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金属镁具有储氢密度大、价格低廉、资源丰富等优点,是当前最有发展前景的储氢材料之一,但其动力学性能差,需要高温才能吸收和放出氢气.为了改善其储氢性能,除制备镁基合金外,利用机械球磨法制备镁基复合储氢材料也得到了广泛研究.对目前制备的镁基复合储氢材料进行了分类,并分别介绍了各类的研究进展.

参考文献

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[8] Ivanov E;Konstanchuk I;Bokhonov B et al.Hydrogen interaction with mechanically alloyed magnesium-salt composite materials[J].Journal of Alloys and Compounds,2003,359:320.
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[11] Hayao Imamura;Shinya Tabata;Yoshirou Takesue .Hydriding-dehydriding behavior of magnesium composites obtained by mechanical grinding with graphite carbon[J].International journal of hydrogen energy,2000(9):837-843.
[12] Chiaki Iwakura;Hiroshi Inoue .A new electrode material for nickel-metal hydride batteries: MgNi-graphite composites prepared by ball-milling[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):653-657.
[13] Imamura H;Takesue Y;Akimoto T et al.Hydrogen-absorbing magnesium composites prepared by mechanical grinding with graphite:Effects of additives on composite structures and hydriding properties[J].Journal of Alloys and Compounds,1999,293-295:564.
[14] 于振兴,孙宏飞,王尔德,梁吉,房文斌.添加碳纳米管镁基材料的储氢性能[J].中国有色金属学报,2005(06):876-881.
[15] Lillo-Ródenas M A;Guo Z X;Aguey-Zinsou K F .Effects of different carbon materials on MgH2 decomposition[J].Carbon,2008,46:126.
[16] 闫晓琦,袁华堂,张松林,张坤,孙波,高学平,宋德瑛.镁基合金与碳纳米纤维复合储氢材料的制备与性能研究(Ⅰ)--以化学镀Ni碳纳米纤维为前驱物热扩散法合成Mg2Ni-CNFs复合储氢材料[J].南开大学学报(自然科学版),2004(04):5-9.
[17] Deepa L. Narayanan;Angela D. Lueking .Mechanically milled coal and magnesium composites for hydrogen storage[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(4):805-820.
[18] 卢国俭,周仕学,马怀营,谭琦,ZHOU Zhuang-fei.反应球磨法制备镁/碳纳米复合储氢材料[J].功能材料,2007(07):1128-1131.
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