JH;Dai K .Influence of diameter of carbon nanotubes mounted in flow-through capacitors on removal of NaCl from salt water[J].Journal of Materials Science,2007(7):2471-2475. |
[16] | Dai K;Shi LY;Zhang DS;Fang JH .NaCl adsorption in multi-walled carbon nanotube/active carbon combination electrode[J].Chemical Engineering Science,2006(2):428-433. |
[17] | Rao A M;Richter E;Bandow S et al.Diameter-selective raman scattering from vibrational modes in carbon nanotubes[J].Science,1997,225:187. |
[18] | Bandow S.;Saito Y.;Rao AM.;Grigorian L.;Richter E.;Eklund PC.;Asaka S. .Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes[J].Physical review letters,1998(17):3779-3782. |
[19] | 孙世强,张文峰,程杰,曹高萍,王志军,杨裕生.活性炭电极电容法脱盐工艺和性能的研究[J].水处理技术,2008(03):31-34. |
[20] | Avraham E;Yaniv B;Soffer A et al.Developing ion electroadsorption stereoselectivity,by pore size adjustment with chemical vapor deposition onto active carbon fiber electrodes,case of Ca《'2+》/Na《'+》 separation in water capacitive desalination[J].Journal of Physical Chemistry C,2008,112:7385. |
[21] | Gabelich C J;Tran T D;Suffer I H .Electrosorption of inorganic salts from aqueous solution using carbon aerogelelectrodes[J].Environmental Science and Technology,2002,36:3010. |
[22] | 王万兵,张睿,刘希邈,王灿,凌立成.酚醛-糠醛基炭气凝胶对NaCl溶液的电吸附行为[J].新型炭材料,2007(01):65-69. |
[23] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56. |
[24] | Zou, L;Li, L;Song, H;Morris, G .Improving the capacitive deionisation performance by optimising pore structures of the electrodes[J].Water Science and Technology,2010(5):1227-1233. |
[25] | Dai K;Shi L Y;Fang J H et al.NaCl adsorption in multiwalled carbon nanotubes[J].Mater I ett,2005,59:1989. |
[26] | 代凯,施利毅,方建慧,张登松,余昺鲲.碳纳米管电极电吸附脱盐工艺的研究[J].应用科学学报,2005(05):539-544. |
[27] | Yang C M;Choi W H;Na B K et al.Aerogelsilica gel composite electrodes[J].Desalination,2005,174:125. |
[28] | Zhang B;Liang J;Xu C L et al.Electic double-layer capacitors using carbon nanotube electrodes and organic electrolyte[J].Materials Letters,2001,51:539. |
[29] | 张彬,马仁志,徐才录,魏秉庆,梁吉,吴德海.双电层电容器碳纳米管固体极板的制备[J].电子学报,2000(08):13-15. |
[30] | 代凯,施利毅,方建慧,张登松,余昺鲲,温轶,刘继全.粘结剂对碳纳米管电极性能的影响[J].化工矿物与加工,2005(05):21-23. |
[31] | Izadi-Najafabadi A;Yasuda S;Kobashi K et al.Extracting the full potential of single-walled carbon nanotuhes as durable supercapacitor electrodes operable at 4V with high power and energy density[J].Advanced Materials,2010,22:E235. |
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