骨架结构的多元硫属金属化合物是一类很好的无机多功能材料,这一类化合物晶体的合成研究引起人们广泛的兴趣.主要介绍了硫、砷(As)与某些金属(如Bi、Ni等)形成阴离子骨架结构这一类化合物的设计合成与研究状况.讨论了采用溶剂热方法合成此类晶体时,影响合成过程的一些因素.
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