Eu(TTA)2(phen)(UAH) (UAH=undecylenic acid)with fine fluorescent property and active group was synthesized. The measurement and characterization of complexes were also carried out. A series of composites based silicon rubber were prepared by blending silicon rubber and Eu(TTA)2(phen)(UAH) rare earth complex with active groups. Next, the effect of vulcanizing time on the property of materials was mainly studied. The results show that the dispersed particle size of rare earth complexes decreases gradually in the vulcanizing process.
参考文献
[1] | Robinson M R;Ostrowski J C;Bazan G C et al.Reduced operating voltages in polymer light-emitting diodes doped with rare-earth comlexes[J].Advanced Materials,2003,15:1547. |
[2] | Yang G Y;Srdanov V;Robnson M R et al.Orienting Eu(dnm)3phen by tensile drawing in polyethylene:polarized Eu3+ emission[J].Advanced Materials,2002,14:980. |
[3] | Zhang XM;Sun RG;Zheng QB;Kobayashi T;Li WL .Temperature-dependent electroluminescence from (Eu, Gd) coordination complexes[J].Applied physics letters,1997(18):2596-2598. |
[4] | Abdullah M;Morimoto T;Okuyama K .Generating blue and red luminescence from ZnO/Poly(ethylene glycol) nanocomposites prepared using an In-Situ method[J].Advanced Functional Materials,2003,13:800. |
[5] | Moleski R.;Stathatos E.;Bekiari V.;Lianos P. .Preparation of thin Ureasil films with strong photoluminescence based on incorporated europium-thenoyltrifluoroacetone-bipyridine complexes[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(1/2):279-283. |
[6] | Huang J M;Bekiari V;Lianos P et al.Study of poly(methyl methacrylate) thin films doped with laster dyes[J].Journal of Luminescence,1999,81:285. |
[7] | Beatriz Julian;Hector Beltran;Eloisa Cordoncillo;Purificacion Escribano;Bruno Viana;Clement Sanchez .Influence of the Matrix in the Optical Response of Organic-Inorganic Hybrid Materials Doped with Europium(III)[J].Journal of Sol-Gel Science and Technology,2003(1/2/3):977-980. |
[8] | Bekiari V;Lianos P;Stangar U L et al.Optimization of the intensity of luminescence emission from silica/poly(ethylene oxide) and silica/poly(propylene oxide) nanocomposite gels[J].Chemistry of Materials,2000,12:3095. |
[9] | Franville A C;Zambon D;Mahiou R et al.Luminescence behavior of sol-gel-derived hybrid materials resulting from covalent grafting of a chromophore unit to different organically modified alkoxysilanes[J].Chemistry of Materials,2000,12:428. |
[10] | Yang C Y;Srdanov V;Robinson M R et al.Orienting Eu(dnm)3phen by tensile drawing in polyethylene:polarized Eu3+ emission[J].Advanced Materials,2002,14:980. |
[11] | Liu L;Lu YL;He L;Zhang W;Yang C;Liu YD;Zhang LQ;Jin RG .Novel europium-complex/nitrile-butadiene rubber composites[J].Advanced functional materials,2005(2):309-314. |
[12] | Beatriz Julian;Hector Beltran;Eloisa Cordoncillo;Purificacion Escribano;Bruno Viana;Clement Sanchez .Influence of the Matrix in the Optical Response of Organic-Inorganic Hybrid Materials Doped with Europium(III)[J].Journal of Sol-Gel Science and Technology,2003(1/2/3):977-980. |
[13] | Paramita Saha Chowdhury;Sujata Saha;Amitava Patra .Influence of nanoenvironment on luminescence of Eu3+ activated SnO2 nanocrystals[J].Solid State Communications,2004,131:785. |
[14] | Legendziewicz J.;Wiglusz R.;Amirkhanov V.;Oczko G. .Correlation between spectroscopic characteristics and structure of lanthanide phosphoro-azo derivatives of beta-diketones[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(0):792-799. |
[15] | Ewa Huskowska;Ilona Turowska-Tyrk;Janina Legendziewicz et al.Two high and low symmetry europium complexes wit L-proline:spectroscopy and structure[J].Journal of Alloys and Compounds,1998,275-277:852. |
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